Polyalkyloxazoline-reinforced acrylic pressure-sensitive adhesive composition

• US 4,737,410 A
• Filed: 11/28/1986
• Issued: 04/12/1988
• Est. Priority Date: 11/28/1986
• Status: Expired due to Term

• Current Assignee: 3M Company
• Original Assignee: 3M Company
• Inventors: Kantner, Steven S.
• Primary Examiner(s): Lilling, Herbert J.
• Application Number:
  US06/936,820
• Time in Patent Office: 501 Days
• Field of Search: 524/516, 524/500, 428/355, 428/356, 428/343, 428/914, 428/352, 428/145, 428/156, 525/186
• US Class Current: 428/343
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 33/14 of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
• CPC Class Codes: C08L 39/00 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 79/04 Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
• CPC Class Codes: C09J 133/062 Copolymers with monomers not covered by C09J133/06
• CPC Class Codes: C09J 2301/302 the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
• CPC Class Codes: Y10T 428/28 Web or sheet containing structurally defined element or component and having an adhesive outermost layer
• CPC Class Codes: Y10T 428/2839 with release or antistick coating
• CPC Class Codes: Y10T 428/2857 including metal or compound thereof or natural rubber
• CPC Class Codes: Y10T 428/2878 including addition polymer from unsaturated monomer
• CPC Class Codes: Y10T 428/2891 including addition polymer from alpha-beta unsaturated carboxylic acid [e.g., acrylic acid, methacrylic acid, etc.] Or derivative thereof

Abstract

Pressure-sensitive adhesives comprise blends of acrylate copolymer copositions with polyalkyloxazolines. The blends exhibit enhanced cohesive strength with balanced adhesive properties and are useful as coatings for sheet materials.

Claims

1. A normally tacky pressure-sensitive adhesive composition comprising a blend of the following:

a. acrylic or methacrylic copolymer having an inherent viscosity greater than about 0.2 comprising copolymerized A and B monomers wherein;

A is at least one free radically polymerizable vinyl monomer, at least one of which is an acrylic or methacrylic acid ester of a non-tertiary alcohol having from 1 to 18 carbon atoms with the average number of carbon atoms being about 4-12; and

B is at least one polar monomer copolymerizable with A, the amount by weight of B monomer being up to about 30% of the total weight of all monomers in the copolymer;

b. up to about 150 parts by weight of compatible tackifying resin per 100 parts by weight copolymer;

c. up to about 50 parts by weight of compatible plasticizer per 100 parts by weight copolymer; and

d. sufficient polyalkyloxazoline of a molecular weight above about 1,000 to provide the resultant blend with increased shear strength.

2. The pressure-sensitive adhesive composition of claim 1 wherein the amount of polyalkyloxazoline in said blend is sufficient to increase the shear strength of said blend by at least about 50% relative to the shear strength of the adhesive composition without polyalkyloxazoline.

3. The pressure-sensitive adhesive composition of claim 1 wherein the amount of polyalkyloxazoline in said blend is sufficient to increase the shear strength of said blend by at least about 100% relative to the shear strength of the adhesive composition without polyalkyloxazoline.

4. The pressure-sensitive adhesive composition of claim 1 wherein the average number of carbon atoms is about 4 to 10.

5. The pressure-sensitive adhesive composition of claim 1 wherein acrylic or methylacrylic acid ester is selected from the group consisting of butyl acrylate, isooctyl acrylate, isononyl acrylate, isodecyl acrylate, and 2-ethylhexyl acrylate.

6. The pressure-sensitive adhesive composition of claim 1 wherein said polar comonomer has hydroxyl or carboxylic, sulfonic, or phosphonic acid functionality.

7. The pressure-sensitive adhesive composition of claim 1 wherein said polar comonomer is selected from the group consisting of acrylic acid, 2-carboxyethyl acrylate, itaconic acid, 2-hydroxyethylacrylate, hydroxypropylacrylate, and 2-sulfoethylmethacrylate.

8. The pressure-sensitive adhesive composition of claim 1 wherein the amount by weight of said polar comonomer is from about 1% to about 15% of the total weight of all monomers in the copolymer.

9. The pressure-sensitive adhesive composition of claim 1 wherein the inherent viscosity is in the range of about 0.4 to about 2.5.

10. The pressure-sensitive adhesive composition of claim 1 wherein the acrylic or methacrylic copolymer contains as one of the A monomers a hydrophilic macromolecular monomer.

11. The pressure-sensitive adhesive composition of claim 1 wherein said polyalkyloxazoline has a repeating unit having the following formula:

##STR3## wherein R is hydrogen or an inertly-substituted lower alkyl group, x is 1 or 2, and R¹ is selected from the group consisting of hydrogen, phenyl, inertly-substituted phenyl, alkyl having up to about 20 carbon atoms, or inertly-substituted alkyl.

12. The pressure-sensitive adhesive composition of claim 11 wherein x is 1, R is hydrogen, and R¹ is selected from hydrogen and alkyl groups containing up to about 10 carbon atoms.

13. The pressure-sensitive adhesive composition of claim 11 wherein x is 1, R is hydrogen, and R¹ is selected from hydrogen, methyl, ethyl and propyl.

14. The pressure-sensitive adhesive composition of claim 1 wherein the amount of polyalkyloxazoline is in the range of about 0.2 parts to about 25 parts by weight polyalkyloxazoline per 100 parts by weight of the combined weight of said copolymer and said polyalkyloxazoline.

15. The pressure-sensitive adhesive composition of claim 1 wherein the amount of polyalkyloxazoline is in the range of about 0.5 parts to about 10 parts by weight polyalkyloxazoline per 100 parts by weight of the combined weight of said copolymer and said polyalkyloxazoline.

16. The pressure-sensitive adhesive composition of claim 1 wherein said polyalkyloxazoline has a molecular weight within the range of about 1,000 to about 2,000,000.

17. The pressure-sensitive adhesive composition of claim 1 wherein said polyalkyloxazoline has a molecular weight within the range of about 2,000 to about 500,000.

18. A sheet material having at least a portion of at least one major surface coated with the pressure-sensitive adhesive composition of claim 1.

19. An adhesive coated tape comprising a flexible backing having at least one major surface coated with the pressure-sensitive adhesive composition of claim 1.

20. The transfer tape comprising a film of the pressure-sensitive adhesive composition of claim 1 borne on at least one release liner.

21. The pressure-sensitive adhesive composition of claim 1 further characterized by being crosslinked.