Assay of ketones in ambient air

• US 4,758,521 A
• Filed: 02/15/1985
• Issued: 07/19/1988
• Est. Priority Date: 02/15/1985
• Status: Expired due to Fees

• Current Assignee: Union Carbide Corporation (Dow, Inc.)
• Original Assignee: Union Carbide Corporation (Dow, Inc.)
• Inventors: Lushbaugh, Robley E., Conway, Richard A., Neff, Joe E.
• Primary Examiner(s): Richman, Barry S.
• Assistant Examiner(s): KRYZA, LYNN M
• Application Number:
  US06/702,318
• Time in Patent Office: 1,250 Days
• Field of Search: 422/59, 422/60, 422/83, 422/88, 436/128, 436/130, 436/167, 73/23, 73/53, 73/61 R, 73/863.21, 55/74
• US Class Current: 436/128
• CPC Class Codes: G01N 30/00 Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation G01N3/00, G01N5/00, G01N7/00, G01N9/00, G01N11/00, G01N13/00, G01N15/00, G01N17/00, G01N19/00, G01N21/00, G01N22/00, G01N23/00, G01N24/00, G01N25/00, G01N27/00, G01N29/00 take precedence
• CPC Class Codes: Y10T 436/200833 Carbonyl, ether, aldehyde or ketone containing
• CPC Class Codes: Y10T 436/202499 Formaldehyde or acetone

Abstract

A method of assaying ketones in ambient air comprising contacting the air with beaded activated carbon followed by desorption with a solvent and analysis of the solvent solution for ketone content has been developed which provided superior results over prior art adsorbents, particularly when the sampling operation is conducted in the presence of humid air.

Claims

1. Method of assaying ketones in ambient air, said ketones being selected from the group consisting of cyclohexanone, methyl ethyl ketone, methyl phenyl ketone, methyl isobutyl ketone and mesityl oxide, said method consisting essentially of:

(a) contacting a known volume of ambient air containing at least one of said ketones, at an ambient temperature with an excess of beaded activated carbon whereby one or more of said ketones is adsorbed onto the beaded activated carbon;

(b) contacting the beaded activated carbon containing one or more adsorbed ketones from step (a) with a solvent for ketones whereby said one or more adsorbed ketones are desorbed from the beaded activated carbon forming a solution of one or more of said ketones in said solvent;

(c) recovering the solution of one or more ketones from step (b); and

(d) analyzing the solution of one or more ketones for ketone content.

2. Method claimed in claim 1 wherein the cycloaliphatic ketone is cyclohexanone.

3. Method claimed in claim 1 wherein the ketone is methyl ethyl ketone.

4. Method claimed in claim 1 wherein the ketone is methyl phenyl ketone.

5. Method claimed in claim 1 wherein the ketone is mesityl oxide.

6. Method claimed in claim 1 wherein the ketone solvent in step (B) is carbon disulfide.

7. Method as in claim 1 wherein the ketone is methyl isobutyl ketone.