Method for agitating metals and producing alloys

• US 4,743,428 A
• Filed: 08/06/1986
• Issued: 05/10/1988
• Est. Priority Date: 08/06/1986
• Status: Expired due to Term

• Current Assignee: Teck Cominco Metals Ltd.
• Original Assignee: Cominco Ltd. (Quebec)
• Inventors: Willans, Robert D. H., Mawer, Eric L., McRae, Dale L.
• Primary Examiner(s): Rosenberg, Peter D.
• Application Number:
  US06/893,843
• Time in Patent Office: 643 Days
• Field of Search: 75/61, 75/93 R, 75/53, 420/590, 266/204, 266/235
• US Class Current: 420/590
• CPC Class Codes: B01F 27/941 being hollow, perforated or having special stirring elements thereon
• CPC Class Codes: F27D 27/00 Stirring devices for molten material F27D3/14 takes precedence
• CPC Class Codes: F27D 3/0026 Introducing additives into the melt

Abstract

Method and apparatus for the agitation of base metal on alloy melts, and for the agitation and alloying of base metal melts with at least one alloying metal. A rotatable device is suspended in a melt of base metal and the device is rotated to draw at least a partial vortex in the melt. The device comprises a hollow cylinder having an open top and a closed bottom. An array of openings in the cylinder side wall is adapted to allow melt of the base metal to pass through. In the agitation of a base metal or alloy melt, the amount of dross formed on the melt is reduced. In alloying, the at least one alloying metal may be added directly to the melt or may be added in particulate form into the vortex in the device, the latter being particularly useful when the melting point of the alloying metal is higher than that of the base metal or alloy. When added into the device, the openings in the cylindrical wall are adapted to retain the particulates in the device to be washed with base metal until the particulates are substantially dissolved. Alloys produced using the device have narrow standard deviations from their specification. The alloying proceeds more efficiently with formation of less dross and less off-specification material, proceeds faster and in less time than heretofore possible, and allows production on a continuous basis.

Claims

1. A method for the agitation of a melt of a base metal or alloy whereby dross formation is reduced which comprises the steps of establishing a melt of base metal or alloy in a vessel;

submerging a rotatable device in said melt;

said rotatable device comprising a hollow cylinder having a side wall with an upper end and a lower end, said cylinder being open at the upper end and closed at the lower end, said side wall having an array of equispaced openings adapted to allow said melt to pass through said openings, and said cylinder having a diameter relative to the diameter of the vessel in the range of about 1.5;

1 to about 3.5;

1;

rotating said cylinder at a predetermined speed in the range of about 100 to about 600 revolutions per minute sufficient to draw at least a partial vortex in said melt into said rotatable device, causing said melt to flow into the top of said device and out through said side wall openings; and

withdrawing melt from said vessel.

2. A method as claimed in claim 1, wherein said melt of base metal is agitated for the alloying of said base metal with at least one alloying metal in said vessel;

an amount of said at least one alloying metal is fed into said melt of base metal, said amount being a predetermined amount sufficient to provide an alloy of desired composition;

an alloy of said base metal is formed with said at least one alloying metal; and

said alloy of desired composition is withdrawn from said vessel.

3. A method as claimed in claim 2, wherein said at least one alloying metal is fed in particulate form into said vortex in said device in a predetermined amount sufficient to provide an alloy containing the desired amount of said at least one alloying metal;

said openings in said cylindrical wall are adapted to retain alloying metal added in particulate form in said device;

said alloying metal added to said device is ashed in said device with said melt of base metal while rotating said device, said washing with base metal while rotating said device causing dissolution of said alloying metal added to said device and formation of an alloy of said base metal with said at least one alloying metal added to said device; and

alloy of desired composition is withdrawn from said vessel.

4. A method as claimed in claim 3, wherein the melting point of said at least one alloying metal fed in particulate form into said vortex in said device is higher than the melting point of said base metal.

5. A method as claimed in claim 4, wherein said base metal is zinc and said alloying metal is chosen from the group consisting of iron, nickel, manganese, aluminum and copper.

6. A method as claimed in claim 2, wherein said base metal is zinc, said alloying metal is aluminum and at least one alloying metal chosen from the group consisting of lead, cadmium, misch metal, lanthanum and cerium.

7. A method as claimed in claim 4, wherein said base metal is zinc, said alloying metal is aluminum and at least one alloying metal chosen from the group consisting of lead, cadmium, misch metal, lanthanum and cerium.

8. A method as claimed in claim 3, wherein an inert gas is supplied in said vessel.

9. A method as claimed in claim 3, wherein said alloying is carried out continuously by adding a measured amount of melt of base metal continuously to said vessel, adding said at least one alloying metal continuously to the rotating, rotatable device at a predetermined rate sufficient to produce an alloy of the desired composition, continuously removing a volume of said alloy from said vessel, and maintaining the level of melt in said vessel substantially constant, said alloy removed from said vessel having a small standard deviation from composition specification.

10. A method as claimed in claim 3, wherein said base metal and said alloying metal fed in particulate form form agglomerates and said agglomerates are retained in said device until substantially dissolved.

11. A method as claimed in claim 4, wherein said base metal and said alloying metal fed in particulate form form agglomerates and said agglomerates are retained in said device until substantially dissolved.