Hot melt magnetic sealant, method of making and method of using same

• US 4,749,434 A
• Filed: 08/31/1987
• Issued: 06/07/1988
• Est. Priority Date: 12/29/1986
• Status: Expired due to Term

• Current Assignee: Permacel Kansas City, Inc. (Nitto Denko Corporation)
• Original Assignee: United Technologies Automotive, Inc. (Lear Corporation)
• Inventors: Harrison, Bruce
• Primary Examiner(s): Jacobs, Lewis T.
• Application Number:
  US07/091,683
• Time in Patent Office: 281 Days
• Field of Search: 252/62.54, 523/400, 523/437, 523/438, 264/174, 264/211.12, 264/232, 156/306.9
• US Class Current: 156/306.9
• CPC Class Codes: C08K 3/10 Metal compounds
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 63/00 Compositions of epoxy resins; Compositions of derivatives of epoxy resins
• CPC Class Codes: C09J 7/10 without carriers

Abstract

A hot melt magnetic sealant that exhibits improved adhesion to oil covered galvanized ferrometallic substrates and to epoxy electrodeposition coated ferrometallic substrates is disclosed. The sealant comprises magnetic filler particles, a hydrocarbon resin, a tackifier resin, a plasticizer, an epoxy resin and an epoxy curing agent. A method for making a hot melt sealant tape comprising mixing a formulation of magnetizable particles, a hydrocarbon resin, a tackifier resin, a plasticizer, an epoxy resin and an epoxy curing agent, extruding the mixture to form a tape and exposing the tape to an electromagnetic field is also disclosed. Methods for using the magnetic sealant tape to seal a joint between ferrometallic members having oil covered galvanized surfaces or epoxy electrodeposition coated ferrometallic members comprising disposing the tape to cover the joint and heating the tape are also disclosed.

Claims

1. A method of sealing a joint between two ferrometallic members, at least one of which has an oil-covered, galvanized surface, comprising,:

(a) disposing a strip of hot melt magnetic sealant tape comprising, in weight percent;

about 8% to about 15% hydrocarbon resin, 0% to about 7% tackifier resin, about 5% to about 18% plasticizer, about 65% to about 72% magnetic particles, about 5% to about 15% epoxy resin and about 0.7% to about 2% epoxy curing agent, to cover said joint, the magnetic properties of the tape holding the tape in place,

(b) heating the magnetic sealant tape to allow the tape to conform with the joint, and

(c) heating the magnetic sealant tape to cure the tape,

said method providing a durable seal that is strongly adherent to the oil-covered, galvanized surface.

2. The method of claim 1, wherein the epoxy resin comprises the diglycidal ether of bisphenol A.

3. The method of claim 1, wherein the epoxy curing agent comprises a boron trichloride-amine complex.

4. A method of sealing a joint between two ferrometallic members, at least one of said members having a surface coated with an electrodeposited epoxy coating, comprising:

(a) disposing a tape of hot melt magnetic sealant tape comprising, in weight percent;

about 8% to about 14% hydrocarbon resin, 0% to about 7% tackifier resin, about 5% to about 18% plasticizer, about 65% to about 72% magnetic particles, about 5% to about 15% epoxy resin and about 0.7% to about 2% epoxy curing agent, to cover said joint, the magnetic properties of the tape holding the tape in place,

(b) heating the tape to allow the tape to conform to the joint, and

(c) heating the tape by exposure to elevated temperature in the range of about 240°

F. to about 300°

F. to cure the tape,

said method providing a durable seal that is strongly adherent to the electrodeposited epoxy coating.

5. The method of claim 4, wherein the epoxy resin comprises the diglycidal ether of bisphenol A.

6. The method of claim 4, wherein the epoxy curing agent comprises a boron trichloride-amine complex.