Capacitative-type humidity sensing element and system, and method of manufacture

• US 4,752,855 A
• Filed: 03/17/1987
• Issued: 06/21/1988
• Est. Priority Date: 04/16/1986
• Status: Expired due to Fees

• Current Assignee: Robert Bosch GmbH
• Original Assignee: Robert Bosch GmbH
• Inventors: De La Prieta, Claudio, Nolting, Peter, Schmid, Kurt, Fedter, Horst, Grunwald, Werner
• Primary Examiner(s): Levy, Stewart J.
• Assistant Examiner(s): Raevis, Robert R.
• Application Number:
  US07/026,866
• Time in Patent Office: 462 Days
• Field of Search: 73/335, 73/336, 73/336.5, 73/29, 252/518, 252/521, 338/35, 236/44 A, 29/25.41, 361/286
• US Class Current: 361/286
• CPC Class Codes: G01N 27/225 by using hygroscopic materials

Abstract

A humidity sensor, and particularly a sensor which can distinguish between low humidity values, for example below 60% humidity, and high humidity values, for example 90% humidity and thereover, and change the capacitance between output electrodes (5, 6) is formed by applying interdigited comb electrodes (1, 2) on a substrate (8) and applying over the substrate a ceramic mass formed of BaRuO₃, V₂ O₅ and Na₂ WO₄, with a weight relationship of (1±0.4):(1±0.4):(0.6±0.2) preferably 1:1:0.6. The sensor is made by first making a powder of the components, mixing it with a glass paste and, if necessary, a thinner, and applying the resulting paste by thick-film technology to a ceramic substrate on which the electrodes have been applied, and then firing the substrate at a temperature of between 550° C. to 850° C. The sensor is particularly sensitive in humidity ranges above 60% relative humidity and is especially suitable to sense fogging of the inside of a windshield of an automotive vehicle.

Claims

1. A method of making a capacitative-type humidity sensor, to measure relative humidity by change of capacitance between two electrodes located on a substrate, in which a ceramic material is applied between the electrodes,

comprising the steps of

homogenizing a mixture of BaRuO₃, V₂ O₅ and Na₂ WO₄ ;

presintering said homogenized mixture;

adding the presintered mixture to a glass paste to form an application paste;

applying the application paste between said two electrodes; and

firing the substrate with the electrodes and the application paste to form said ceramic material.

2. The method of claim 1, wherein said step of applying the application paste comprises applying said application paste by thick-film technology.

3. The method of claim 1, wherein the mixture is present in a ratio of about 1:

1;

0.6 by weight;

said presintering step is carried out at about 850°

C.;

the presintered mixture is ground to a powder;

the step of adding the presintered mixture to the glass paste comprises adding said powder to said glass paste to provide a mixture having 10 to 20% of glass paste;

and wherein said firing step is carried out between about 550°

C. to 850°

C.

4. The method of claim 3, further comprising the step of adding a thinner to the glass paste until the resulting glass paste, powder and thinner is capable of being printed by thick-film technology.

6. The method of claim 1, wherein BaRuO₃, V₂ O₅ and Na₂ WO₄ are present in a relationship, by weight, of (1±

0.4);

(1±

0.4);

(0.6±

0.2).

5. The method of claim 5, wherein the substrate (8) comprises Al₂ O₃, and the electrodes are applied to a surface thereof in interdigited or double-comb form.

7. A mixture for manufacturing a capacitative-type humidity sensor, wherein the mixture is applied between two capacitative measuring electrodes and fired, said mixture comprising

a mixture of ceramic material consisting essentially of BaRuO₃, V₂ O₅ and Na₂ WO₄ with glass paste.

8. The mixture of claim 7, wherein the components of the mixture are present in a proportion--by weight--of (1±

0.4);

(1±

0.4);

(0.6±

0.2).

9. The mixture of claim 7, wherein the components of the mixture are present in a proportion--by weight--of 1:

1;

0.6.

10. A capacitative-type relative humidity sensor

comprising a ceramic substrate;

two interdigited double-comb electrodes applied to the substrate;

and a homogenized thick-film ceramic located between said electrodes comprising a fired mixture of BaRuO₃, V₂ O₅ and Na₂ WO₄.

11. The sensor of claim 10, wherein the components of the mixture are present in a proportion--by weight--of (1±

0.4);

(1±

0.4);

(0.6±

0.2).

12. The sensor of claim 10, wherein the components of the mixture are present in a proportion--by weight--of 1:

1;

0.6.

13. In an automotive vehicle, a capacitative-type humidity sensor positioned within the passenger copartment of the vehicle, said humidity sensor comprising

a ceramic substrate plate;

interdigited comb-like electrodes applied to the surface of said plate;

and a ceramic material on said substrate plate between said electrodes, said ceramic material comprising a fired powder mixture of BaRuO₃, V₂ O₅ and Na₂ WO₄, and a glass paste to form said ceramic material, which changes the capacitance between the electrodes upon change in ambient humidity in said passenger compartment.

14. The sensor of claim 13, wherein said sensor is applied to the windshield of the motor vehicle to form a fogging sensor for the windshield.

15. The sensor of claim 13, wherein the components of the mixture are present in a proportion--by weight--of (1±

0.4);

(1±

0.4);

(0.6±

0.2).

16. The sensor of claim 13, wherein the components of the mixture are present in a proportion--by weight--of 1:

1;

0.6.