Gas sensor and method of using same

• US 4,729,824 A
• Filed: 10/14/1986
• Issued: 03/08/1988
• Est. Priority Date: 05/11/1982
• Status: Expired due to Term

• Current Assignee: Giner Electrochemical Systems, LLC (Ener1, Inc.)
• Original Assignee: Giner, Inc.
• Inventors: Giner, Jose D.
• Primary Examiner(s): NIEBLING, JOHN F
• Application Number:
  US06/918,652
• Time in Patent Office: 511 Days
• Field of Search: 204/1 T, 204/1 K, 204/1 P, 204/1 Y, 204/400, 204/402, 204/406, 204/407, 204/412, 204/431, 204/433, 204/1 F, 204/1 N, 204/415, 128/635
• US Class Current: 204/415
• CPC Class Codes: G01N 27/38 Cleaning of electrodes
• CPC Class Codes: G01N 27/4045 for gases other than oxygen
• CPC Class Codes: G01N 27/49 Systems involving the determination of the current at a single specific value, or small range of values, of applied voltage for producing selective measurement of one or more particular ionic species

Abstract

An electrochemical sensor capable of determining the partial pressure of various gases (e.g., CO, CO₂, H₂ S, alcohol vapors, hydrocarbons, NO_x, etc.) and, optionally, substantially concurrently, but independently, oxygen content in gases and liquids. The sensor measures the amount of chemisorbent species formed either electrochemically by partial reduction (such as "Reduced-CO₂ " in the case of CO₂) or partial oxidation (in the case of alcohol) or non-electrochemically via specific adsorption (in the case of CO and hydrocarbons) on platinum or other metals. The charge required to oxidize this chemisorbed species is proportional to the amount of adsorbate on the electrode surface which is made a reproducible and reliable function of the partial pressure of the gas to be measured. By the proper selection of the sensor construction and electrical parameters, high sensitivity, fast response time, and high selectivity can be obtained.

Claims

1. A system for determining the concentration of carbon dioxide in a subject fluid comprising a sensor comprising at least a working electrode which will reductively adsorb carbon dioxide, a counter electrode, and means whereby said subject fluid containing carbon dioxide contacts said working electrode, said electrodes of said sensor being connected to a current or potential controlling device which, in turn, is connected to a current integrator, whereby carbon dioxide reductively adsorbed on said working electrode of said sensor is measured.

2. The system of claim 1 wherein said sensor is connected to a potentiostat which is, in turn, connected to a potential wave form generator and a current integrator.

3. The system of claim 2 wherein said sensor includes a reference electrode.

4. The system of claim 1 wherein said sensor is connected to a galvanostat and potentiostat through a switch, and said potentiostat is connected to an applied potential wave form generator.

5. The sensor of claim 1 wherein said sensor is connected to a galvanostat and an integrator through a switch, and said sensor includes a reference electrode which is directly connected to said integrator.

6. Apparatus for sensing and measuring a gas comprising:

7. (1) at least a working electrode, a counter electrode, a reference electrode, and an electrolyte inside of an enclosure and in contact with an external medium by means of a hydrophobic membrance;

11. The gas sensor of claim 7 which also includes a reference electrode in contact with said electrolyte.

12. The gas sensor of claim 7 wherein the hydrophobic membrance contains a fluorocarbon polymer.

13. The gas sensor of claim 7 wherein the hydrophobic membrane contains a polymer of a silicone.

14. The gas sensor of claim 7 wherein the hydrophobic membrane contains polypropylene.

15. The gas sensor of claim 7 wherein the working electrode includes a metal of the platinum group or gold.

16. The gas sensor of claim 12 wherein the membrane is a fluorocarbon polymer.

17. The gas sensor of claim 13 wherein the electrolyte is a substantially free electrolyte.

18. The gas sensor of claim 13 wherein electrolyte is impregnated into a matrix, and said working electrode and counter electrode are in contact with said matrix.

21. The gas sensor of claim 7 wherein said hydrophobic membrane is a part of said working electrode.

8. (2) means to regulate the potential of the working electrode so as to produce repeatable temporal function of potential with a total period of less then five minutes, said function containing at least a potential region for formations of a gas-derived adsorbate and a potential region for measurement of the adsorbed species;

and

19. The gas sensor of claim 8 wherein the reference electrode is remotely spaced from said working electrode and counter electrode, and in liquid contact with said electrolyte-impregnated matrix through an electrolyte reservoir containing electrolyte.

20. The gas sensor of claim 8 wherein electrolyte is retained in a matrix and each of said working electrode, counter electrode, and reference electrode is in contact with said matrix, and said hydrophobic membrane is in contact with the opposite surface of said matrix.

9. (3) means to measure amount of adsorbate.

10. A gas sensor for determining the concentration of gases in a subject fluid comprising at least a working electrode which will adsorb a gas, a counter electrode, an electrolyte in contact with each of said electrodes, a support structure, and a hydrophobic membrane;

said support structure and hydrophobid membrane forming an enclosure within which said electrolyte is contained and separated from said subject fluid;

said hydrophobic membrane being constructed and arranged to permit passage of gases from said subject fluid to said electrolyte for contact with said working electrode; and

means for controlling the electrical potential or current of said working electrode including electrical means to form on said working electrode chemisorbed species originating from said gases, and electrical means to measure the amount of said chemisorbed species.

22. A gas sensor for determining the concentration of gases in a subject fluid comprising at least a working electrode which will adsorb a gas, a counter electrode, an electrolyte in contact with each of said electrodes;

and means for controlling the electrical potential or current of said working electrode including electrical means to form on said working electrode chemisorbed species originating from said gases, and electrical means to measure said chemisorbed species.