Method for evaluating the remaining useful life of a lubricant

• US 4,744,870 A
• Filed: 12/23/1986
• Issued: 05/17/1988
• Est. Priority Date: 12/23/1986
• Status: Expired due to Term

• Current Assignee: University of Dayton
• Original Assignee: University of Dayton
• Inventors: Kauffman, Robert E.
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US06/945,755
• Time in Patent Office: 511 Days
• Field of Search: 436/60, 436/61, 204/1 T, 204/1 K
• US Class Current: 205/775
• CPC Class Codes: G01N 27/48 using polarography, i.e. measuring changes in current under a slowly-varying voltage
• CPC Class Codes: G01N 33/2888 Lubricating oil characteristics, e.g. deterioration lubricating properties G01N33/30

Abstract

A method is disclosed for measuring the remaining useful life of an ester-based lubricant containing at least one antioxidant species. A lubricant sample is mixed with a solvent, an organic base and an electrolyte to produce an analysis sample. The analysis sample is placed into an electrolytic cell and subjected to a cyclic voltammetric analysis, whereby a varying electric current is produced within the cell. The current during the cyclic voltammetric analysis is measured and recorded. Remaining useful life for the lubricant is then determined from the average maximum reduction current wave height produced.

Claims

1. A method for measuring the remaining useful life of a lubricant containing at least one antioxidant species, comprising the steps of:

mixing a lubricant sample with a solvent, organic base, and an electrolyte to produce an analysis sample;

placing said analysis sample into an electrolytic cell;

applying an electric potential of a first value to said analysis sample to produce an electric current therethrough;

varying said potential from said first value to a second value to produce an oxidation reaction of said antioxidant species within said cell;

varying said potential from said second value to said first value to produce a reduction reaction of an oxidized product of said antioxidant species within said cell; and

measuring and recording said current during at least said reduction reaction.

2. The method as defined in claim 1, wherein said lubricant is an ester-based oil.

3. The method as defined in claim 1, wherein said organic base is pyridazine.

4. The method as defined in claim 1, wherein said organic base is pyridine.

5. The method as defined in claim 1, wherein said organic base is dipyridyl.

6. The method as defined in claim 1, wherein the ratio by weight of said organic base to said electrolyte and said solvent within said analysis sample is within the range of 1:

300 to 1;

30,000.

7. The method as defined in claim 6, wherein said ratio of said organic base to said electrolyte and said solvent is 1:

3000.

8. The method as defined in claim 1, wherein the ratio by volume of said lubricant to said organic base, said electrolyte and said solvent within said analysis sample is within the range of 1:

5 to 1;

500.

9. The method as defined in claim 8, wherein said ratio of said lubricant to said organic base, said electrolyte and said solvent is 1:

50.

10. The method as defined in claim 1, wherein said solvent is acetone.

11. The method as defined in claim 1, wherein said electrolyte is lithium perchlorate (LiClO₄).

12. The method as defined in claim 1, wherein said electrolytic cell includes a microelectrode, a reference electrode, and an auxiliary electrode.

13. The method as defined in claim 12, wherein said microelectrode is a glassy carbon electrode.

14. The method as defined in claim 12, wherein said reference electrode is Ag/AgCl.

15. The method as defined in claim 12, wherein said auxiliary electrode is a platinum wire.

16. The method as defined in claim 1, wherein said first and second potential values are within the range of +1.5 V and -1.5 V.

17. The method as defined in claim 16, wherein said first and second potential values are, respectively, 0.0 V and +1.0 V.

18. The method as defined in claim 17, wherein said potential is varied at a rate within the range of 0.2 V/sec to 30.0 V/sec.

19. The method as defined in claim 17, wherein said potential is varied at a rate of 5.0 V/sec.

20. The method as defined in claim 1, comprising the further step of determining the maximum current produced during said reduction reaction.

21. The method as defined in claim 1, comprising the further steps of:

repeating varying of said potential from said first value to said second value and to said first value for a plurality of times; and

continuing to measure and record said current during at least said reduction reactions produced during said varying.

22. The method as defined in claim 21, wherein varying of said potential from said first value to said second value and to said first value is performed ten times.

23. The method as defined in claim 22, comprising the further step of determining the maximum current produced during each of the sixth through tenth of said reduction reactions, and calculating therefrom an average maximum current value.

24. A method for measuring the remaining useful life of an ester-based lubricant containing at least one antioxidant species, comprising the steps of:

mixing a lubricant sample with a solvent, an organic base and an electrolyte to produce an analysis sample;

placing said analysis sample into an electrolytic cell;

subjecting said analysis sample to a cyclic voltammetric analysis comprising a plurality of cycles, whereby a varying electric current is produced within said cell; and

measuring and recording said current during said cyclic voltammetric analysis.

25. The method as defined in claim 24, comprising the further step of determining a maximum current value during a reduction reaction portion of said cyclic voltammetric analysis.

26. The method as defined in claim 24, comprising the further steps of determining a maximum current value during a reduction reaction portion of each of said cycles of said cyclic voltammetric analysis, and calculating from at least some of said maximum current values an average maximum current value.

27. The method as defined in claim 24, wherein said cyclic voltammetric analysis includes ten cycles.