Timed-release bleach coated with an inorganic salt and an amine with reduced dye damage

• US 4,728,453 A
• Filed: 01/13/1987
• Issued: 03/01/1988
• Est. Priority Date: 01/13/1987
• Status: Expired due to Term

• Current Assignee: Clorox Company
• Original Assignee: Clorox Company
• Inventors: Choy, Clement K.
• Primary Examiner(s): Lieberman, Paul
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US07/002,806
• Time in Patent Office: 413 Days
• Field of Search: 252/102, 252/174.13, 252/186.34, 252/186.35, 252/544, 252/525, 427/214, 427/220
• US Class Current: 252/186.34
• CPC Class Codes: C11D 17/0039 Coated compositions or coated components in the compositions, (micro)capsules
• CPC Class Codes: C11D 3/30 Amines; Substituted amines ; Quaternized amines
• CPC Class Codes: C11D 3/3955 Organic bleaching agents C11D3/3951 takes precedence

Abstract

Delayed-release hypohalite bleach compositions are provided which include encapsulates having a granular, hypohalite-releasing core and a coating delaying release of hypohalite ion and scavenging hypohalite ion when the encapsulates are exposed to an aqueous solution. The coating must include an amine compound with limited solubility in water. The core preferably includes a dihalodialkyl hydantoin and the coating an amine having a saturated hydrocarbon carbon of about 6 to about 24 carbon atoms.

Claims

1. A delayed-release hypohalite bleach comprising:

a halogen-substituted hydantoin capable of releasing hypohalite ion, the hydantoin forming a granular core;

a substantially water soluble inorganic salt coated on the granular core and being in an amount from about 0.5 wt. % about 50 wt % of the total composition; and

a substituted amine coated on the inorganic salt and having limited solubility in water at 25°

C. of from about 0.001 wt. % to about 5 wt. %, and being in an amount from about 0.5 wt. % to about 50 wt. % of the total composition the amine being substituted with a hydrocarbon moiety having at least 5 carbon atoms.

2. The compound of claim 1 wherein said halogen-substituted hydantoin is a compound of the structure ##STR3## wherein R₁ and R₂ are alkyl substituents and X and Y are halogen substituents.

3. The compound of claim 2, wherein R₁ is methyl, R₂ is methyl or ethyl, X is chlorine, and Y is chlorine or bromine.

4. The compound of claim 1 wherein the inorganic salt is sodium sulfate.

5. The compound of claim 1 wherein the substituted amine has the formula R₁ NHR₂, where R₁ is hydrogen or a hydrocarbon moiety of between 6 and 24 carbon atoms and R₂ includes a hydrocarbon moiety of between 6 and 24 carbon atoms.

6. The compound of claim 5 wherein the hydrocarbon moeity of R₂ includes at least one alkoxy group.

7. Dry delayed-release bleach encapsulates comprising:

a halogen-substituted isocyanurate or hydantoin forming a granular core of the encapsulates;

a substantially water-soluble inorganic salt coated on the granular core and being in an amount from about 0.5 wt. % to about 50 wt. % of the encapsulates; and

a substituted amine coated on the inorganic salt having a solubility in water at 25°

C. of from about 0.001 wt. % to about 5 wt. %, and being in an amount from about 0.5 wt. % to about 50 wt. % of the encapsulates.

8. The bleach encapsulates as in claim 7 wherein the substituted amine has the formula R₁ NHR₂, where R₁ is hydrogen or a hydrocarbon moiety of between about 6 and 24 carbon atoms and R₂ includes a hydrocarbon moiety of between about 6 and 24 carbon atoms.

9. The bleach encapsulates as in claim 7 wherein the fatty amine includes a saturated hydrocarbon chain having at least about 5 carbon atoms.

10. The bleach encapsulates as in claim 9 wherein the fatty amine includes dodecylamine, stearylamine, oleylamine, cocoamine, hexadecylamine, octadecylamine, the diamines thereof, or a long chain ethoxylated amine.