Sensor element for determination of concentration of substances

• US 4,755,667 A
• Filed: 04/17/1987
• Issued: 07/05/1988
• Est. Priority Date: 10/10/1986
• Status: Expired due to Term

• Current Assignee: AVL AG
• Original Assignee: AVL AG
• Inventors: Karpf, Hellfried, Leitner, Alfred, Marsoner, Hermann
• Primary Examiner(s): Westin, Edward P.
• Application Number:
  US07/040,628
• Time in Patent Office: 445 Days
• Field of Search: 250/574, 250/576, 250/227, 250/461.1, 250/484.1, 356/338-343, 356/317, 356/318, 356/417, 356/39
• US Class Current: 250/227.24
• CPC Class Codes: G01N 21/7703 using reagent-clad optical fibres or optical waveguides using measurement of total internal reflection or attenuated total reflection G01N21/552; optical fibres or waveguides per se G02B
• CPC Class Codes: G01N 2201/0622 Use of a compensation LED
• CPC Class Codes: G02B 6/34 utilising prism or grating G02B6/293 takes precedence
• CPC Class Codes: G02B 6/42 Coupling light guides with opto-electronic elements

Abstract

A sensor element for use in determining the concentrations of substances contained in gaseous and liquid samples includes a carrier layer and an indicator layer containing one or more indicator substances whose optical properties change depending on the concentration of the substances to be measured, the carrier layer being provided with at least one photosensitive element with electrical contacts in planar arrangement, the indicator layer acting as a waveguide for excitation radiation coupled therein by an optical element.

Claims

1. A sensor element for determining the concentrations of substances contained in gaseous and liquid samples, comprising a carrier layer and an indicator layer, comprising one or more indicator substances, at least one of the optical properties of said indicator substances will change upon interaction with said substance to be measured, depending on the concentration of said substance, wherein said carrier layer is provided with at least one photosensitive element and electrical contacts of said photosensitive element in planar arrangement, wherein said indicator layer containing said indicator substance is acting as a waveguide for excitation radiation, said excitation radiation can be coupled into said indicator layer by means of an optical element, and wherein said indicator substance excited by said excitation radiation is in optical contact with said photosensitive element.

2. A sensor element according to claim 1, wherein said optical element is a coupling prism which is attached to said indicator layer acting as said waveguide.

3. A sensor element according to claim 1, wherein said optical element is a grating coupler which is attached to a side of said indicator layer facing away from said sample.

4. A sensor element according to claim 3, wherein said photosensitive element is configured as an annular diode having an inner circular area, and wherein said grating coupler is situated on said indicator layer in said inner circular area of said diode.

5. A sensor element according to claim 3, wherein two or more photodiodes are placed symmetrically, i.e., at least one on either side of said grating coupler, to act as said photosensitive elements.

6. A sensor element according to claim 2, wherein said optical element is connected, at least indirectly, to the end of a lightguide, having an excitation filter situated between said end of said lightguide and said optical element.

7. A sensor element according to claim 3, wherein said optical element is connected, at least indirectly, to the end of a lightguide, having an excitation filter situated between said end of said lightguide and said optical element.

8. A sensor element according to claims 6 or 7, wherein said lightguide comprising a core and a cladding, said core, said cladding, said indicator layer and said sample having refractive indices and wherein the ratio of said refractive indices of said core and said cladding differs only slightly from the ratio of said refractive indices of said indicator layer and said sample.

9. A sensor element according to any of claims 3 to 5, wherein a light-emitting source is provided facing said grating coupler including an excitation filter situated between grating coupler and light-emitting source.

10. A sensor element according to claim 1, wherein said photosensitive elements are covered by a filter layer, in particular an interference filter.

11. A sensor element according to claim 10, wherein said filter layer is an interference filter.

12. A sensor element according to claim 1, wherein a transparent layer or channel plate, having an angle of acceptance, is added between said photosensitive elements and said indicator layer, said angle of acceptance prevents transport of said excitation radiation to said photosensitive elements.

13. A sensor element according to claim 12, wherein different indicator substances are used in individual areas of said indicator layer corresponding to certain of said photosensitive elements.

14. A sensor element according to claim 1, wherein said indicator layer is provided with a cover layer on the side facing said sample.

15. A sensor element according to claim 9, wherein additional electronic circuits are integrated into said carrier layer, said electronic circuits are used for amplifying electric signals of said photosensitive elements and/or for control of the brightness of radiation generated by said light-emitting sources.

16. A sensor element according to claim 9, wherein said carrier layer is provided with highly integrated electronic circuits for signal evaluation tasks.

17. A sensor element according to claim 1, wherein additional electronic circuits are integrated into said carrier layer, said electronic circuits are used for amplifying electric signals of said photosensitive elements and/or for control of the brightness of radiation generated by said light-emitting sources.

18. A sensor element according to claim 1, wherein said carrier layer is provided with highly integrated electronic circuits for signal evaluation tasks.