Photovoltaic heterojunction structures

• US 4,753,684 A
• Filed: 10/31/1986
• Issued: 06/28/1988
• Est. Priority Date: 10/31/1986
• Status: Expired due to Term

• Current Assignee: Standard Oil Company (BP PLC)
• Original Assignee: Standard Oil Company (BP PLC)
• Inventors: Ondris, Miroslav, Pichler, Marty A.
• Primary Examiner(s): Weisstuch, Aaron
• Application Number:
  US06/926,283
• Time in Patent Office: 606 Days
• Field of Search: 136/255, 136/258 PC, 136/260, 136/264, 136/265, 357/16, 357/30 E, 357/30 K, 357/59 D
• US Class Current: 136/258
• CPC Class Codes: H01L 31/073 comprising only AIIBVI compound semiconductors, e.g. CdS/CdTe solar cells
• CPC Class Codes: H01L 31/1832 comprising ternary compounds, e.g. Hg Cd Te
• CPC Class Codes: Y02E 10/543 Solar cells from Group II-VI materials

Abstract

A three layer, photovoltaic structure having polycrystalline semiconductor layers disposed in series optically and in sequential touching contact includes a relatively wide optical bandgap energy window layer, a light-absorbing layer and a third, relatively wide bandgap energy layer that forms a minority carrier mirror with the light-absorbing layer. All three layers have different compositions so that the structure includes two heterojunctions. The light-absorbing layer and third layer are of the same conductivity type. The structure is conveniently realized using II-VI semiconductor compounds such as a cadmium sulfide or zinc sulfide window layer, a mercury cadmium telluride, cadmium telluride, zinc cadmium telluride or mercury zinc telluride light-absorbing layer and a third layer of cadmium telluride, zinc telluride, zinc cadmium telluride, mercury cadmium telluride or cadmium manganese telluride. Cadmium is present in at least two of the three layers of the novel structures. Tellurium is present in two of the three layers. Structures according to the invention may be conveniently formed by electrodeposition and may employ opaque or transparent substrates depending on the particular semiconductor materials used and their relative positions.

Claims

1. An improved photovoltaic structure comprising:

three layers of polycrystalline semiconductor materials for the production and collection of electronic charge carriers generated in response to the incidence of light on said layered structure, said layers being disposed in series optically and in sequential touching contact;

wherein each layer has a different composition so that a heterojunction is formed at each of the two junctions between said three layers, two of said layers are of a first conductivity type and are in touching contact at one of said heterojunctions, the third layer is of a conductivity type opposite said first conductivity type, at least two of said layers contain cadmium as a principal constituent, two of said layers contain tellurium as a principal constituent, and the central layer between the two other layers of said structure is selected from the group consisting of n-type cadmium telluride, p-type Cd_x Hg_1-x Te, p-type Cd_x Zn_1-x Te, and p-type Hg_x Zn_1-n Te , where x ranges from greater than zero to less than one.

2. The structure of claim 1 wherein x varies with position within said central layer along a line passing through said central layer and connecting said heterojunctions, whereby the performance of said structure is improved.

3. The structure of claim 1 wherein at least one of said layers contains sulfur as a principal constituent.

4. The structure of claim 3 wherein one of said layers disposed in contact with the central layer is selected from the group consisting of n-type Cd_y Zn_1-y S, where y ranges from more than zero to no more than one.

5. The structure of claim 1 wherein one of said layers disposed in contact with the central layer is selected from the group consisting of Cd_z Zn_1-z Te and Cd_z Mn_1-z Te, where z ranges from zero to no more than one.

6. The structure of claim 1 where one of said three layers is n-type Cd_y Zn_1-y S, where y ranges from greater than zero to no more than one, the central layer is one of p-type Cd_x Hg_1-x Te, Cd_x Zn_1-x Te and Hg_x Zn_1-n Te , where x ranges from zero to less than one, and the other layer in contact with said central layer is p-type Cd_z Zn_1-z Te, where z ranges from greater than zero to no more than one, and z is greater than x when two layers each contain cadmium, zinc and tellurium.

7. The structure of claim 6 wherein x varies with position within said central layer along a line passing through said central layer and connecting said heterojunctions, whereby performance of the structure is improved.

8. The structure of claim 1 wherein one of said three layers is n-type CdS, the central layer is p-type Cd_x Hd_1-x Te, where x ranges from zero to less than one, and the other layer in contact with said central layer is p-type Cd_z Hg_1-z Te, where z ranges from greater than zero to less than one and z is greater than x.

9. An improved photovoltaic structure comprising:

three layers of polycrystalline semiconductor materials for the production and collection of electronic charge carriers generated in response to the incidence of light on said layered structure, said layers being disposed in series optically and in sequential touching contact, wherein each layer has a different composition so that a heterojunction is formed at each of the two junctions between the three layers, two of said layers are of a first conductivity type and are in touching contact at one of said heterojunctions, the third layer is of a conductivity type opposite the first conductivity type, and one of said three layers is n-type cadmium sulfide, the central layer in contact with the other two layers is cadium telluride and the other layer in contact with said central layer is p-type Cd_z Zn_1-z Te where z ranges from zero to less than one.

10. The structure of claim 9 wherein said central layer is p-type cadmium telluride.

11. The structure of claim 9 wherein said central layer is n-type cadmium telluride.