Production of paper and cardboard

• US 4,749,444 A
• Filed: 10/20/1986
• Issued: 06/07/1988
• Est. Priority Date: 11/21/1985
• Status: Expired due to Fees

• Current Assignee: BASF AG (BASF SE)
• Original Assignee: BASF AG (BASF SE)
• Inventors: Linhart, Friedrich, Matz, Manfred, Lorz, Rudolf, Auhorn, Werner
• Primary Examiner(s): Chin, Peter
• Application Number:
  US06/920,604
• Time in Patent Office: 596 Days
• Field of Search: 162/168.1, 162/168.2, 162/181.8, 162/183, 162/168.3
• US Class Current: 162/168.3
• CPC Class Codes: D21H 17/375 Poly(meth)acrylamide
• CPC Class Codes: D21H 17/455 comprising tertiary amine or being at least partially quaternised
• CPC Class Codes: D21H 17/55 Polyamides; Polyaminoamides; Polyester-amides
• CPC Class Codes: D21H 17/56 Polyamines; Polyimines; Polyester-imides
• CPC Class Codes: D21H 17/68 siliceous, e.g. clays
• CPC Class Codes: D21H 23/765 Addition of all compounds to the pulp

Abstract

Paper and cardboard are produced by draining a paper stock by a method in which a stock having a consistency of from 2.5 to 5% by weight is used as a starting material, and (a) from 0.1 to 2% by weight of an activated bentonite are added and the stock consistency is then brought to 0.3-2% by weight by dilution with water, after which (b) from 0.01 to 0.1% by weight of a cationic polyelectrolyte having a charge density of not less than 4 meq/g of polyelectrolyte is added and distributed therein, and, after thorough mixing (c) from 0.003 to 0.3% by weight of a high molecular weight polymer based on acrylamide or methacrylamide is metered in and mixed with the paper stock, the percentages in each case being based on dry paper stock, and the resulting pulp is drained on a wire. The paper obtained is distinguished in particular by good printing properties in the offset printing process.

Claims

1. A process for the production of paper and cardboard by draining a paper stock, wherein

(a) from 0.1 to 2% by weight of a water-swellable bentonite is added to an aqueous pulp whose stock consistency is from 2.5 to 5% by weight and the stock consistency is then brought to 0.3-2% by weight by dilution with water,

(b) from 0.01 to 0.1% by weight of a cationic polyelectrolyte having a charge density of not less than 4 meq/g (measured at pH 4.5) of polyelectrolyte is added and distributed therein, and after thorough mixing, from

(c) 0.003 to 0.03% by weight of a high molecular weight polymer based on acrylamide or methacrylamide having a maximum charge density of about 3.5 meq/g (measured at pH 4.5) is metered in and mixed with the paper stock, and the resulting pulp is drained on a wire, the percentages of (a), (b) and (c) each being based on dry paper stock.

2. A process as claimed in claim 1, wherein polyethyleneimines, water-soluble crosslinked condensates containing ethyleneimine as condensed units and based on polyamidoamines, polyetheramines, polyvinylamines, polydiallylammonium chloride and/or not less than 10 mol % of hydrolyzed poly-N-vinylformamides are used as component (b).

3. A process as claimed in claim 1, wherein homopolymers of acrylamide and methacrylamide which have a weight average molecular weight of from 1,000,000 to 20,000,000 are used as component (c).

4. A process as claimed in claim 1, wherein copolymers of acrylamide and one or more anionic monomers from the group consisting of the ethylenically unsaturated C₃ -C₅ -carboxylic acids, vinylsulfonic acid, acrylamidopropanesulfonic acids and/or their alkali metal, ammonium and amine salts are used as component (c).

5. A process as claimed in claim 1, wherein copolymers of acrylamide and one or more cationic monomers from the group consisting of di-C₁ - or C₂ -alkylamino-C₂ -alkyl C₆ -(meth)acrylates, di-C₁ - or C₂ -alkylamino-C₆ -C₂ -alkyl (meth)acrylamides, N-vinylimidazoles, N-vinylpyridines and N-vinylimidazolines, if appropriate in quarternized form or as salts, and diallyldi-C₁ - or C₂ -alkylammonium halides are used as component (c).