Dispersion strengthened metal composites

• US 4,752,334 A
• Filed: 12/13/1983
• Issued: 06/21/1988
• Est. Priority Date: 12/13/1983
• Status: Expired due to Term

• Current Assignee: SCM Metal Products Incorporated Western Reserve Building
• Original Assignee: SCM Metal Products, Inc. (Kymera International)
• Inventors: Synk, James E., Samal, Prasanna K., Nadkarni, Anil V.
• Primary Examiner(s): Terapane, John F.
• Assistant Examiner(s): Jorgensen, Eric
• Application Number:
  US06/561,035
• Time in Patent Office: 1,652 Days
• Field of Search: 75/232, 75/234, 75/235, 75/0.5 BC, 75/951, 419/19, 419/41, 419/4, 428/558, 200/144 B
• US Class Current: 75/235
• CPC Class Codes: B22F 1/12 Metallic powder containing non-metallic particles containing lubricating or binding agents or organic material B22F1/10
• CPC Class Codes: B22F 2998/00 Supplementary information concerning processes or compositions relating to powder metallurgy
• CPC Class Codes: B22F 9/082 atomising using a fluid using centrifugal force B22F9/10
• CPC Class Codes: C22C 32/0021 Matrix based on noble metals, Cu or alloys thereof
• CPC Class Codes: H01H 1/025 having copper as the basic material
• CPC Class Codes: H01R 13/03 characterised by the material, e.g. plating, or coating materials
• CPC Class Codes: Y10S 75/951 Oxide containing, e.g. dispersion strengthened
• CPC Class Codes: Y10T 428/12097 Nonparticulate component encloses particles

Abstract

There is provided a substantially fully dense powdered metal composite comprising a highly conductive metal or metal alloy matrix having dispersed therein discrete microparticles of a refractory metal oxide and discrete macroparticles of an additive metal or metal alloy, such as a nickel/iron alloy. The respective components undergo minimal alloying because sintering is not utilized in forming the composite. These composites are characterized by high thermal or electrical conductivity and a desired property attributable to the composite forming additive metal or metal alloy. The composites are useful in forming lead frames for integrated circuit chips, electric lamp lead wires, and electrical contact members.

Claims

1. A substantially fully dense compacted and unsintered powdered metal composite comprising (a) a metal or metal alloy matrix having uniformly dispersed therein discrete microparticles of a refractory metal oxide and (b) discrete macroparticles of a metal, metal alloy or metal compound selected from the group consisting of the metals molybdenum, titanium, and niobium, the metal alloys of nickel with iron, nickel with iron and cobalt, cobalt with iron, nickel with chromium, nickel with molybdenum, chromium with molybdenum, and the metal compound titanium carbide, said components (a) and (b) being no more than minimally alloyed together.

2. A substantially fully dense composite as defined in claim 1 wherein the refractory metal oxide is aluminum oxide.

3. A substantially fully dense composite as defined in claim 2 wherein the concentration of aluminum in the matrix is in the weight range of from 0.01% to about 5%.

4. A substantially fully dense composite as defined in claim 1 wherein componenent (a) is a dispersion strengthened metal having an electrical resistivity below 8×

10^-6 ohm-cm.

5. A substantially fully dense composite as defined in claim 1 wherein component (a) is dispersion strengthened copper.

6. A substantially fully dense composite as defined in claim 1 wherein component (a) is a dispersion strengthened copper, and said composite has a coefficient of thermal expansion below 13×

10^-6 /°

C. at 20°

C.

7. A substantially fully dense composite as defined in claim 1 wherein component (a) is dispersion strengthened copper alloy.

8. A substantially fully dense unsintered powdered metal composite comprising (a) a metal alloy matrix having uniformly dispersed therein discrete microparticles of a metal oxide and (b) discrete macroparticles of an additive metal or its alloys or its compounds.

9. A substantially fully dense composite as defined in claim 8 wherein said additive metal or its alloy is molybdenum,--or--niobium.

10. A substantially fully dense compacted and unsintered powdered metal composite comprising (a) a copper-tin alloy matrix having uniformly dispersed therein discrete microparticles of a refractory metal oxide and (b) discrete macroparticles of a metal, metal alloy or metal compound selected from the group consisting of the metals molybdenum, tungsten, titanium, and niobium, the metal alloys of nickel with iron, nickel with cobalt and iron, cobalt with iron, nickel with chromium, nickel with molybdenum, chromium with molybdenum, and the metal compounds tungsten carbide and titanium carbide, said components (a) and (b) being no more than minimally alloyed together.

11. A substantially fully dense composite as defined in claim 10 wherein the metal alloy of nickel and iron contains from 30% to 55% nickel by weight.

12. A substantially fully dense composite as defined in claim 11 wherein the metal alloy of nickel and iron contains about 42% by weight nickel.

13. A substantially fully dense compacted and unsintered powdered metal composite comprising (a) a metal or metal alloy matrix having uniformly dispersed therein discrete microparticles of a refractory metal oxide and (b) discrete macroparticles of metal, metal alloy or metal compound selected from the group consisting of the metals molybdenum, tungsten, titanium, and niobium, the metal alloys of nickel with iron, nickel with iron and cobalt, cobalt with iron, nickel with chromium, nickel with molybdenum, chromium with molybdenum, and the metal compounds tungsten carbide and titanium carbide, said components (a) and (b) being no more than minimally alloyed together wherein the composite is contained within at least one metallic sheath.

14. A substantially fully dense composite as defined in claim 13 wherein the metallic sheath is nickel.

15. A substantially fully dense composite as defined in claim 13 wherein the metallic sheath is copper.

16. A substantially fully dense compacted and unsintered powdered metal composite comprising (a) a metal or metal alloy matrix having uniformly dispersed therein discrete microparticles of a metal oxide and (b) discrete macroparticles of an additive metal, or its alloys, or its intermetallic compounds, and wherein the composite is contained within at least one metallic sheath.

17. A substantially fully dense composite as defined in claim 16 wherein the metallic sheath is nickel.

18. A substantially fully dense composite as defined in claim 16 wherein the metallic sheath is copper.

19. A substantially fully dense compacted and unsintered powdered metal composite comprising (a) dispersion strengthened copper having uniformly dispersed therein discrete microparticles of aluminum oxide and (b) discrete macroparticles of a metal alloy of nickel with iron, said components (a) and (b) being no more than minimally alloyed together.