Amphiphilic monomer and hydrophobe associative composition containing a polymer of a water-soluble monomer and said amphiphilic monomer

• US 4,728,696 A
• Filed: 12/02/1985
• Issued: 03/01/1988
• Est. Priority Date: 12/02/1985
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Van Phung, Kien, Evani, Syamalarao
• Primary Examiner(s): HENDERSON JR, CHRISTOPHER A
• Application Number:
  US06/803,757
• Time in Patent Office: 820 Days
• Field of Search: 526/304, 526/287, 526/288, 526/289, 526/274, 526/277, 526/286, 526/318, 526/320, 526/307, 526/307.2
• US Class Current: 526/304
• CPC Class Codes: C09K 8/035 Organic additives
• CPC Class Codes: C09K 8/588 characterised by the use of specific polymers polymeric surfactants C09K8/584
• CPC Class Codes: C09K 8/68 containing organic compounds
• CPC Class Codes: C10M 173/02 not containing mineral or fatty oils
• CPC Class Codes: C10M 2201/02 Water
• CPC Class Codes: C10M 2217/022 containing monomers having an unsaturated radical bound to an amino group
• CPC Class Codes: C10M 2217/024 containing monomers having an unsaturated radical bound to an amido or imido group
• CPC Class Codes: C10M 2217/06 Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
• CPC Class Codes: C10M 2221/02 Macromolecular compounds obtained by reactions of monomers involving only carbon-to-carbon unsaturated bonds sulfurised polyolefins C10M2221/041
• CPC Class Codes: C10N 2040/08 Hydraulic fluids, e.g. brake-fluids
• CPC Class Codes: C10N 2050/01 Emulsions, colloids, or micelles
• CPC Class Codes: Y10S 507/922 Fracture fluid
• CPC Class Codes: Y10S 507/936 Flooding the formation

Abstract

The invention comprises a composition comprising at least one compound defined by the formula ##STR1## wherein R is hydrogen, C_1-4 alkyl or a group ##STR2## wherein G is a divalent hydrocarbyl-linking group and J, D, E and F are hereinafter defined; wherein J and E independently are divalent linking groups selected from ##STR3## wherein R'"'"' is hydrogen or C_1-4 alkyl; D is a divalent hydrocarbyl group which lends hydrophobicity to the compound; and F is a monovalent hydrocarbyl group which lends hydrophilicity to the compound. Such compositions are useful as comonomers with water-soluble monomers such as acrylamide and acrylic acid which form water-dispersible thickening agents which are resistant to shear degradation and heat and have a broad range of salt tolerance. Aqueous solutions thickened with such copolymers are useful in enhanced oil recovery processes as fluid mobility control agents, as fracturing fluids and drilling muds as well as hydraulic fluids and lubricants in many applications.

Claims

1. A composition comprising a polymerization product of

(A) one or more water-soluble monomers which are sufficiently water-soluble to form at least a 10 weight percent solution when dissolved in water and which undergo addition polymerization to form polymers which are water-soluble;

and

(B) at least one compound defined by the formula ##STR18## wherein R is hydrogen or C_1-4 alkyl, D is a C_8-12 divalent alkyl group and m is 2-10 wherein said polymerization product is aqueous-soluble.

2. The composition of claim 1 which has a viscosity significantly greater than a composition the same in all respects except that there is no inorganic salt in the solution.

3. The composition of claim 1 wherein the polymer contains sufficient hydrophobic moieties D to render the polymer hydrophobe associative in aqueous media.

4. The composition of claim 3 wherein the polymer has a weight average molecular weight of from about 800,000 to about 2.5 million as determined by intrinsic viscosity.

5. The composition of claim 4 wherein the water-soluble monomers are acrylamide, acrylic acid, salts of acrylic acid or mixtures thereof.

6. The composition of claim 5 wherein the water-soluble monomer is a mixture of acrylamide and acrylic acid or salts of acrylic acid with about 5 to about 30 mole percent acrylic acid or salts of acrylic acid in the mixture.

7. The composition of claim 6 wherein compound (B) comprises from about 0.1 to about 2 mole percent of the polymer.

8. The composition of claim 7 wherein R is hydrogen.

9. The composition of claim 1 wherein the polymerization product will not form gels as a result of precipitation by electrolytes over a wider range of electrolyte concentration than a second polymer identical to the polymerization product except that D is distal to the polymer backbone and --(CH₂ CH₂ O)_m CH₃ is proximal to the polymer backbone.

10. The composition of claim 1 wherein --(CH₂ CH₂ O)_m CH₃ is capable of hydrating in aqueous media and is capable of dehydrating with a temperature increase or an increase in electrolyte concentation.