Flexible primer composition

• US 4,739,020 A
• Filed: 12/24/1986
• Issued: 04/19/1988
• Est. Priority Date: 12/13/1985
• Status: Expired due to Fees

• Current Assignee: PPG Industries Incorporated (Nouryon BV)
• Original Assignee: PPG Industries Incorporated (Nouryon BV)
• Inventors: Schmitt, Robert J., Wallace, David R., Seneker, Carl A., Carson, Dennis W., Van Kuren, Thomas A.
• Primary Examiner(s): Page, Thurman K.
• Application Number:
  US06/946,257
• Time in Patent Office: 482 Days
• Field of Search: 525/481, 525/939, 525/528
• US Class Current: 525/481
• CPC Class Codes: C08G 18/4027 Mixtures of compounds of group C08G18/54 with other macromolecular compounds
• CPC Class Codes: C08G 18/4045 Mixtures of compounds of group C08G18/58 with other macromolecular compounds
• CPC Class Codes: C08G 59/4028 Isocyanates; Thioisocyanates
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C09D 163/00 Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
• CPC Class Codes: Y10S 525/939 Multipackage system

Abstract

A coating composition contains an organic polyol, a polyepoxide, a polyisocyanate crosslinking agent, and a phenolic resin. The composition is flexible, having an elongation of at least 10 percent when cured. This coating composition is particularly suitable as a primer in preparing substrates with a multilayer coating having good flexibility.

Claims

1. A two package coating composition comprising an organic polyol, a polyepoxide, a free polyisocyanate crosslinking agent and a phenolic resin;

with the proviso that the organic polyol is present in one package and the free polyisocyanate crosslinking agent is present in a second package.

2. The coating composition of claim 1 wherein the organic polyol has a number average molecular weight of at least 500 and a hydroxyl number of at least 30.

3. The coating composition of claim 2 wherein the organic polyol is selected from polyester polyols, polyether polyols, acrylic polyols, and polyurethane polyols.

4. The coating composition of claim 2 wherein the organic polyol has a number average molecular weight of from about 500 to about 20,000 and a hydroxyl number of from about 30 to about 200.

5. The coating composition of claim 1 wherein the polyepoxide is the condensation product of a epihalihydrin with bisphenol A.

6. The coating composition of claim 1 wherein the epoxide equivalent weight of the polyepoxide ranges from about 280 to about 4,000.

7. The coating composition of claim 1 wherein the phenolic resin is the condensation product of a phenol or alkyl substituted phenol and formaldehyde.

8. The coating composition of claim 1 wherein the organic polyol is present in an amount ranging from about 15 percent to about 70 percent the percentages being based on the total resin solids content of the composition.

9. The coating composition of claim 1 wherein the polyepoxide is present in an amount ranging from about 5 percent to about 40 percent, the percentages being based on the total resins solids content of the composition.

10. The coating composition of claim 1 wherein the polyisocyanate is present in an amount ranging from about 15 percent to about 70 percent, the percentages being based on the total solids content of the composition.

11. The coating composition of claim 1 wherein the phenolic resin is present in an amount ranging from about 1 percent to about 20 percent, the percentages being based on the total resin solids content of the composition.

12. The coating composition of claim 1 wherein the composition has an elongation of at least 10 percent when cured.

13. The coating composition of claim 1 wherein the free polyisocyanate is selected from aliphatic polyisocyanates, aromatic polyisocyanates, cycloaliphatic polyisocyanates and mixtures thereof.

14. A two package coating composition, comprising:

a first package comprising an organic polyol, a polyepoxide and a phenolic resin and a second package comprising a free polyisocyanate crosslinking agent.