Gas liquefaction method and apparatus

• US 4,740,223 A
• Filed: 11/03/1986
• Issued: 04/26/1988
• Est. Priority Date: 11/03/1986
• Status: Expired due to Term

• Current Assignee: BOC Group Pty Limited (Linde Plc)
• Original Assignee: BOC Group Pty Limited (Linde Plc)
• Inventors: Gates, Robert G.
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US06/926,278
• Time in Patent Office: 540 Days
• Field of Search: 62/9, 62/11, 62/23, 62/38, 62/40
• US Class Current: 62/612
• CPC Class Codes: F25J 1/0015 Nitrogen
• CPC Class Codes: F25J 1/0035 by gas expansion with extraction of work
• CPC Class Codes: F25J 1/0037 of a return stream
• CPC Class Codes: F25J 1/004 by flash gas recovery F25J1/0267 takes precedence
• CPC Class Codes: F25J 1/0219 in combination with an internal quasi-closed refrigeration loop, e.g. using a deep flash recycle loop
• CPC Class Codes: F25J 1/0285 Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings
• CPC Class Codes: F25J 1/0288 using work extraction by mechanical coupling of compression and expansion of the refrigerant, so-called companders
• CPC Class Codes: F25J 2270/90 External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
• CPC Class Codes: F25J 2290/10 Mathematical formulae, modeling, plot or curves; Design methods

Abstract

The present invention relates to the liquefaction of a permanent gas comprising nitrogen. The temperature of the permanent gas stream at a pressure in the range of 75 to 90 atmospheres is reduced to below its initial temperature. Providing at least part of the necessary refrigeration, a single nitrogen working fluid cycle is performed in which the nitrogen working fluid is compressed to a pressure in the range of 75 to 90 atmospheres, cooled to a temperature in the range of 170 to 200 K., work expanded to a temperature in the range of 107 to 120 K., and warmed by heat exchange countercurrently to the permanent gas stream, thereby providing refrigeration for the stream.

Claims

1. A method of liquifying a stream of permanent gas comprising nitrogen utilizing a single fluid cycle comprising:

(a) compressing said gas stream to a pressure of from about 75 to 90 atmosphere;

(b) providing a nitrogen working fluid at a pressure of from about 75 to 90 atmospheres;

(c) cooling said fluid to a temperature of from about 170 to 200 K;

(d) work-expanding said fluid toa temperature of from about 107 to 120 K;

(e) warming the work-expanded fluid by heat exchange countercurrently to said gas stream thereby providing refrigeration necessary to reduce the temperature of said gas to below its critical temperature.

2. A method in accordance with claim 1, in which the permanent gas stream is initially cooled to a temperature of from about 170 to 185 K by means of a mixed refrigerant cycle.

3. A method in accordance with claim 1, in which the nitrogen working fluid at the end of work expansion in step (d) is in a saturated state.

4. A method in accordance with claim 3, in which the temperature of the nitrogen working fluid at the end of work expansion in step (d) is from about 108 to 112 K.

5. A method in accordance with claim 1, in which the nitrogen working fluid is compressed to the same pressure as the permanent gas stream.

6. A method as claimed in claim 5, in which said permanent gas stream is subjected to at least three isenthalpic expansions to reduce it in pressure to a storage pressure.

7. A method in accordance with claim 5, wherein the nitrogen working fluid and the permanent gas stream are compressed to a pressure of about 80 atmospheres.

8. A method as claimed in claim 1 in which after passing out of heat exhange relationship with said nitrogen working fluid the said permanent gas stream is expanded to a storage pressure, the resulting liquid being collected and the resulting gas heat exchanged countercurrently to said permanent gas stream.

9. A method in accordance with claim 1, wherein said fluid is withdrawn from said permanent gas stream.

10. A method in accordance with claim 1, including the additional steps of expanding the liquified permanent gas stream to storage pressure thereby forming a liquid fraction and a gaseous fraction, collecting the liquid for storage and passing the gaseous fraction in countercurrent heat exchange to said permanent gas stream.

11. A method in accordance with claim 10, wherein said liquified gas stream is subjected to at least three isenthapic expansions to reduce the pressure thereof to a storage pressure.