Electrochromic nonglaring mirror

• US 4,741,603 A
• Filed: 05/05/1986
• Issued: 05/03/1988
• Est. Priority Date: 05/08/1985
• Status: Expired due to Fees

• Current Assignee: Nissan Motor Co., Ltd.
• Original Assignee: Nissan Motor Co., Ltd.
• Inventors: Ishikawa, Masazumi, Murofushi, Yasuyuki, Miyagi, Harutoshi
• Primary Examiner(s): Wan, Gene
• Assistant Examiner(s): Lee, James C.
• Application Number:
  US06/859,355
• Time in Patent Office: 729 Days
• Field of Search: 350/357
• US Class Current: 359/270
• CPC Class Codes: B60R 1/088 using a cell of electrically changeable optical characteristic, e.g. liquid-crystal or electrochromic mirrors
• CPC Class Codes: G02F 1/15165 Polymers
• CPC Class Codes: G02F 1/153 Constructional details

Abstract

Disclosed is a nonglaring mirror which is an electrochromic device in principle. The mirror comprises a transparent front substrate laid with a transparent first electrode film, a back substrate laid with a second electrode film which is opposite and spaced from the first electrode film, first and second electrochromic layers formed on the first and second electrode films, respectively, and an electrolyte liquid which fills up the space between the two substrates. A reflecting surface is provided by using a transparent sheet as the back substrate and coating the rear surface of the back substrate with a reflecting metal film, or by using a reflecting metal film as the second electrode film. One of the first and second electrochromic layers is formed of a polymer of a conjugated compound, such as substituted or unsubstituted triphenylamine, and the other is formed of a transition metal oxide such as WO₃. In the initial state both the first and second electrochromic layers are colorless and transparent. For coloration, the conjugated polymer layer is oxidized and the transition metal oxide layer is reduced. In the colored state the reflectance of the mirror becomes 7-15% and is controllable.

Claims

1. An electrochromic nonglaring mirror, comprising:

a transparent front substrate which is coated with a transparent first electrode film, and a back substrate which is coated with a second electrode film, said back substrate positioned parallel to said front substrate such that the first and second electrode films are opposite to and spaced from each other;

a first electrochromic layer formed on said first electrode film and a second electrochromic layer formed on said second electrode film;

means for providing a reflecting surface to said back substrate; and

an electrolyte liquid provided in the space between said front and back substrates;

one of said first and second electrochromic layers being formed from a conjugated polymer which undergoes electrochemical oxidation and reduction and becomes lower in light transmittance when it is in an oxidized state, said conjugated polymer being a polymer prepared from a compound represented by the following general formula;

##STR2## wherein X, Y and Z each represent a hydrogen atom, a halogen atom, a hydroxyl group, an alkyl group, an alkoxyl group, an acyl group, an allyl group, a vinyl group or a vinylidene group, the other electrochromic layer being formed of a transition metal oxide which becomes lower in light transmittance when it is in an electrochemically reduced state.

2. A mirror according to claim 1, wherein said conjugated polymer is selected from the group consisting of polytriphenylamine, poly(4,4'"'"'-dichlorotriphenylamine), poly(4,4'"'"'-dibromo-4'"'"'-methyltriphenylamine) and poly(4,4'"'"'-dibromo-4"-methoxytriphenylamine).

3. A mirror according to claim 1, wherein said transition metal oxide is selected from the group consisting of WO₃, MoO₃, Nb₂ O₅, Cr₂ O₃, Ta₂ O₅, TiO₂, Fe₂ O₃ and AgO.

4. A mirror according to claim 1 wherein both said back substrate and said second electrode film are transparent, said means for providing a reflecting surface comprises a reflecting metal film coated on the rear surface of said back substrate.

5. A mirror according to claim 1 wherein said second electrode film and said means comprise a reflecting metal film.

6. A mirror according to claim 5, wherein the material of said second electrode film is selected from the group consisting of Ta, W, Re, Os, Ir, Pt and Au.

7. A mirror according to claim 5, wherein the distance between said first and second electrode films is in the range from 30 to 1000 μ

m.

8. A mirror according to claim 7, wherein said distance is not greater than 450 μ

m.

9. A mirror according to claim 1, wherein said electrolyte liquid is a solution of an alkali metal compound selected from the group consisting of LiClO₄, LiBF₄, LiPF₆, KClO₄, KBF₄ and KPF₆ in a solvent.

10. A mirror according to claim 9, wherein said solvent is selected from tne group consisting of acetonitrile, propylene carbonate, N,N'"'"'-dimethylformamide and water, and mixtures thereof.

11. A mirror according to claim 1, further comprising a transparent spacer which is disposed between said first and second electrochromic layers so as to contact with said first and second electrochromic layers only in limited areas.

12. A mirror according to claim 11, wherein said spacer comprises a plurality of glass spheres which are substantially uniform in diameter.

13. A mirror according to claim 1 wherein said electrolyte liquid comprises an alkali metal compound in an organic solvent, water, or a mixed solvent system which includes water.

14. A mirror according to claim 13 wherein said alkali metal compound comprises LiCIO₄, LiBF₄, LiBF₆, KCIO₄, KBF₄ or KPF₆.