Double layer capacitors with polymeric electrolyte

• US 4,730,239 A
• Filed: 10/29/1986
• Issued: 03/08/1988
• Est. Priority Date: 10/29/1986
• Status: Expired due to Fees

• Current Assignee: Stemcor Corporation
• Original Assignee: Stemcor Corporation
• Inventors: Bennett, Phillip D., Currie, John C., DiFranco, Linda F.
• Primary Examiner(s): GRIFFIN, DONALD
• Application Number:
  US06/924,525
• Time in Patent Office: 496 Days
• Field of Search: 29/570, 361/433, 361/323
• US Class Current: 361/502
• CPC Class Codes: H01G 11/24 characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
• CPC Class Codes: H01G 11/56 Solid electrolytes, e.g. gels; Additives therein
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors

Abstract

A solid state double layer capacitor includes an organic electrolyte doped with a soluble salt to render the electrolyte ionically conductive.

Claims

1. A double layer capacitor comprising a pair of high surface area electrodes each having an electronically conductive surface on one side thereof, said electrodes comprising carbon in particulate, fiber or cloth form, the high surface area electrodes being impregnated with a multiphasic polymeric electrolyte, said multiphasic electrolyte comprising polymer material doped with a soluble salt to confer ionic conductivity and electronically non-conductive means separating said electrodes to prevent short-circuiting therebetween.

2. The double layer capacitor of claim 1 wherein said polymer material comprises one or more polyethers.

3. The double layer capacitor of claim 2 wherein said polymer material comprises polyethylene oxide.

4. The double layer capacitor of claim 3 wherein said polymer material comprises a plasticizer.

5. The double layer capacitor of claim 4 wherein said plasticizer is polyethylene glycol.

6. The double layer capacitor of claim 5 wherein said polyethylene glycol is present in an amount of up to about 0.5 mole fraction of said polymer material.

7. The double layer capacitor of claim 6 wherein the high surface area electrode comprises carbon cloth.

8. The double layer capacitor of claim 7 wherein said soluble salt is lithium perchlorate and is present in an amount sufficient to provide an oxygen to lithium ratio of 9:

1.

9. The double layer capacitor of claim 8 wherein said electronically conductive surface consists of a metallized region on said electrode.

10. The double layer capacitor of claim 8 wherein said electronically conductive surface is provided by a carbon-loaded polymer element in electrical contact with said electrode.

11. The double layer capacitor of claim 6 wherein said soluble salt is selected from the group consisting of (C₂ H₅)₄ NBF₄, (C₂ H₅)₄ NClO₄, LiBF₄ and LiClO₄.

12. The double layer capacitor of claim 5 wherein said electronically non-conductive means is a non-conductive polymer element interposed between said electrodes.

13. The double layer capacitor of claim 5 wherein said electronically non-conductive means is provided by said multiphasic polymeric electrolyte which is present in sufficient thickness on the surface of one or both said electrodes to prevent carbon-to-carbon contact.

14. The double layer capacitor of claim 2 wherein said polymer material comprises polypropylene oxide.

15. The double layer capacitor of claim 14 wherein said polymer material comprises a plasticizer.

16. The double layer capacitor of claim 15 wherein said plasticizer is polyethylene glycol.

17. The double layer capacitor of claim 16 wherein the high surface area electrode comprises carbon in the form of woven or unwoven cloth.

18. The double layer capacitor of claim 17 wherein said soluble salt is lithium perchlorate and is present in an amount sufficient to provide an oxygen to lithium ratio of 9:

1.

19. The double layer capacitor of claim 18 wherein said electronically conductive surface consists of a metallized region on said electrode.

20. The double layer capacitor of claim 18 wherein said electronically conductive surface is provided by a carbon-loaded polymer element in electrical contact with said electrode.

21. The double layer capacitor of claim 18 wherein said electronically non-conductive means is a non-conductive polymer element interposed between said electrodes.

22. The double layer capacitor of claim 18 wherein said electronically non-conductive means is provided by said multiphasic polymeric electrolyte which is present in sufficient thickness on the surface of one or both said electrodes to prevent carbon-to-carbon contact.

23. The double layer capacitor of claim 16 wherein said soluble salt is selected from the group consisting of (C₂ H₅)₄ NBF₄, (C₂ H₅)₄ NClO₄, LiBF₄, and LiClO₄.

24. The double layer capacitor of claim 1 wherein said soluble salt is selected from the group consisting of (C₂ H₅)₄ NBF₄, (C₂ H₅)₄ NClO₄, LiBF₄ and LiClO₄.