Process for bleaching a mechanical pulp with hydrogen peroxide

• US 4,756,798 A
• Filed: 04/16/1987
• Issued: 07/12/1988
• Est. Priority Date: 06/15/1984
• Status: Expired due to Term

• Current Assignee: Christian De Choudens, Claude Bourne, Dominique Lachenal
• Original Assignee: Christian De Choudens, Claude Bourne, Dominique Lachenal
• Inventors: Lachenal, Dominique, Bourne, Claude, de Choudens, Christian
• Primary Examiner(s): Lacey, David L.
• Assistant Examiner(s): MANOHARAN, VIRGINIA
• Application Number:
  US07/039,794
• Time in Patent Office: 453 Days
• Field of Search: 162/65, 162/71, 162/78, 162/24
• US Class Current: 162/24
• CPC Class Codes: D21C 9/1057 Multistage, with compounds cited in more than one sub-group D21C9/10, D21C9/12, D21C9/16
• CPC Class Codes: D21C 9/163 with peroxides

Abstract

Mechanical pulp is bleached by a treatment with hydrogen peroxide wherein prior to or simultaneously with said treatment the mechanical pulp is subject to an oxygen pressure.

Claims

1. A process for bleaching a mechanical pulp comprising:

subjecting the mechanical pulp to oxygen, and treating the pulp with hydrogen peroxide, the hydrogen peroxide bleaching the mechanical pulp, and the oxygen reinforcing the bleaching power of the hydrogen peroxide.

2. A process according to claim 1, comprising subjecting the mechanical pulp to said oxygen simultaneously with said hydrogen peroxide treatment.

3. A process according to claim 1, comprising subjecting the mechanical pulp to oxygen prior to said treatment with hydrogen peroxide.

4. A process according to claim 1, comprising effecting said treatment with the oxygen at atmospheric pressure.

5. A process according to claim 1, wherein said oxygen is gaseous oxygen under super atmospheric pressure.

6. A process according to claim 1, wherein the oxygen pressure is lower than 5 bars.

7. A process according to claim 6, wherein the oxygen pressure is between 2 and 3 bars.

8. A process according to claim 1, wherein, the pH of the pulp is between 9 and 12.

9. A process according to claim 8 wherein said pH is between 10 and 11.

10. A process according to claim 1 wherein the temperature of the pulp is between 40°

and 100°

C.

11. A process according to claim 10, wherein said temperature is between 50°

and 70°

C.

12. A process according to claim 1, wherein the consistency of the treated mechanical pulp is between 8 and 30%.

13. A process according to claim 12, wherein the consistency of the treated mechanical pulp is between 10 and 20%.

14. A process according to claim 1 wherein the pulp is treated with bleaching liquor containing, in addition to the hydrogen peroxide, soda, sodium silicate, and sequestering agents.

15. A process for bleaching mechanical pulp comprising, in combination:

introducing mechanical pulp into an enclosure;

directing oxygen into the enclosure to expose the mechanical pulp to an oxygen atmosphere; and

while the pulp is exposed to said oxygen atmosphere, treating the mechanical pulp with an alkaline solution of hydrogen peroxide stabilized with a stabilizing agent;

the hydrogen peroxide bleaching the mechanical pulp, and the oxygen reinforcing the bleaching power of the hydrogen peroxide.

16. A process according to claim 15, wherein the stabilizing agent is sodium silicate.

17. A process according to claim 15, wherein the stabilizing agent is a magnesium salt.

18. A process according to claim 15, wherein the stabilizing agent is a metallic cation sequestering agent.