Vessel for the generation of synthesis gas

• US 4,741,885 A
• Filed: 09/09/1986
• Issued: 05/03/1988
• Est. Priority Date: 09/11/1985
• Status: Expired due to Term

• Current Assignee: UHDE GmbH (Thyssenkrupp AG)
• Original Assignee: UHDE GmbH (Thyssenkrupp AG)
• Inventors: Herbort, Hans-Joachim, Marsch, Hans-Dieter
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): Johnson, William R.
• Application Number:
  US06/905,120
• Time in Patent Office: 602 Days
• Field of Search: 422/197, 422/196, 422/202, 422/158
• US Class Current: 422/625
• CPC Class Codes: B01J 2208/00309 with two or more reactions in heat exchange with each other, such as an endothermic reaction in heat exchange with an exothermic reaction
• CPC Class Codes: B01J 2208/00495 using insulating materials or refractories
• CPC Class Codes: B01J 2208/00504 by means of a burner
• CPC Class Codes: B01J 2208/021 comprising a plurality of beds with flow of reactants in parallel
• CPC Class Codes: B01J 2219/185 vertical
• CPC Class Codes: B01J 8/0278 Feeding reactive fluids for solid material B01J8/0015
• CPC Class Codes: B01J 8/062 being installed in a furnace
• CPC Class Codes: C01B 2203/0844 the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
• CPC Class Codes: C01B 3/384 the catalyst being continuously externally heated

Abstract

A vessel for the generation of synthesis gas at a high pressure, using hydrocarbons, includes a catalytic endothermic reforming section with a plurality of reformer tubes heated externally and filled with a catalyst, and a mixture of hydrocarbons and steam entering the reformer tubes which are positioned by a common plate. The reforming gas generated in the tubes flows from the tubed section into a partial oxidation section which has a larger diameter than the tubed section and the shape of a pressure vessel closed at one end, the free ends of the reformer tubes penetrating into the partial oxidation section, and in which inlet gas such as additional hydrocarbons and oxygen or oxygen-rich gas are mixed with the reforming gas. A plurality of inlet devices for the inlet gas are positioned in the cylindrical shell of the partial oxidation section with the axes of the gas flow streams being inclined away from the radial. The inlet devices are spaced a predetermined distance from the outlet end of the reformer tubes such that a rotary gas vortex is produced and the product gas stream flows through the outer section of the chamber, heats the reformer tubes and leaves the reforming section via an outlet nozzle.

Claims

1. In an essentially cylindrical vessel for the generation of synthesis gas at relatively high pressure utilizing hydrocarbons, including a first wall portion defining a catalytic endothermic reforming section, a plurality of reformer tubes having outlet ends, the reformer tubes capable of being heated externally and being filled with a catalyst, the reformer tubes mounted within the reforming section and extending parallel to the longitudinal axial direction of the vessel, an inlet nozzle opening into the first wall portion for introducting a mixture of hydrocarbons and steam into the vessel such that the mixture flows through the reformer tubes, whereby reforming gas is generated in the reformer tubes, an outlet nozzle defined in the first wall portion, a second wall portion adjacent the first wall portion, the second wall portion having a greater diameter than the first wall portion, an end wall connected to the second wall portion, the second wall portion and the end wall defining a pressure chamber forming a partial oxidation section, the outlet ends of the reformer tubes opening into the partial oxidation section, the partial oxidation section serving for mixing the reforming gas with additional hydrocarbons and oxygen or oxigen-rich gas, the improvement comprising a plurality of inlet devices for the hydrocarbons and oxygen or oxygen-rich gas, the inlet devices each defining an axis and mounted in the second wall portion, the axes of the inlet devices extending at an angle α

relative to the radial direction of the vessel and the axes of the inlet devices extending transversely of the axial direction of the vessel at an angle β

ranging from parallel with to inclined to a radial plane of the vessel, the inlet devices axially spaced from the outlet ends of the reformer tubes and from the bottom wall of the vessel, whereby the gases in the partial oxidation section are conducted in a rotating pattern in circumferential direction of the vessel and in a loop-shaped pattern in axial direction of the vessel, such that the gases are conducted from the center of the partial oxidation section toward the bottom wall and then toward the lower wall portion, so that the gases flow upwardly along the lower wall portion toward the reforming section where the gases heat the reformer tubes and subsequently leave the vessel via the outlet nozzle.

2. The vessel according to claim 1, wherein the improvement further includes that the partial oxidation section has an axial length selected in such a way that the minimum dwell time of the glass is 4 seconds.

3. The vessel according to claim 1, wherein the inlet nozzle has a plurality of nozzle openings.

4. The vessel according to claim 1, wherein the angle α

ranges from 1°

to 30°

, the angle β

with the radial plane ranges from +5°

to -15°

, and an axial distance h from the ends of the inlet devices to the outlet ends of the reformer tubes is in the range of 0.15 to 1.0 times the diameter of a circle enveloping the reformer tubes.

5. The vessel according to claim 4, wherein the angle α

ranges from 5°

to 20° and

the angle β

ranges from 0 to -10°

.

6. The vessel according to claim 4, wherein the improvement further includes that outlet end of the reformer tubes has an internal diameter d, and all gas outlet openings define a maximum pitch t, the distance h, the diameter d, and the maximum pitch t complying with the following requirement:

space="preserve" listing-type="equation">t is less than or equal to d +(0.317×

h)

7. The vessel according to claim 1, wherein the improvement furhter includes that the Reynolds number for the flow conditions of the gas streams the outlet ends of the reformer tubes is at least 5×

10³.

8. The vessel according to claim 7, wherein the improvement further includes that the Reynolds number for the flow conditions of the gas streams the outlet ends of the reformer tubes is greater than 5×

10⁴.

9. The vessel according to claim 1, wherein the improvement further includes that Reynolds number for the flow conditions in the inlet devices is greater than 4×

10³.

10. The vessel according to claim 9, wherein the improvement further includes that Reynolds number for the flow conditions in the inlet devices is greater than 4×

10⁴.

11. The vessel according to claim 1, wherein the improvement further includes that partial oxidation section has an internal diameter which is at least 1.1 times the diameter of a circle enveloping the reformer tubes.

12. The vessel according to claim 11, wherein the improvement further includes that the internal diameter of the partial oxidation section is a maximum of two times the diameter of the enveloping circle.

13. The vessel according to claim 1, wherein a catalyst for a catalytic steam reforming step is mounted near the outlet ends of the reformer tubes such that the ends of the reformer tubes penetrate the catalyst.

14. The vessel according to claim 13, wherein the catalyst is supported by a layer, the layer serving additionally to facilitate transfer of the heat of the gases onto the reformer tubes so that an adequate cooling time is ensured.

15. The vessel according to claim 11, wherein the layer is a packing.