Abrasion resistant polyurethane coatings for rigid plastics

• US 4,731,289 A
• Filed: 11/24/1986
• Issued: 03/15/1988
• Est. Priority Date: 02/14/1980
• Status: Expired due to Term

• Current Assignee: PPG Industries Incorporated (Nouryon BV)
• Original Assignee: PPG Industries Incorporated (Nouryon BV)
• Inventors: Coleman, Charles R.
• Primary Examiner(s): Ives, P. C.
• Application Number:
  US06/935,107
• Time in Patent Office: 477 Days
• Field of Search: 428/334, 428/412, 428/423.1, 428/423.3, 428/424.4, 428/423.7
• US Class Current: 428/334
• CPC Class Codes: C08G 18/08 Processes
• CPC Class Codes: C08G 18/4277 Caprolactone and/or substituted caprolactone
• CPC Class Codes: C08G 18/75 cycloaliphatic
• CPC Class Codes: C08J 2475/00 Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
• CPC Class Codes: C08J 7/0427 with only one layer of a composition containing a polymer binder with more layers C08J7/042
• CPC Class Codes: C08J 7/046 Forming abrasion-resistant coatings; Forming surface-hardening coatings
• CPC Class Codes: Y10T 428/263 Coating layer not in excess of 5 mils thick or equivalent
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31554 Next to second layer of polyamidoester
• CPC Class Codes: Y10T 428/31565 Next to polyester [polyethylene terephthalate, etc.]
• CPC Class Codes: Y10T 428/31576 Ester monomer type [polyvinylacetate, etc.]

Abstract

A method is disclosed for casting a colorless, single phase liquid reaction mixture comprising an aliphatic diisocyanate and a polyester polyol against a rigid transparent plastic and curing at a sufficiently rapid rate at temperatures of about 175° to 275° F. (about 79° to 135° C.) to form a relatively soft, resilient, abrasion resistant branched polyurethane coating without warpage or deterioration of the rigid plastic. The polyesterurethane coatings disclosed are characterized by durometer values at 70° F. between Shore A 50 and Shore D 80, and molecular weights between branch points between 1000 and 13,000.

Claims

1. An abrasion resistant branched polyurethane coated rigid plastic transparency comprising:

a. a transparent rigid plastic substrate; and

b. an abrasion resistant transparent branched polyurethane coating at least 5 mils thick formed from the reaction of an aliphatic diisocyanate and a polyol comprising a polyester polyol, said polyurethane having a durometer value at 70°

F. between Shore A 50 and Shore D 80 and said polyol comprising sufficient triol to produce a branched polyurethane with a molecular weight between branch points between 1000 and 13,000

2. An abrasion resistant polyurethane coated plastic transparency according to claim 1, wherein the rigid transparent substrate is selected from the group consisting of polycarbonate, acrylic and polyurethane polymers having a durometer value at 70°

F. of at least Shore D 80.

3. A plastic transparency according to claim 2, wherein the coating is formed from a polyol selected from the group consisting of polyester diols and triols, polycarbonate diols and triols, monomeric polyols and mixtures thereof.

4. A plastic transparency according to claim 3, wherein the polyol is selected from the group consisting of polycaprolactone diols and triols of molecular weight 300 to 2000, polybutylene and polyhexylene adipate diols, polycarbonate polyols of molecular weight 100 to 2000, butanediol, 1,6 hexanediol, 1,12 dodecanediol, cyclohexanedimethanol, trimethylolpropane and mixtures thereof.

5. A plastic transparency according to claim 4, wherein the coated surface, after 300 passes on a Bayer Abrader, exhibits less than 25 percent haze.

6. A plastic transparency according to claim 5, wherein the coated surface has a durometer value of at least Shore D 60 and exhibits less than 10 percent haze.

7. A plastic transparency according to claim 5, wherein the coated surface has a durometer value of about Shore A 50 to Shore A 80 and exhibits less than 2 percent haze.

8. A plastic transparency according to claim 5, wherein a first surface of the rigid plastic substrate is coated with an abrasion resistant polyester urethane having a durometer value of at least Shore D 60 and less than 10 percent haze, and a second surface of the rigid transparent substrate is coated with an abrasion resistant polyester urethane having a durometer value of about Shore A 50 to Shore A 80 and less than 2 percent haze.

9. A plastic transparency according to claim 8, wherein the coated substrate is installed in a vehicle with the first coated surface oriented toward the exterior of the vehicle.