Method for the manufacture of product comprising foamed plastic material and using a low-pressure chamber

• US 4,743,417 A
• Filed: 05/13/1985
• Issued: 05/10/1988
• Est. Priority Date: 09/12/1983
• Status: Expired due to Term

• Current Assignee: Camoplast Inc (Compagnie Generale DES Etablissements Michelin SCA)
• Original Assignee: Rovac Technology A.B.
• Inventors: Bakkelunn, Terje
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US06/734,947
• Time in Patent Office: 1,093 Days
• Field of Search: 264/45.3, 264/45.1, 264/53, 264/54, 264/DIG. 5, 264/50, 264/101, 264/DIG. 83, 264/46.5, 264/328.6
• US Class Current: 264/45.1
• CPC Class Codes: B29C 44/3403 Foaming under special conditions, e.g. in sub-atmospheric pressure, in or on a liquid
• CPC Class Codes: B29K 2067/00 Use of polyesters or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2105/12 of short lengths, e.g. chopped filaments, staple fibres or bristles
• CPC Class Codes: B29K 2707/04 Carbon
• CPC Class Codes: B29K 2709/08 Glass
• CPC Class Codes: Y10S 264/05 Use of one or more blowing agents together
• CPC Class Codes: Y10T 428/249955 Void-containing component partially impregnated with adjacent component

Abstract

A propellant is mixed with unsaturated polyester inside a first space (A) at a first pressure, for example at the atmospheric pressure. The polyester is then sprayed on the whole or parts of an open or exposed mould which is applied in a low-pressure chamber having a powerful negative pressure of 60-95% vacuum. In order to spray a first layer, polyester having a first amount of propellant is sprayed on the mould. At the initiation the propellant causes a powerful foaming effect at which bubbles are created and/or expanded in the polyester. In order to spray a second layer, which can be applied before or after the first layer, polyester having a second amount of propellant, or is without propellant, is sprayed on the mould, which causes fewer bubbles or no bubbles at all. The resulting polyester which comprises formed and expanded bubbles is bound (is allowed to tack rigid shape/is polymerized) by the use of a short tack-free time in the low pressure, said short time being preferably 5-10 minutes.

Claims

1. A method for manufacturing a plastic article comprising at least two foamed layers which have different densities comprising:

(a) mixing together in a first zone an unsaturated polyester and a foaming agent, said foaming agent being present in a first concentration and said first zone being maintained at a first pressure;

(b) providing a curing agent for said unsaturated polyester in the mixture of unsaturated polyester and foaming agent to provide a first sprayable mixture;

(c) spraying said first sprayable mixture into a second zone and onto the outer surface of an open mold which is within said second zone, and said second zone being maintained at a second pressure which is less than said first pressure in said first zone to form, on said mold, a first plastic layer having a first density;

(d) forming and spraying into said second zone and onto said first plastic layer formed in step (c), a second sprayable mixture of unsaturated polyester and foaming agent which had been mixed together in said first zone together with a curing agent for said unsaturated polyester, said second sprayable mixture containing said foaming agent in a second concentration sufficiently different from the concentration of foaming agent in said first sprayable mixture to produce a second layer of plastic bonded to said first layer, said second layer having a density which is different from the density of said first layer.

2. A method in accordance with claim 1 wherein said first pressure in said first zone is at least atmospheric pressure and said second pressure in said second zone is from about 0.05 bar to about 0.4 bar.

3. A method in accordance with claim 1 wherein said first pressure in said first zone is about atmospheric pressure and said second pressure in said second zone is from about 0.10 bar to about 0.3 bar.

4. A method in accordance with claim 1 wherein said first pressure in said first zone is about atmospheric and said second pressure in said second zone is from about 0.10 bar to about 0.15 bar.

5. A method in accordance with claim 1 wherein said curing agent is provided in a concentration to result in a curing time of from about 30 seconds to about 20 minutes.

6. A method in accordance with claim 1 wherein said curing agent is provided in a concentration to result in a curing time of from about 2 minutes to about 10 minutes.

7. A method in accordance with claim 1 wherein foaming agent produces gases as a result of a chemical reaction and said foaming agent is present in at least one of said spraying mixtures in a concentration from about 0.2 to about 1.0 percent.

8. A method in accordance with claim 1 wherein said foaming agent is a physical agent and is present in at least one of said spraying mixtures in a concentration from about 0.05 to about 0.5 percent.

9. A method in accordance with claim 1 wherein the concentration of foaming agents in said first and second sprayable mixtures are controlled to produce a first plastic layer which has a higher density than the density of said second plastic layer.

10. A method in accordance with claim 1 wherein the concentrations of foaming agent in said first and second sprayable mixtures are controlled to produce a first plastic layer which has a lower density than the density of said second plastic layer.

11. A method in accordance with claim 1 wherein the second sprayable mixture is sprayed onto said first plastic layer while said first plastic layer is wet.

12. A method in accordance with claim 1 wherein reinforcing fibers are added to the sprayable mixture as it is being sprayed into the mold.

13. A method in accordance with claim 1 wherein reinforcing fibers selected from chopped glass fibers and chopped carbon fibers in a concentration of about 10 to about 40 percent by weight are added to the sprayable mixture as it is being sprayed into the mold.

14. A method in accordance with claim 1 wherein said curing agent is introduced into said mixture of said unsaturated polyester and said foaming agent under said first pressure.

15. A method in accordance with claim 1 wherein said curing agent is introduced into said mixture of said unsaturated polyester and said foaming agent under said second pressure.

16. A method in accordance with claim 1 wherein said curing agent is a peroxide.

17. A method in accordance with claim 1 wherein the quantity of foaming agent is selected to produce a density in the range of 170-600 Kg/m³ for at least one of said layers.

18. A method for manufacturing a plastic article comprising at least three layers comprising:

(a) mixing together in a first zone an unsaturated polyester and a foaming agent, said foaming agent being present in a first concentration and said first zone being maintained at a a pressure of at least about 1 atmosphere;

(b) providing a curing agent for said unsaturated polyester in the mixture of unsaturated polyester and foaming agent to provide a first sprayable mixture;

(c) spraying said first sprayable mixture into a second zone and onto the outer surface of an open mold which is within said second zone, said second zone being maintained at a second pressure from about 0.05 bar to about 0.4 bar to form, in said mold, a first plastic layer;

(d) forming and spraying into said second zone and onto said first plastic layer formed in step (c), a second sprayable mixture of unsaturated polyester and foaming agent which had been mixed together in said first zone together with a curing agent for said unsaturated polyester, said second sprayable mixture containing said foaming agent in a concentration sufficiently higher than the concentration of foaming gent in said first sprayable mixture to produce a second layer of plastic bonded to said first layer, said second layer having a density which is lower than the density of said first layer; and

(e) repeating steps (a) and (b) and spraying the resulting sprayable mixture on the low density plastic formed in step (d), thereby forming a plastic structure having a low density core.