Hydrometallurigcal process for producing finely divided spherical precious metal based powders

• US 4,731,110 A
• Filed: 03/16/1987
• Issued: 03/15/1988
• Est. Priority Date: 03/16/1987
• Status: Expired due to Fees

• Current Assignee: GTE Products Corporation
• Original Assignee: GTE Products Corporation
• Inventors: Johnson, Walter A., Kopatz, Nelson E., Ritsko, Joseph E.
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US07/026,222
• Time in Patent Office: 365 Days
• Field of Search: 75/0.5 A, 75/0.5 B, 75/0.5 C
• US Class Current: 75/342
• CPC Class Codes: B22F 1/065 Spherical particles
• CPC Class Codes: B22F 9/22 using gaseous reductors

Abstract

A process for producing finely divided spherical precious metal based powders comprises forming an aqueous solution containing a source of at least one precious metal value forming a solid reducible precious metal material from the solution, reducing the solid material to precious metal powder particles, subjecting the precious metal based particles to a high temperature zone to melt at least a portion of the precious metal based powder particles and cooling the molten material to form essentially spherical precious metal based alloy particles.

Claims

1. A process comprising:

(a) forming an aqueous solution containing at least one precious metal value,

(b) forming a solid reducible material selected from the group consisting of precious metal salts, precious metal oxides and mixtures thereof,

(c) reducing said solid material to form precious metal based particles,

(d) entraining at least a portion of said precious metal particles in a carrier gas,

(e) feeding said entrained particles and said carrier gas into a high temperature zone and maintaining said particles in said zone for a sufficient time to melt at least about 50% by weight of said particles, and to form droplets therefrom and

(f) cooling said droplets to form precious metals based metallic particles having essentially a spherical shape and a majority of said particles having a size less than 20 micrometers.

2. A process according to claim 1 wherein said solution contains a water soluble acid.

3. A process according to claim 2 wherein said water soluble acid is hydrochloric acid.

4. A process according to claim 2 wherein said solid reducible material is formed by the evaporation of sufficient water to form a residue.

5. A process according to claim 2 wherein said solid reducible material is formed by adjusting the pH to form the solid which is separated from the resulting aqueous phase.

6. A process according to claim 1 wherein the material from step (b) is subjected to a particle size reduction step prior to the chemical reduction step (c).

7. A process according to claim 1 wherein the powder particles from step (c) are subjected to a particle size reduction step prior to the entraining step (d).

8. A process according to claim 1 wherein said high temperature zone is created by a plasma torch.

9. A process according to claim 1 wherein said carrier gas is an inert gas.

10. A process according to claim 1 wherein essentially all of said precious metal particles are melted.

11. A process according to claim 1 wherein at least 50% of said particles have a size less than about 3 micrometers.

12. A process according to claim 1 wherein said precious metal is selected from the group consisting of silver, gold, platinum and palladium.