Selective-permeation gas-separation process and apparatus

• US 4,750,918 A
• Filed: 05/28/1985
• Issued: 06/14/1988
• Est. Priority Date: 05/28/1985
• Status: Expired due to Term

• Current Assignee: The Trustees of The Stevens Institute of Technology (Stevens Institute Of Technology)
• Original Assignee: The Trustees of The Stevens Institute of Technology (Stevens Institute Of Technology)
• Inventors: Sirkar, Kamalesh K.
• Primary Examiner(s): SPITZER, ROBERT H
• Application Number:
  US06/738,793
• Time in Patent Office: 1,113 Days
• Field of Search: 55/16, 55/158, 423/226, 423/228, 423/229, 423/232, 423/242, 423/243
• US Class Current: 95/44
• CPC Class Codes: B01D 2251/304 of sodium
• CPC Class Codes: B01D 2251/306 of potassium
• CPC Class Codes: B01D 2251/606 Carbonates
• CPC Class Codes: B01D 2252/10 Inorganic absorbents chemical reactants B01D2251/00
• CPC Class Codes: B01D 2252/20484 with one hydroxyl group
• CPC Class Codes: B01D 2252/20489 with two or more hydroxyl groups
• CPC Class Codes: B01D 2256/245 Methane
• CPC Class Codes: B01D 2257/304 Hydrogen sulfide
• CPC Class Codes: B01D 2257/502 Carbon monoxide
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2258/05 Biogas
• CPC Class Codes: B01D 2317/08 Use of membrane modules of different kinds
• CPC Class Codes: B01D 2319/06 Use of membranes of different materials or properties within one module
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: B01D 53/22 by diffusion manufacturing semi-permeable membranes B01D67/00; form, structure or properties of semi-permeable membranes B01D69/00; material for semi-permeable membranes B01D71/00
• CPC Class Codes: B01D 53/229 Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
• CPC Class Codes: B01D 61/38 Liquid-membrane separation
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A permeant gas is selectively transferred from a feed-gas mixture which comprises the permeant gas and at least one other component to an output fluid by the process of the invention. The process involves introducing a selective-permeation liquid into a permeation-transfer chamber. A gas-depletion channel and a gas-enrichment channel pass through the permeation chamber and are separated from the chamber respectively by porous walls. The selective-permeation liquid contacts the porous walls but does not flow into the gas-depletion or gas-enrichment channels. The feed-gas mixture is introduced into the gas-depletion channel so that permeant gas in the mixture can pass through the pores of the walls of the channel into the selective-permeation liquid and from the selective-permeation liquid through the pores of the walls of the gas-enrichment channel into the gas-enrichment channel. Permeant gas is withdrawn from the gas-enrichment channel and a stream of gas depleted in the permeant gas is withdrawn from the gas-depletion channel. A gas-transfer unit permits the process of the invention to be carried out effectively.

Claims

1. A process for separating a permeant gas from a feed-gas mixture, the feed-gas mixture comprising the permeant gas and at least one other gaseous component, the process comprising the steps of:

(a) introducing a selective-permeation liquid into a permeation-transfer chamber, the selective-permeation liquid being selectively permeable to the permeant gas relative to the other component of the feed-gas mixture, a gas-depletion channel extending through the permeation-transfer chamber, the gas-depletion channel being separated from the permeation-transfer chamber by a gas-depletion porous wall, a gas-enrichment channel extending through the permeation-transfer chamber disjoint from the gas-depletion channel, the gas-enrichment channel being separated from the permeation-transfer chamber by a gas-enrichment porous wall, the gas-depletion and gas enrichment porous walls being in close proximity to one another, the gas-enrichment channel and the gas-depletion channel together defining gas-transfer channels, regions adjacent to the porous walls of the gas-transfer channels and exterior of the channels within the permeation-transfer chamber constituting open passages to permit a substantially free liquid passage of the selective-permeation liquid so that surfaces of the porous walls of the gas-transfer channels are contacted by the selective-permeation liquid in the permeation-transfer chamber;

(b) introducing a stream of the feed-gas mixture into the gas-depletion channel and allowing the feed-gas mixture to flow through the channel in the permeation-transfer chamber so that permeant gas in the feed gas mixture can pass through the pores of the walls of the gas-depletion channel into the selective permeation liquid in the permeation-transfer chamber and from the selective-permeation liquid through the pores of the walls of the gas-enrichment channel into the gas-enrichment channel;

(c) maintaining a difference between the pressure of the selective-permeation liquid in the permeation-transfer chamber and the pressure of the gas in the gas-depletion channel at a value which substantially prevents the selective permeation liquid from flowing through the gas-depletion porous wall into the gas-depletion channel and substantially prevents gas in the gas-depletion channel from flowing through the gas-depletion porous wall into the permeation-transfer chamber;

(d) maintaining a difference between the pressure of the selective permeation liquid in the permeation-transfer chamber and the pressure of the fluid in the gas-enrichment channel at a value which substantially prevents the selective-permeation liquid from flowing through the gas-enrichment porous wall into the gas-enrichment channel and substantially prevents fluid in the gas-enrichment channel from flowing through the gas-enrichment porous wall into the permeation-transfer chamber;

(e) withdrawing permeant gas from the gas-enrichment channel; and

(f) withdrawing a stream of gas depleted in the permeant gas from the gas-depletion channel.

2. The process according to claim 1 in which the gas-depletion channel comprises the lumina of a multiplicity of porous-wall hollow fibers which extend through the permeation-transfer chamber and the gas-enrichment channel comprises the lumina of a multiplicity of a porous-wall hollow fibers which extend through the permeation-transfer chamber.

3. A process for separating a permeant gas from a feed-gas mixture, the feed-gas mixture comprising the permeant gas and at least one other gaseous component, the process comprising the steps of:

(a) introducing a selective-permeation liquid into a permeation-transfer chamber, the selective-permeation liquid being selectively permeable to the permeant gas relative to the other component of the feed-gas mixture, a first multiplicity of porous-wall hollow fibers extending through the permeation-transfer chamber to define gas-depletion hollow fibers, a second multiplicity of porous-wall hollow fibers extending through the permeation-transfer chamber to define gas-enrichement hollow fibers, the gas-depletion and the gas-enrichment hollow fibers commingling in close proximity to one another in the permeation-transfer chamber, the gas-enrichment hollow fibers and the gas-depletion hollow fibers together defining gas-transfer hollow fibers, radially-outer surfaces of the walls of the permeant-gas-transfer hollow fibers being contacted by the selective-permeation liquid in the permeation-transfer chamber, surfaces of the walls of the gas-transfer hollow fibers in the permeation-transfer chamber being composed of a material which tends not to be wetted by the selective-permeation liquid;

(b) introducing a stream of the feed-gas mixture into the lumina of the gas-depletion hollow fibers and allowing the feed-gas mixture to flow through the lumina in the permeation-transfer chamber so that the permeant gas in the feed gas mixture can pass through the pores of the walls of the gas-depletion hollow fibers into the selective permeation liquid in the permeation-transfer chamber and from the selective-permeation liquid through the pores of the walls of the gas-enrichment hollow fibers into the lumina of the fibers;

(c) withdrawing permeant gas from the lumina of the gas-enrichment hollow fibers; and

(d) withdrawing a stream of gas depleted in the permeant gas from the lumina of the gas-depletion hollow fibers.

4. The process according to claim 3 further comprising the step of introducing a sweep fluid into the lumina of the gas-enrichment hollow fibers.

5. The process according to claim 4 in which the sweep fluid is a gas and the step of withdrawing permeant gas from the lumina of the gas-enrichment hollow fibers comprises withdrawing a stream of gas enriched in the permeant gas from the lumina of the gas enrichment hollow fibers.

6. The process according to claim 5 in which the stream of feed-gas mixture is introduced into the lumina of the gas-depletion hollow fibers at a location outside of the permeation-transfer chamber, the stream of sweep gas is introduced into the gas-enrichment hollow fibers at a location outside of the permeation-transfer chamber, the stream of gas enriched in the permeant gas is withdrawn from the lumina of the gas-enrichment hollow fibers at a location outside of the permeation-transfer chamber, and the stream of gas depleted in the permeant gas is withdrawn from the lumina of the gas-depletion hollow fibers at a location outside of the permeation-transfer chamber.

7. The process according to claim 3 in which the gas-transfer hollow fibers are made of a hydrophobic material and the selective-permeation liquid is an aqueous solution.

8. The process according to claim 7 in which the gas-transfer hollow fibers are made of porous polypropylene, porous polyethylene or porous polytetrafluoroethylene.

9. The process according to claim 7 in which the permeant-gas is carbon dioxide and the selective-permeation liquid is an aqueous solution of an alkali-metal carbonate.

10. The process according to claim 7 in which the permeant gas is selected from the group consisting of carbon dioxide and hydrogen sulfide and the selective-permeation liquid comprises an amine selected from the group consisting of monoethanolamine, diethanolamine and hindered amines.

11. The process according to claim 7 in which the permeant-gas is carbon dioxide or carbon monoxide and the selective-permeation liquid is an aqueous solution of cuprous chloride and an alkali-metal chloride.

12. The process according to claim 7 in which the permeant gas is sulfur dioxide and the selective-permeation liquid is an aqueous solution of a salt selected from the group consisting of an alkali metal bisulfate and an alkali metal sulfite.

13. The process according to claim 7 in which the permeant gas is selected from the group consisting of ethylene and propylene and the selective-permeation liquid is an aqueous solution of water-soluble silver salt.

14. The process according to claim 7 in which the permeant gas is sulfur dioxide and the selective-permeation liquid is selected from the group consisting of sulfolane and polyethylene glycol.

15. The process according to claim 7 in which the permeant gas is ethanol and the selective permeation liquid is a non-polar organic liquid having a boiling point substantially higher than the boiling point of ethanol.

16. The process according to claim 5 further comprising the step of maintaining the selective-permeation liquid in the permeation-transfer chamber at a pressure higher than the pressure of the gas in the gas-depletion fibers and higher than the pressure of the gas in the gas enrichment fibers.

17. The process according to claim 3 in which each gas-transfer fiber includes a first and a second radial layer, the first radial layer being composed of a porous hydrophilic material and the second radial layer being composed of a porous hydrophobic layer.

18. A gas-transfer unit for selectively transferring a permeant gas from a feed-gas mixture comprising the permeant gas and at least one other component to an output fluid, the gas-transfer unit comprising:

(a) a fluid-tight housing, an interior of the housing defining a gas-transfer chamber, the housing having a feed-gas input port, a depleted-gas output port, a sweep-fluid input port, an enriched-gas output port and a selective-permeation liquid inlet port, the five ports providing communication with the gas-transfer chamber;

(b) gas-depletion porous-wall means located within the gas-transfer chamber for forming at least a portion of a wall of a gas-depletion channel which passes through the gas-transfer chamber, the gas-depletion channel connecting the feed-gas input port to the depleted-gas output port;

(c) gas-enrichment porous-wall means located within the gas-transfer chamber for forming at least a portion of a wall of a gas-enrichment channel which passes through the gas-transfer chamber, the gas-enrichment channel connecting the sweep-fluid input port to the enriched-gas output port, the gas-enrichment channel being disjoint from the gas-depletion channel, a region within the gas-transfer chamber and outside of the gas-enrichment channel and the gas-depletion channel defining a selective-permeation chamber, the selective-permeation-liquid inlet port providing communication with the selective-permeation chamber, the selective-permeation chamber including open passages adjacent to the gas-depletion porous-wall means and the gas-enrichment porous-wall means to permit a substantially free liquid passage of a preselected selective-permeation liquid introduced into the selective-permeation chamber through the selective-permeation-liquid inlet port to contact the gas-depletion porous-wall means and the gas-enrichment porous-wall means, the gas-depletion porous-wall means and the gas-enrichment porous-wall means being made of a material which tends to prevent the selective-permeation liquid in the selective-permeation chamber from flowing into the gas-depletion channel and into the gas-enrichment channel, so that a selective-permeation liquid can be confined in the selective-permeation chamber to facilitate the selective transfer of the permeant gas from the gas-depletion channel to the gas-enrichment channel of the gas-transfer unit.

19. The gas-transfer unit according to claim 18 in which:

the gas-depletion porous-wall means forms a multiplicity of gas-depletion hollow fibers, the lumina of the gas-depletion hollow fibers comprising the gas-depletion channel;

the gas enrichment porous-wall means forms a multiplicity of gas-enrichment hollow fibers, the lumina of the gas-enrichment hollow fibers comprising the gas-enrichment channel.