Hydrometallurical process for producing finely divided spherical refractory metal based powders

• US 4,731,111 A
• Filed: 03/16/1987
• Issued: 03/15/1988
• Est. Priority Date: 03/16/1987
• Status: Expired due to Fees

• Current Assignee: GTE Products Corporation (Ams-Osram AG)
• Original Assignee: GTE Products Corporation (Ams-Osram AG)
• Inventors: Johnson, Walter A., Kopatz, Nelson E., Ritsko, Joseph E.
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US07/026,312
• Time in Patent Office: 365 Days
• Field of Search: 75/0.5 AB, 75/0.5 BB, 75/0.5 AC, 75/0.5 BC, 75/251, 75/0.5 B, 75/0.5 BA
• US Class Current: 75/342
• CPC Class Codes: B22F 1/065 Spherical particles

Abstract

A process for producing finely divided spherical refractory metal based powders comprises forming an aqueous solution containing at least one refractory metal, forming a solid reducible refractory metal based material containing a compound selected from the group consisting of refractory metal salts, refractory metal oxides, hydroxides and mixtures thereof, reducing the solid material to refractory metal based powder particles, subjecting the refractory based metal particles to a high temperature zone to melt a portion of the particles and cooling the molten material to form essentially spherical refractory metal based powder particles.

Claims

1. A process comprising:

(a) forming an aqueous solution containing at least one refractory metal,

(b) forming a solid reducible material having a major portion selected from the group consisting of reducible refractory metal salts, oxides and mixtures thereof,

(c) reducing said solid reducible material to form refractory metal based powder particles,

(d) entraining at least a portion of said refractory metal particles in a carrier gas,

(e) feeding said entrained particles and said carrier gas into a high temperature zone and maintaining said particles in said zone for a sufficient time to melt at least about 50% by weight of said particles, and to form droplets therefrom and

(f) cooling said droplets to form refractory metal based metallic particles having essentially a spherical shape and a majority of said particle having a size less than 20 micrometers.

2. A process according to claim 1 wherein said solution contains a water soluble acid.

3. A process according to claim 2 wherein said mineral acid is selected from the group consisting of hydrochloric, sulfuric and nitric acids.

4. A process according to claim 3 wherein said mineral acid is hydrochloric acid.

5. A process according to claim 3 wherein said solid reducible material is formed by evaporation.

6. A process according to claim 3 wherein said solid reucible material is formed by adjusting the pH to form the solid which is separated from the resulting aqueous phase.

7. A process according to claim 3 wherein said high temperature zone is created by a plasma touch.

8. A process according to claim 3 wherein said carrier gas is an inert gas.

9. A process according to claim 3 wherein essentially all of said metallic particles are melted.

10. A powdered material consisting essentially of spherical particles of a refractory metal based material, said powdered material being essentially free of elliptical shaped material and essentially free of elongated particles having rounded ends, said powdered material having an average particle size of less than about 20 microns.

11. A powdered material of claim 10 wherein said refractory metal based material is a metal selected from the group consisting of tungsten, molybdenum, niobium, tantalum, and rhenium.

12. A powdered material of claim 10 wherein said refractory metal based material is an alloy selected from the group consisting of tungsten alloys, molybdenum alloys, niobium alloys, tantalum alloys, and rhenium alloys.

13. A powdered material of claim 10 wherein said refractory metal based material is selected from the group consisting of tungsten metal, tungsten heavy alloys, molybdenum alloys containing of titanium, zirconium, and hafnium, tungsten alloyed with rhenium, and molybdenum alloyed with rhenium.

14. A powdered tungsten based material consisting essentially of spherical tungsten based powder, particles of an average size of less than about 20 microns.