Optical information recording medium

• US 4,752,554 A
• Filed: 06/02/1986
• Issued: 06/21/1988
• Est. Priority Date: 11/02/1983
• Status: Expired due to Term

• Current Assignee: Ricoh Company Limited
• Original Assignee: Ricoh Company Limited
• Inventors: Sato, Tsutomu, Oba, Hideaki
• Primary Examiner(s): Thomas, Alexander S.
• Application Number:
  US06/870,201
• Time in Patent Office: 750 Days
• Field of Search: 428/64, 428/65, 430/945, 430/273, 430/961, 369/284, 369/286, 369/288, 346/135.1
• US Class Current: 430/270.21
• CPC Class Codes: G11B 7/244 comprising organic materials only
• CPC Class Codes: G11B 7/245 containing a polymeric component
• CPC Class Codes: G11B 7/246 containing dyes
• CPC Class Codes: G11B 7/2472 cyanine
• CPC Class Codes: G11B 7/254 of protective topcoat layers
• CPC Class Codes: Y10S 430/146 Laser beam
• CPC Class Codes: Y10S 430/162 Protective or antiabrasion layer

Abstract

The present invention relates to an optical information recording medium comprising a substrate, recording layer and protective layer, characterized in that said protective layer comprises, as the main components, a high molecular compound and at least one of record-promoting agents selected from the group of (a) explosive material, (b) plasticizer, (c) organic low molecular compound having a melting point not higher than 140° C., and (d) light-absorbing material.

Claims

1. In an optical information recording medium comprising a substrate, a light-reflective recording layer comprising a cyanine organic coloring matter and a protective layer, the improvement which comprises:

said protective layer comprises, as the main components, a high molecular weight binder and a plasticizer, said plasticizer being used in an amount of 20-60% by weight, based on the total weight of the protective layer, and said plasticizer being selected from the group consisting of phosphoric acid ester plasticizers, phthalic acid ester plasticizers, aliphatic acid ester plasticizers, dihydric alcohol ester plasticizers, oxyacid ester plasticizers, chlorinated paraffin, chlorinated biphenyl and 2-nitrobiphenyl.

2. The optical information recording medium according to claim 1, wherein said protective layer has a thickness of 0.5 μ

m-500 μ

m.

3. The optical information recording medium according to claim 1, wherein said protective layer has a thickness of 10 μ

m-200 μ

m.

4. The optical information recording medium according to claim 1, wherein said plasticizer is a phthalic acid ester.

5. The optical information recording medium according to claim 1, wherein said plasticizer is an aliphatic acid ester.

6. The optical information recording medium according to claim 1, wherein said plasticizer is a dihydric alcohol ester.

7. The optical information recording medium according to claim 1, wherein said plasticizer is an oxyacid ester.

8. The optical information recording medium according to claim 1, wherein said recording layer also contains a resin.

9. The optical information recording medium according to claim 1, wherein said recording layer consists of a cyanine colorant.

10. The optical information recording medium according to claim 9, wherein said cyanine colorant is an indolenine colorant.

11. The optical information recording medium according to claim 10, wherein said indolenine colorant is 1-methyl-2-(7-(1-methyl-3,3'"'"'-dimethyl-5-halo-2-indolinilidene)-1,3,5-heptatrienyl)-3,3-dimethyl-5-halo-indolium perchlorate.

12. The optical information recording medium according to claim 10, wherein said recording layer is applied to spin-coating.

13. The optical information recording medium according to claim 1, wherein said recording layer has a thickness of 100-5000 Å

.

14. The optical information recording medium according to claim 1, wherein said recording layer has a thickness of 100-1000 Å

.

15. The optical information recording medium according to claim 1, wherein said recording layer has a thickness of 200-600 Å

.

16. An optical information recording medium comprising:

a support;

a light-sensitive recording layer on said support, said recording layer consisting essentially of indolenine cyanine colorant, said recording layer having a thickness of from 200 to 600 Angstrom units; and

a protective layer covering said recording layer, said protective layer having a thickness of from 10 to 200 micrometers and consisting essentially of a blend of a binder resin and a plasticizer for said binder resin, said plasticizer comprising from 20 to 60% by weight of the total weight of said protective layer and being selected from the group consisting of phosphoric acid ester plasticizers, phthalic acid ester plasticizers, aliphatic acid ester plasticizers, dihydric alcohol ester plasticizers, oxyacid ester plasticizers, chlorinated paraffin, chlorinated biphenyl and 2-nitrobiphenyl.

17. An optical information recording medium as claimed in claim 16 in which said plasticizer is selected from the group consisting of dibutyl phthalate, methoxyethyl acetylricinoloeate, tetrahydrofurfuryl oleate, dibutyl maleate, diethylene glycol dibenzoate, acetyltriethyl citrate, 1,3-butylene glycol adipate and chlorinated paraffin.

18. An optical information recording medium as claimed in claim 16 in which said plasticizer is methoxyethyl acetylricinoleate.

19. An optical information recording medium as claimed in claim 16 in which said plasticizer is tetrahydrofurfuryl oleate.