Capacitive chemical sensor for detecting certain analytes, including hydrocarbons in a liquid medium

• US 4,728,882 A
• Filed: 04/01/1986
• Issued: 03/01/1988
• Est. Priority Date: 04/01/1986
• Status: Expired due to Term

• Current Assignee: Johns Hopkins University
• Original Assignee: Johns Hopkins University
• Inventors: Newman, Arnold L., Stanbro, William D.
• Primary Examiner(s): Eisenzopf, Reinhard J.
• Assistant Examiner(s): Mueller, Robert W.
• Application Number:
  US06/846,778
• Time in Patent Office: 700 Days
• Field of Search: 324/61 R, 324/61 P, 324/71.5, 204/1 T, 204/400
• US Class Current: 324/687
• CPC Class Codes: G01N 27/227 Sensors changing capacitance upon adsorption or absorption of fluid components, e.g. electrolyte-insulator-semiconductor sensors, MOS capacitors G01N27/225 takes precedence
• CPC Class Codes: G01N 33/1833 Oil in water

Abstract

An apparatus for detecting the concentration of certain analytes, including hydrocarbons, in a liquid medium, is disclosed. The apparatus uses a planar or "open" capacitor containing an active layer. In response to selected analyte in the liquid medium, the active layer causes capacitance to decrease with increasing analyte concentration. The capacitance decreases because higher dielectric water molecules are displaced from a region of the capacitor'"'"'s electric field. For certain hydrocarbon analytes having high Henry'"'"'s Law constants, the active layer causes bubbles to nucleate in the liquid medium on the surface of the active layer. Bubble formation displaces water molecules and decreases capacitance.

Claims

1. A device for sensing selected analyte in a liquid medium, comprising:

a concentrating and nucleating material adapted to be exposed to a liquid medium under test, for causing nucleated formation of bubbles in a liquid medium on the surface of said material in response to selected analyte contained in said liquid medium; and

,

a means, positioned in association with said concentrating and nucleating material, responsive to the formation of said bubbles.

2. The device of claim 1, wherein said responsive means is a capacitor and wherein said bubble formation causes a change in capacitance with increasing analyte concentration.

3. The device of claim 1, wherein said responsive means is a capacitor having at least one pair of spaced apart electrode elements, and wherein said bubble formation causes a decrease in capacitance with increasing analyte concentration.

4. The device of claim 1, wherein said concentrating and nucleating material is a material having an affinity to non-polar molecules, wherein non-polar analyte molecules having a high Henry'"'"'s Law constant tend to nucleate in the liquid medium on the surface of said material.

5. The device of claim 1, wherein said concentrating and nucleating material is selected from the group consisting of polymeric and lipid materials having a high affinity to non-polar molecules.

6. The device of claim 1, wherein said concentrating and nucleating material is selected from a group consisting of:

polyurethane, ethylene propylene rubber, styrene butadiene, polyacrylate, silicone rubber, and iso-butylene isoprene.

7. The device of claim 1, wherein said concentrating and nucleating material is silicone rubber.

8. The device of claim 3, wherein said electrode elements are made from doped semiconductor material.

9. The device of claim 3, wherein said electrode elements are made from electrically conductive material.

10. The device of claim 3, further comprising an electronic means, operably coupled to said capacitor, for measuring and displaying the change in capacitance.

11. A device for sensing a selected analyte in a liquid medium, comprising:

a capacitor having at least one pair of spaced apart electrode elements; and

,

a concentrating and nucleating material positioned in association with said electrode elements and adapted to be exposed to liquid medium under test, for causing nucleated formation of bubbles in a liquid medium on the surface of said concentrating and nucleating material, thereby decreasing capacitance with increasing analyte concentration.

12. The device of claim 11, wherein an electrically insulating material separates said at least one pair of electrode elements from said concentrating and nucleating material.

13. The device of claim 12, wherein said electrically insulating material forms a first layer coating at least a portion of said electrode elements and wherein said concentrating and nucleating material forms a second layer coating at least a portion of said first layer.

14. The device of claim 13, wherein said at least one pair of spaced apart electrical elements form a channel therebetween, and wherein said concentrating and nucleating material fills at least a portion of said channel.

15. The device of claim 11, wherein said concentrating and nucleating material is a material having an affinity to non-polar molecules, wherein non-polar analyte molecules having a high Henry'"'"'s Law constant tended to nucleate in the liquid material on the surface of said material.

16. The device of claim 11, wherein said concentrating and nucleating material is selected from the group consisting of polymeric and lipid materials having a high affinity to non-polar molecules.

17. The device of claim 11, wherein said concentrating and nucleating material is selected from a group consisting of:

polyurethane, ethylene propylene rubbe , styrene butadiene, polyacrylate, silicone rubber, and iso-butylene isoprene.

18. The device of claim 11, wherein said concentrating and nucleating material is silicone rubber.

19. The device of claim 11, wherein said electrode elements are made from doped semiconductor material.

20. The device of claim 11, wherein said electron elements are made from a electrically conductive material.

21. The device of claim 11, further comprising an electronic means operably coupled to said capacitor, for measuring and displaying the change in capacitance.

22. A device for sensing a hydrocarbon analyte in an aqueous selection, comprising:

a capacitor having at least one pair of spaced apart electrode elements; and

,

a layer of polymeric material positioned in association with said electrode elements and adapted to be exposed to an aqueous solution under test, for causing nucleated formation of bubbles in the aqueous solution on the surface of said layer in response to presence of hydrocarbon analytes in said aqueous solution, thereby decreasing capacitance with increasing concentration of said hydrocarbon analyte.

23. The device of claim 22, wherein said polymeric material is a material having a high affinity to hydrocarbon molecules.

24. The device of claim 23, wherein said polymeric material is a selected from a group consisting of:

polyurethane, ethylene propylene rubber, styrene butadiene, polyacrylate, silicone rubber, iso-butylene isoprene.

25. The device of claim 23, wherein said polymeric material is silicone rubber.

26. The device of claim 22, wherein said electrode elements are made from doped semiconductor material.

27. The device of claim 22, wherein said electron elements are made from electrically conductive material.

28. The device of claim 22, further comprising an electronic means operably coupled to said capacitor, for measuring and displaying the change in capacitance.

29. The device of claim 22, further comprising a means for periodically vibrating said polymeric layer thereby removing bubbles from the surface of said polymeric layer, so as to allow the sensor to make continuous hydrocarbon concentration measurements.

30. The device of claim 22, wherein said capacitor is positioned in a protective casing, and wherein a portion of said casing contains a porous membrane allowing liquid to penetrate said casing.

31. A differential sensor for sensing hydrocarbon analyte in a liquid medium comprising:

a first capacitor having at least one pair of spaced apart electrode elements;

a layer of polymeric material positioned in association with said electrode elements of said first capacitor and adapted to be exposed to a liquid medium under test, for causing nucleated formation of bubbles in the liquid medium on a surface of said layer in response to analyte hydrocarbon contained in the liquid medium;

a second capacitor having at least one pair of spaced apart electrode elements;

a layer of electrically insulating material coating said spaced apart electrode elements of said second capacitor and adapted to the exposed to said liquid medium under test; and

,

an electronic means, operably connected to said first and second capacitor for calculating the hydrocarbon concentration in said liquid medium.

32. The device of claim 31, wherein said polymeric material is selected from a group consisting of:

polyurethane, ethylene propylene rubber, styrene butadiene, polyacrylate, silicone rubber iso-butylene isoprene.

33. The device of claim 31, wherein said polymeric material is silicone rubber.

34. The device of claim 31, wherein an electrically insulating material separates said at least one pair of electrode elements of said first capacitor, from said polymeric layer.

35. The device of claim 31, further comprising a means for periodically vibrating said polymeric layer thereby removing bubbles from the surface of said polymeric layer so as to allow the sensor to make continuous analyte concentration measurements.

36. The device of claim 31, wherein said first and second capacitor are positioned in a protective casing, and wherein a portion of said casing contains a porous membrane allowing liquid to penetrate such casing.

37. A device for sensing a hydrocarbon analyte in a liquid medium comprising:

a substrate;

a plurality of spaced apart finger electrodes positioned on said substrate to form an open sensor capacitor;

a first electrically insulating layer coating said finger electrodes of said sensor capacitor; and

,

a second layer of polymeric material coating said first layer and at least partially filling a volume between said spaced apart finger electrodes and adapted to be exposed to the liquid medium under test, wherein said polymeric material has an affinity for non-polar hydrocarbon molecules, thereby causing a decrease in capacitance of said sensor capacitor with increasing hydrocarbon concentration.

38. The apparatus of claim 37, wherein said second layer is selected from the group consisting of:

polyurethane, ethylene propylene rubber, styrene butadiene, polyacrylate, silicone rubber and iso-butylene isoprene.

39. The device of claim 37, wherein said second layer is made from silicone rubber.

40. The device of claim 37, wherein said capacitor is positioned in a protective casing, and wherein the portion of said casing contains a porous membrane allowing liquid to penetrate said casing.

41. The device of claim 37, further comprising a liquid medium containing a selected salt concentration that fills at least a portion of said casing.

42. The device of claim 37, further comprising a means for periodically vibrating said second layer thereby removing bubbles from the surfacc of said second layer, so as to allow the device to make continuous analyte concentration measurements.

43. The device of claim 37, further comprising a reference capacitor having:

a substrate;

a plurality of spaced apart finger electrodes positioned on said substrate to form an open capacitor; and

, an electrically insulating layer coating said finger electrodes, and adapted to be exposed to the fluid medium under test.

44. The device of claim 43, further comprising an electronic means, operably connected to said sensor capacitor and said reference capacitor, for calculating the hydrocarbon concentration in the liquid medium under test.

45. The device of claim 44, wherein said sensor capacitor, said reference capacitor, and said electronic means, are integrated onto a single integrated circuit chip.