Process using light and light activated adhesive compositions to secure light opaque end caps to fluorescent tubes

• US 4,753,704 A
• Filed: 06/30/1986
• Issued: 06/28/1988
• Est. Priority Date: 06/30/1986
• Status: Expired due to Fees

• Current Assignee: Loctite Corporation (Henkel AG & Co KGaA)
• Original Assignee: Loctite Corporation (Henkel AG & Co KGaA)
• Inventors: Stewart, John J.
• Primary Examiner(s): Cashion, Jr., Merrell C.
• Application Number:
  US06/879,680
• Time in Patent Office: 729 Days
• Field of Search: 428/36, 427/67, 427/54.1, 313/318, 313/493, 445/26, 250/492.1, 350/168-169, 156/69, 156/272.2, 156/272.4, 156/273.5, 156/294, 156/273.9, 156/275.1, 156/275.3, 156/275.5, 156/275.7, 156/293, 156/303.1, 156/308.4, 156/309. 6
• US Class Current: 156/275.5
• CPC Class Codes: B29C 65/1403 characterised by the type of electromagnetic or particle radiation B29C65/1603 takes precedence
• CPC Class Codes: B29C 65/1406 Ultraviolet [UV] radiation
• CPC Class Codes: B29C 65/1409 Visible light radiation
• CPC Class Codes: B29C 65/1429 characterised by the way of heating the interface B29C65/1629 takes precedence
• CPC Class Codes: B29C 65/1435 at least passing through one of the parts to be joined, i.e. transmission welding
• CPC Class Codes: B29C 65/1483 coated on the article
• CPC Class Codes: B29C 65/4845 Radiation curing adhesives, e.g. UV light curing adhesives
• CPC Class Codes: B29C 66/1122 Single lap to lap joints, i.e. overlap joints B29C66/45, B29C66/472, B29C66/52272 take precedence
• CPC Class Codes: B29C 66/24221 being circular B29C66/51 takes precedence
• CPC Class Codes: B29C 66/534 Joining single elements to open ends of tubular or hollow articles or to the ends of bars
• CPC Class Codes: B29C 66/5432 joining hollow covers and hollow bottoms to open ends of container bodies
• CPC Class Codes: B29C 66/612 Making circumferential joints
• CPC Class Codes: B29C 66/7465 Glass
• CPC Class Codes: B29K 2709/08 Glass
• CPC Class Codes: H01J 9/34 Joining base to vessel

Abstract

The use of radiant energy and a radiation curable adhesive to bond components to glass where direct irradiation proves impossible is disclosed. The process utilizes the light scattering properties of glass to convey radiant light energy along an axis generally perpendicular to the incident radiant light resulting in cure of adhesive in shadow areas. The process finds particular utility in the bonding of light opaque end caps to fluorescent tubes.

Claims

1. A process for curing a radiation curable adhesive layer between a first irradiation opaque substrate and a second radiation transmissive substrate, said second substrate extending longitudinally beyond the edge of the first substrate and having a radiation inaccessible portion defined by the area of overlap of the first substrate over the second substrate, the process comprising irradiating the second substrate in a direction generally perpendicular to the second substrate, on the portion thereof extending beyond the first substrate so as to scatter sufficient radiation longitudinally through the second substrate into the adhesive layer for sufficient time to cause the adhesive layer to cure.

2. A process as described in claim 1 wherein the radiant light energy employed is UV light energy.

3. A process as in claim 1 wherein the radiation transmissive substrate is glass.

4. A process as in claim 1 wherein the adhesive is an acrylic adhesive.

5. A process as in claim 1 wherein the adhesive comprises cationically polymerizable material.

6. A process as in claim 5 wherein the adhesive comprises an epoxy compound and a cationic photoinitiator.

7. A process as in claim 1 wherein the radiant energy employed in electron beam radiation.

8. A process in claim 1 wherein the radiant energy employed is visible light energy.

9. A process for cuing a layer of radiation curable adhesive between facing sides of first and second substrates, said adhesive being curable with radiation of a type selected from visible, UV and electron beam radiation, said first substrate being opaque to the type of radiation which cures said adhesive and said second substrate characterized in that the side of the second substrate which faces said first substrate extends beyond the edge of the first substrate and said second substrate is comprised of a material which is generally transmissive of the type of radiation which cures said adhesive but which scatters a portion of said radiation along said second substrate in a direction generally perpendicular to the incident radiation, said process comprising irradiating the side of said second substrate facing said first substrate on the portion thereof extending beyond the first substrate in a direction generally perpendicular thereto with radiation of the type which cures said adhesive for sufficient time to cure the adhesive layer between the first and second layers.

10. A process as in claim 10 wherein the second substrate is glass.

11. A process as in claim 12 wherein the adhesive is a UV curing adhesive and the radiation is UV light.