Dephlegmator process for nitrogen rejection from natural gas

• US 4,732,598 A
• Filed: 11/10/1986
• Issued: 03/22/1988
• Est. Priority Date: 11/10/1986
• Status: Expired due to Fees

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Davis, Ruth A., Rowles, Howard C.
• Primary Examiner(s): Warner, Steven E.
• Application Number:
  US06/929,045
• Time in Patent Office: 498 Days
• Field of Search: 62/9, 62/11, 62/23, 62/24, 62/27-29, 62/31, 62/32, 62/36, 62/38, 62/39, 62/41, 62/42, 62/44
• US Class Current: 62/621
• CPC Class Codes: C07C 7/005 Processes comprising at least two steps in series
• CPC Class Codes: C07C 9/04 Methane production by treatment of sewage C02F11/04; natural gas, synthetic natural gas C10L3/06
• CPC Class Codes: F25J 2200/04 in a dual pressure main column system
• CPC Class Codes: F25J 2200/80 using integrated mass and heat exchange, i.e. non-adiabatic rectification in a reflux exchanger or dephlegmator
• CPC Class Codes: F25J 2235/60 the fluid being (a mixture of) hydrocarbons
• CPC Class Codes: F25J 2240/12 the fluid being nitrogen
• CPC Class Codes: F25J 2270/04 Internal refrigeration with work-producing gas expansion loop
• CPC Class Codes: F25J 3/0209 Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more
• CPC Class Codes: F25J 3/0257 separation of nitrogen from air F25J3/04, production of nitrogen in general C01B21/00
• CPC Class Codes: Y10S 62/927 Natural gas from nitrogen

Abstract

A process is disclosed for the rejection of nitrogen from natural gas with the optional recovery of natural gas liquids. The process of the present invention employs a dephlegmator which provides a high purity nitrogen reflux for a low pressure distillation column and provides subcooling of the feed and reflux to the low pressure column and reboiling of the low pressure column. The dephlegmator of the present invention combines the high pressure column and three heat exchangers of a conventional double column process into a single, compact unit, with corresponding reductions in interconnecting piping and capital investment.

Claims

1. A process for the rejection of nitrogen from a pressurized natural gas feed stream containing nitrogen by cryogenic distillation comprising the steps of:

(a) cooling the pressurized natural gas feed stream containing nitrogen whereby said stream partially condenses;

(b) separating said feed stream into a liquid phase and a gaseous phase in a separator;

(c) cooling said gaseous phase in a dephlegmator whereby said gaseous phase is partially condensed and rectified and whereby gravity separates said partially condensed gaseous phase into a methane enriched condensed portion and a nitrogen enriched non-condensed portion;

(d) returning said methane enriched condensed portion to said separator in step (b) whereby said methane enriched condensed portion becomes part of said liquid phase;

(e) cooling, condensing and expanding said nitrogen enriched non-condensed portion and feeding said cooled, condensed, expanded, nitrogen enriched portion to a low pressure distillation column as reflux;

(f) subcooling the liquid phase of step (d) in said dephlegmator, expanding said subcooled liquid phase, and feeding said expanded subcooled liquid phase to an intermediate location of said low pressure distillation column;

(g) removing a first portion of a bottoms liquid from the bottom of said low pressure distillation column, at least partially vaporizing said first portion in said dephlegmator thereby providing refrigeration duty to said dephlegmator, and returning said partially vaporized first portion to the bottom of the low pressure distillation column thereby providing reboiler duty to said low pressure distillation column;

(h) removing a second portion of the bottoms liquid from the bottom of said low pressure distillation column, pumping said second portion to an elevated pressure, warming said second portion thereby recovering refrigeration value from said second portion, and removing said pumped, warmed, second portion from the process as a methane product; and

(i) removing an overhead vapor from the top of said low pressure distillation column, warming said overhead vapor thereby recovering refrigeration value from said overhead, and removing said warmed overhead vapor from the process as a nitrogen product.

2. The process according to claim 1 which further comprises the step of recovering natural gas liquids from said pressurized natural gas feed stream prior to cooling said feed in step (a).

3. The process according to claim 1 which further comprises subcooling said cooled, condensed nitrogen enriched portion of step (e) prior to expanding.

4. The process according to claim 1 which further comprises expanding said cooled pressurized natural gas feed stream of step (a).

5. The process according to claim 4 which further comprises the step of recovering natural gas liquids from said pressurized natural gas feed stream prior to cooling and expanding said feed in step (a).

6. The process according to claim 5 which further comprises subcooling said cooled, condensed nitrogen enriched portion of step (e) prior to expanding.

7. A process for the rejection of nitrogen from a pressurized natural gas feed stream containing nitrogen by cryogenic distillation comprising the steps of:

(a) cooling the pressurized natural gas feed stream containing nitrogen whereby said stream partially condenses;

(b) separating said feed stream into a liquid phase and a gaseous phase in a separator;

(c) cooling said gaseous phase in a dephlegmator whereby said gaseous phase is partially condensed and rectified and whereby gravity separates said partially condensed gaseous phase into a methane enriched condensed portion and a nitrogen enriched non-condensed portion;

(d) returning said methane enriched condensed portion to said separator in step (b) whereby said methane enriched condensed portion becomes part of said liquid phase;

(e) separating said nitrogen enriched non-condensed portion of step (c) into a first substream and a second substream;

(f) cooling, condensing and expanding said first substream and feeding said cooled, condensed, expanded, first substream to a low pressure distillation column as reflux;

(g) expanding said second substream to provide refrigeration;

(h) subcooling the liquid phase of step (d) in said dephlegmator, expanding said subcooled liquid phase, and feeding said expanded subcooled liquid phase to an intermediate location of said low pressure distillation column;

(i) removing a first portion of a bottoms liquid from the bottom of said low pressure distillation column, at least partially vaporizing said first portion in said dephlegmator thereby providing refrigeration duty to said dephlegmator, and returning said partially vaporized first portion to the bottom of the low pressure distillation column thereby providing reboiler duty to said low pressure distillation column;

(j) removing a second portion of the bottoms liquid from the bottom of said low pressure distillation column, pumping said second portion to an elevated pressure, warming said second portion thereby recovering refrigeration value from said second portion, and removing said pumped, warmed, second portion from the process as a methane product; and

(k) removing an overhead vapor from the top of said low pressure distillation column, warming said overhead vapor thereby recovering refrigeration value from said overhead, and removing said warmed overhaad vapor from the process as a nitrogen product.

8. The process according to claim 7 which further comprises expanding said cooled pressurized natural gas feed stream of step (a).

9. The process according to claim 7 which further comprises combining said second substream from step (g) with said overhead vapor of step (k) prior to warming said overhead vapor to recover refrigeration.

10. The process according to claim 7 which further comprises subcooling said cooled, condensed first substream of step (f) prior to expanding.

11. The process according to claim 7 which further comprises the step of recovering natural gas liquids from said pressurized natural gas feed stream prior to cooling said feed in step (a).

12. The process according to claim 11 which further comprises combining said second substream from step (g) with said overhead vapor of step (k) prior to warming said overhead vapor to recover refrigeration.

13. The process according to claim 11 which further comprises subcooling said cooled, condensed first substream of step (f) prior to expanding.

14. The process according to claim 11 which further comprises expanding said cooled pressurized natural gas feed stream of step (a).

15. The process according to claim 14 which further comprises subcooling said cooled, condensed first substream of step (f) prior to expanding.

16. The process according to claim 14 which further comprises combining said second substream from step (g) with said overhead vapor of step (k) prior to warming said overhead vapor to recover refrigeration.

17. The process according to claim 16 which further comprises subcooling said cooled, condensed first substream of step (f) prior to expanding.