Porous propellant grain and method of making same

• US 4,758,287 A
• Filed: 06/15/1987
• Issued: 07/19/1988
• Est. Priority Date: 06/15/1987
• Status: Expired due to Term

• Current Assignee: Nammo Talley, Inc. (Nammo AS)
• Original Assignee: Talley Industries, Inc.
• Inventors: Pietz, John F.
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Application Number:
  US07/062,547
• Time in Patent Office: 400 Days
• Field of Search: 149/2, 149/35, 149/61, 149/77, 149/109.6, 264/3.1, 280/728, 280/741, 102/291, 102/292
• US Class Current: 149/2
• CPC Class Codes: C06B 21/0091 Elimination of undesirable or temporary components of an intermediate or finished product, e.g. making porous or low density products, purifying, stabilising, drying; Deactivating; Reclaiming; porous inert particles or chemicals compounded for these purposes C06B23/00
• CPC Class Codes: C06B 35/00 Compositions containing a metal azide

Abstract

A process for preparing a porous propellant grain which comprises blending at least two combustible materials to form a homogeneous mixture, adding a predetermined amount of a liquid dispersant to said mixture to form a slurry, and flash drying the slurry in order to form a porous, single grain propellant having a greatly increased burning surface. A single grain propellant is produced having a flat, torroidal shape with a central cylindrical core and honeycombed with a plurality of porous channels extending entirely through the grain to increase the burning surface thereof.

Claims

1. A process for preparing a porous propellant grain which comprises:

blending a predetermined amount of at least two combustible materials, said materials being capable of rapidly reacting to generate a gaseous product, and a liquid dispersant to form a slurry; and

flash drying said slurry to substantially evaporate said dispersant and form a porous propellant grain.

3. The process of claim 1 or 2 wherein said combustible materials comprise at least an alkali metal azide and a metal oxide.

4. The process of claim 3 wherein the alkali metal azide is sodium azide, potassium azide, lithium azide or mixtures thereof.

5. The process of claim 4 wherein said azide is sodium azide, said azide being added in an amount of between about 40-80 parts per hundred by weight of the total composition.

6. The process of claim 3 wherein said metal oxide is added to said azide in an amount slightly in excess of the stoichiometric requirement.

7. The process of claim 6 wherein the metal oxide is ferric oxide, copper (II) oxide, manganese oxide, tin oxide, titanium oxide, nickel oxide and mixtures thereof.

8. The process of claim 1 or 2 which further comprises adding a stoichiometric amount of at least one oxidizing agent to said mixture.

9. The process of claim 8 wherein said oxidizing agent is an alkaline nitrate, an alkaline chlorate, an alkaline perchlorate or a mixture thereof.

10. The process of claim 1 or 2 wherein said blending step is performed by dry mixing the combustible reactants.

11. The process of claim 1 or 2 wherein said liquid dispersant comprises a solution of sodium silicate in water.

12. The process of claim 11 wherein the percentage of sodium silicate in said solution ranges between about 10-70% by weight.

13. The process of claim 1 or 2 wherein said liquid dispersant is water and which further comprises adding a predetermined amount of a sodium silicate solution to said slurry.

14. The process of claim 1 or 2 wherein said liquid dispersant is an aliphatic hydrocarbon compound.

16. The process of claim 1 or 2 wherein said slurry is flash dried by exposure to a predetermined level of microwave radiation for a predetermined duration to remove substantially all of the water therefrom.

17. The process of claim 1 or 2 which further comprises molding a quantity of said slurry into a predetermined shape prior to flash drying said slurry.

18. The process of claim 17 which further comprises filling a plastic combuster cup with a predetermined amount of said slurry in order to mold said slurry into a predetermined shape prior to exposing the slurry to said microwave radiation.

19. The process of claim 16 wherein said slurry is irradiated for about 30 seconds during any one exposure period.

20. The process of claim 19 wherein the total period during which said slurry is exposed to said radiation is about four minutes in order to remove substantially all of the liquid therefrom.

21. The process of claim 1 or 2 which further comprises extruding a quantity of said slurry into a predetermined shape prior to flash drying said extrudate.

35. The porous propellant grain prepared by the process of claim 1.

2. A process for preparing a porous propellant grain which comprises:

blending a predetermined amount of at least two combustible materials to form a homogeneous mixture, said materials capable of rapidly reacting to generate a non-toxic, non-noxious gas;

adding a predetermined amount of a liquid dispersant to said mixture to form a slurry; and

flash drying said slurry in order to evaporate said dispersant and form a porous propellant grain having a burning surface capable of producing a desired amount of gaseous product to substantially fully inflate an automobile air bag in about 30-60 milliseconds.

36. The porous propellant grain prepared by the process of claim 2.

15. A process for preparing a porous propellant grain which comprises:

dry blending a mixture of 40-80 parts per hundred by weight of a sodium azide and from about 20-60 parts per hundred by weight of a mixture of ferric oxide and cupric oxide, said metal oxide being added in an amount slightly in excess of the stoichiometric requirement, with an oxidizing agent selected from among an alkaline nitrate, an alkaline chlorate, an alkaline perchlorate and mixtures thereof, to form a homogeneous mixture;

adding a predetermined amount of a solution of sodium silicate in water to said mixture to form a slurry; and

flash drying said slurry in order to evaporate water from the slurry and form a porous, single-grain propellant composition with a sufficient burning surface capable of producing a desired amount of gaseous product to substantially fully inflate an automobile air bag in about 30-60 milliseconds.

37. The porous propellant grain prepared by the process of claim 15.

22. A process for preparing a porous propellant grain which comprises:

dry blending 40-80 parts per hundred by weight of an alkali metal azide selected from among sodium azide, potassium azide, lithium azide and mixtures thereof together with about 20-60 parts per hundred by weight of a metal oxide selected from among iron oxide, copper (II) oxide, manganese oxide, tin oxide, titanium oxide, nickel oxide and mixtures thereof, said amount of metal oxide being slightly in excess of the stoichiometric requirement and an additional oxidizing agent selected from among an alkaline nitrate, an alkaline chlorate, an alkaline perchlorate and mixtures thereof, to form a homogeneous mixture;

adding a predetermined amount of a sodium slicate solution in water to said mixture to form a slurry wherein the percentage of said sodium silicate ranges between 10-70% by weight;

placing said slurry into an automobile gas generator combuster cup in an amount sufficient to substantially fill said cup so as to mold the slurry into a predetermined shape; and

irradiating said slurry with a source of microwave radiation for a period of about 3-5 minutes, wherein said period is comprised of a plurality of discrete radiation treatments, each lasting about 30 seconds, to evaporate substantially all of the water from the slurry and form a porous, single grain propellant having a burning surface capable of producing a desired amount of gaseous product to substantially fully inflate an automobile air bag in about 30-60 milliseconds.

38. The porous propellant grain prepared by the process of claim 22.

23. A process for rapidly generating a quantity of a gaseous product which comprises:

preparing a porous propellant grain by

blending a predetermined amount of at least two combustible materials, said materials capable of rapidly reacting to generate a gaseous product, and a liquid dispersant to form a slurry; and

flash drying said slurry to substantially evaporate said dispersant, thus forming said porous grain; and

igniting said grain so as to produce a desired quantity of gaseous product.

24. The process of claim 23 which further comprises placing said porous grain within combustion means prior to said ignition step.

25. The process of claim 24 wherein said combustion means is chamber means, said chamber means forming a portion of a gas generator assembly.

26. The process of claim 25 which further comprises installing said gas generator assembly in a motor vehicle as a portion of an occupant passive restraint system.

27. The process of claim 25 which further comprises substantially inflating an expandable safety device with said gaseous product.

28. The process of claim 27 which further comprises selecting said expandable safety device from among an aircraft escape slide, an inflatable life raft and an automobile air bag.

29. The process of claim 23 which further comprises utilizing said gaseous product to propel projectile means.

30. The process of claim 23 wherein said combustible materials comprise at least an alkali metal azide and a metal oxide.

31. The process of claim 23 which further comprises dry blending said combustible materials to form a homogeneous mixture and subsequently adding a predetermined amount of a liquid dispersant thereto in order to form said slurry.

32. The process of claim 23 which further comprises igniting said porous grain by chemical, electrical or thermal means.

33. The process of claim 32 wherein said electrical means is electrically activated squib means.

34. A process for rapidly generating a desired quantity of a gaseous product to substantially fully inflate an automobile air bag in between about 30-60 milliseconds which comprises:

preparing a porous propellant grain by

blending a predetermined amount of at least an alkali metal azide and a metal oxide, said azide and said oxide capable of rapidly reacting to generate a nonnoxious, non-toxic gaseous product, and an aqueous dispersant to form a slurry; and

flash drying said slurry to substantially evaporate said dispersant, thus forming said porous grain;

placing said porous grain within a combustion chamber portion of an automotive air bag gas generator assembly; and

igniting said porous grain to generate said gas.

39. A porous propellant grain wherein said grain has a plurality of randomly oriented, radial and longitudinally interconnected porous channels having a variety of diameters, extending entirely through said grain to increase the burning surface of said grain.

40. The porous propellant grain of claim 39 wherein the density of said grain ranges between about 0.85-1.45 grams/cm³.

41. The porous propellant grain of claim 39 wherein said grain is resistant to abrasion and breakup during loading within an automobile gas generator and upon ignition.

42. The porous propellant grain of claim 39 wherein said grain is produced having a flat torroidal shape.

43. The porous propellant grain of claim 42 wherein said grain further defines a central cylindrical channel extending therethrough from a bottom surface to a top surface thereof, configured to completely surround an igniter portion of an automobile gas generator.

44. A porous propellant grain resistant to abrasion and breakup during loading into a gas generator and upon ignition thereof, wherein said grain has a plurality of randomly oriented uniformly distributed porous channels extending entirely therethrough, having a variety of diameters, said channels being radially and longitudinally interconnected to increase the burning surface of said grain, said grain having a density of between about 0.85-1.45 grams/cm³, and having a flat, torroidal shape.

45. A porous propellant grain resistant to abrasion and breakup during loading into a gas generator and upon ignition thereof, comprising a homogeneous mixture of at least two combustible reactants, said mixture containing a plurality of randomly oriented porous channels having a variety of diameters, uniformly distributed therethrough, said channels being radially and longitudinally interconnected to provide a sufficient burning surface for rapidly producing a large quantity of gaseous product upon ignition of said propellant.

46. The porous propellant grain of claim 45 wherein the reactants include an azide compound and a transition metal oxide, with the oxide present in an amount in excess of the stoichiometric requirement.