Curable fluorosilicone rubber composition

• US 4,742,101 A
• Filed: 02/10/1987
• Issued: 05/03/1988
• Est. Priority Date: 02/14/1986
• Status: Expired due to Term

• Current Assignee: Shin-Etsu Chemical Company Limited
• Original Assignee: Shin-Etsu Chemical Company Limited
• Inventors: Yoshida, Takeo
• Primary Examiner(s): Marquis, Melvyn I.
• Application Number:
  US07/013,253
• Time in Patent Office: 448 Days
• Field of Search: 528/24, 528/42, 528/15, 528/31, 528/32, 524/267, 524/268, 524/731, 524/493
• US Class Current: 524/267
• CPC Class Codes: C08K 5/5419 containing at least one Si—C bond
• CPC Class Codes: C08L 83/08 containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen

Abstract

A curable fluorosilicone rubber composition comprising particular organopolysiloxane having a fluoroalkyl group and having a viscosity of 1,000 cP or more at 25° C., reinforcing silica powder having a specific surface area of 50 m² /g or more, and a vulcanizing agent; which further comprises, as a fluid for bleed, a fluid organopolysiloxane compound represented by General Formula: ##STR1## wherein some R'"'"' represent methyl groups and other R'"'"' represent phenyl groups; the ratio of the number of the methyl group to the number of the phenyl group in the molecule ranges between 70/30 and 25/75; and n is an integer of 0 to 5.

Rubber obtained by curing of this composition has excellent oil and solvent resistance, thermal resistance and low-temperature resistance which are inherent in ordinary fluorosilicone rubber, and moreover has a good fluid-bleeding property.

Claims

1. A curable fluorosilicone rubber composition comprising:

(A) 100 parts by weight of an organopolysiloxane represented by General Unit Formula (I);

##STR8## wherein R comprises 25 to 50 mole % of a group represented by the formula;

--CH₂ CH₂ Rf, where Rf represents a perfluoroalkyl group having 1 to 3 carbon atoms, and 75 to 50 mole % of a group selected from the group consisting of a methyl group, an ethyl group, a phenyl group and a vinyl group; and

a is a number of 1.98 to 2.02;

and having a viscosity of at least 1,000 cP at 25°

C.;

(B) 10 to 50 parts by weight of reinforcing silica powder having a specific surface area of at least 50 m² /g;

(C) 0 to 100 parts by weight of semi-reinforcing silica powder having an average particle diameter of not greater than 50 μ

m;

(D) 3 to 10 parts by weight of a fluid organopolysiloxane compound represented by General Formula (II);

##STR9## wherein some R'"'"' represent methyl groups and other R'"'"' represent phenyl groups;

the ratio of the number of the methyl group to the number of the phenyl group in the molecular ranges between 70/30 and 25/75; and

n is an integer of 0 to 5; and

(E) a vulcanizing agent.

2. The composition according to claim 1, wherein Component (A) is organopolysiloxane represented by General Unit Formula (I), wherein R comprises 25 to 50 mole % of a 3,3,3-trifluoropropyl group or 3,3,4,4,4-pentafluorobutyl group, and 75 to 50 mole % of a methyl group, an ethyl group or a vinyl group, and a is a number of 1.98 to 2.02;

and having a viscosity of 3,000 to 1×

10⁷ cP at 25°

C.

3. A curable fluorosilicone rubber composition according to claim 1, wherein Component (B) is a silica powder having a specific surface area of 130 to 400 m² /g.

4. A curable fluorosilicone rubber composition according to claim 1, wherein Component (C) is a silica powder having an average particle diameter of 0.1 to 30 μ

m.

5. A curable fluorosilicone rubber composition according to claim 1, wherein Component (D) is a fluid organopolysiloxane compound represented by General Formula (I), wherein the ratio of the number of the methyl group to the number of the phenyl group in the molecule ranges between 60/40 and 40/60.

6. A curable fluorosilicone rubber composition according to claim 1, wherein the vulcanizing agent of Component (E) is a peroxide.

7. A curable fluorosilicone rubber composition according to claim 1 consisting essentially of (A), (B), (C), (D) and (E).

8. A curable fluorosilicone rubber composition according to claim 1, wherein said fluid organopolysiloxane (D) is present in an amount from 5 to 8 parts by weight.

9. A curable fluorosilicone rubber composition according to claim 7, wherein said fluid organopolysiloxane (D) is present in an amount from 5 to 8 parts by weight.