Process for the production of premium grade needle coke from a hydrotreated SRC material

• US 4,737,261 A
• Filed: 10/05/1984
• Issued: 04/12/1988
• Est. Priority Date: 10/05/1984
• Status: Expired due to Fees

• Current Assignee: International Coal Refining Co.
• Original Assignee: International Coal Refining Co.
• Inventors: Hoover, David
• Primary Examiner(s): Sneed, Helen M. S.
• Assistant Examiner(s): MCFARLANE, ANTHONY R
• Application Number:
  US06/657,862
• Time in Patent Office: 1,285 Days
• Field of Search: 208/89, 208/95, 208/50, 208/58, 208/8 LE, 208/10, 208/254 H, 208/216 R, 208/217, 208/131
• US Class Current: 208/50
• CPC Class Codes: C10B 55/00 Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material cracking oils C10G

Abstract

The invention disclosed in this application is a process for the production of a premium grade needle coke which is historically feedstock dependent. The selected feedstock for this process is a hydrotreated SRC material (solvent refined coal) which produces a premium grade needle coke having a low ash, low sulfur and low solids content. The hydrotreating of the SRC material, before conversion to the premium grade needle coke, changes the molecular structure of the product by putting hydrogen therein and results in a different arrangement of the aromatic molecules in the resultant premium grade needle coke.

Claims

1. A process for the production of premium grade needle coke which consists essentially of the steps of providing a solvent refined coal feed, catalytically hydrocracking said solvent refined coal in the presence of a hydrocracking catalyst and hydrogen at a temperature in the range of from 500°

to 900°

F. and at a pressure of from 100 psig to 2000 psig, coking the catalytically hydrocracked solvent refined coal at a temperature of from 850°

to 950°

F. and a pressure of from 1 atmosphere to 100 psig to produce green needle coke, and calcining said green needle coke at a temperature of from 1500°

to 2500°

F. to produce premium grade needle coke.

2. The process of claim 1 further characterized in that the sulfur content of the catalytically hydrocracted solvent refining coal is less than 0.5 wt %.

3. The process of claim 1 wherein said catalytically hydrocracted solvent refined coal is indirectly heat exchanged prior to coking to a temperature of 850°

to 950°

F.

4. The process of claim 1 further characterized in that the coking time is from 1/4 hour to 6 hours.

5. The process of claim 1 wherein said calcining time is from 1/4 hour to 5 hours.

6. The process of claim 1 wherein said catalytically hydrocracted SRC feed material possesses a molecular weight of from 1,000 to 30,000.

7. The process of claim 1 wherein said needle coke and said catalytically hydrocracted SRC material possess a sulfur content of less than 0.5 percent sulfur, an ash content of less than 0.3 wt % ash and a solid residue content of less than 0.5 wt % solid particles.

8. The process of claim 1 wherein said coking occurs in a swing-bed coking system having at least two coker beds.

9. A needle coke product produced by the process of claim 1.

10. The product of claim 9 wherein said needle coke has an ash content of less than 0.2 wt %, a sulfur content of less than 0.5 wt % sulfure and a residual content less than 1.0 wt % solids.