Antiperspirant and/or deodorant stick having suspended therein fragrance-containing polymeric particles

• US 4,731,243 A
• Filed: 02/14/1986
• Issued: 03/15/1988
• Est. Priority Date: 10/19/1984
• Status: Expired due to Term

• Current Assignee: International Flavors & Fragrances Incorporated
• Original Assignee: International Flavors & Fragrances Incorporated
• Inventors: Suran, Valerie M., Cincotta, David E., Lindauer, Jerome I., Reich, Sharon L., Trizzino, Rose L.
• Primary Examiner(s): Echols, P. W.
• Assistant Examiner(s): Gorski, Joseph M.
• Application Number:
  US06/829,484
• Time in Patent Office: 760 Days
• Field of Search: 241/3, 241/23, 241/DIG. 37, 252/522 A, 264/178 R, 424/DIG. 5, 424/65
• US Class Current: 424/65
• CPC Class Codes: A61K 2800/56 Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms
• CPC Class Codes: A61K 8/0229 Sticks
• CPC Class Codes: A61K 8/0241 Containing particulates characterized by their shape and/or structure see also A61K8/04, A61K8/11, and A61K8/14, further aspects are classified in A61K2800/40 and subcodes
• CPC Class Codes: A61Q 15/00 Anti-perspirants or body deodorants deodorisation of air A61L9/00
• CPC Class Codes: B29B 13/10 by grinding, e.g. by triturating; by sieving; by filtering
• CPC Class Codes: B29B 9/06 in the form of filamentary material, e.g. combined with extrusion
• CPC Class Codes: B29K 2023/00 Use of polyalkenes or derivatives thereof as moulding material
• CPC Class Codes: B29K 2105/04 cellular or porous
• CPC Class Codes: B29L 2031/718 Cosmetic equipment, e.g. hair dressing, shaving equipment brushes B29L2031/42, combs B29L2021/005
• CPC Class Codes: C08J 3/005 Processes for mixing polymers
• CPC Class Codes: Y10S 424/05 Stick

Abstract

Described are deodorant and/or antiperspirant sticks which contain suspended therein fragrance-containing polymeric pellets containing 1 to 80% fragrance, the polymeric pellets produced by means of cryogenically grinding an extruded mixture of perfume composition and polymer.

Claims

1. A deodorant or antiperspirant solid suspension comprising a deodorant or antiperspirant-containing suspension agent selected from the group consisting of:

(i) hydrocarbon wax; and

(ii) sodium stearate

and suspended therein perfume-containing thermoplastic polymer particles having an average particle size of between 50 and 225 microns, said thermoplastic polymer being selected from the group consisting of;

(1) low density polyethylene;

(2) high density polyethylene;

(3) co-extruded high molecular high density polyethylene and low density polyethylene;

(4) polypropylene;

(5) a co-polymer of ethylene and vinyl acetate;

(6) polyvinyl chloride;

(7) a copolymer of ethylene and ethyl acrylate;

(8) a copolymer of ethylene and methyl acrylate;

(9) a copolymer of ethylene and butyl acrylate;

(10) a copolymer of ethylene and acrylic acid; and

(11) the hydrolyzed co-polymer of ethylene and vinyl acetate

said polymeric particles containing from 1 up to about 80% by weight of perfume, said polymeric particles being produced according to the process comprising the steps of;

(i) co-extruding the thermoplastic polymer with from about 1% up to about 80% of said perfume thereby forming an extrudate with the polymer feed rate range being from 80 up to 300 pounds per hour and the feed rate range of perfume being between 1.01% and 400% of the feed rate range of thermoplastic polymer;

(ii) quick-chilling said extrudate by contacting said extrudate with an inert cooling liquid at a temperature of from about 5°

C. up to about 60°

C. whereby extrudate pellets are formed;

(iii) cryogenically grinding the resulting extrudate pellets to a particle size of from about 10 up to about 500 microns and an average particle size of between 50 and 225 microns thereby forming cryogenically ground extrudate pellets;

(iv) intimately admixing the resulting cryogenically ground extrudate pellets with said deodorant-containing suspension composition or said antiperspirant-containing suspension composition whereby a liquid suspension is formed; and

(v) forming the thus created liquid suspension into deodorant or antiperspirant sticks.

the weight percent of cryogenically ground polymer in the resulting suspension being from about 2% up to about 8%, the resulting polymeric particles in said suspension being capable of controlled release of said perfume therefrom into and through the resulting deodorant sticks or anti-perspirant sticks.

2. The product defined according to claim 1 wherein in the process, the step (iii) of cryogenically grinding includes the step of direct treatment of the extrudate pellets with liquid nitrogen.

3. The product of claim 2 wherein the thermoplastic polymer is high density polyethylene.

4. The product of claim 1 wherein in the process, the process includes adding a gaseous or liquid blowing agent during the step (i) of co-extruding.

5. The product of claim 4 wherein the thermoplastic polymer is high density polyethylene.

6. The product of claim 1 wherein the thermoplastic polymer is high density polyethylene.