Apparatus for gas-monitoring and method of conducting same

• US 4,759,210 A
• Filed: 06/06/1986
• Issued: 07/26/1988
• Est. Priority Date: 06/06/1986
• Status: Expired due to Term

• Current Assignee: Microsensor Systems, Inc. (MSA Safety, Inc.)
• Original Assignee: Microsensor Systems, Inc. (MSA Safety, Inc.)
• Inventors: Wohltjen, Henry
• Primary Examiner(s): Tokar, Michael J.
• Assistant Examiner(s): Williams, Hezron E.
• Application Number:
  US06/871,694
• Time in Patent Office: 781 Days
• Field of Search: 73/23, 73/863.11, 73/863.12, 73/23.1, 340/632, 324/71.1 R, 55/205, 55/179, 422/88
• US Class Current: 73/31.07
• CPC Class Codes: G01N 2030/303 using peltier elements
• CPC Class Codes: G01N 30/00 Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation G01N3/00, G01N5/00, G01N7/00, G01N9/00, G01N11/00, G01N13/00, G01N15/00, G01N17/00, G01N19/00, G01N21/00, G01N22/00, G01N23/00, G01N24/00, G01N25/00, G01N27/00, G01N29/00 take precedence
• CPC Class Codes: G01N 33/0022 using a number of analysing channels
• CPC Class Codes: G01N 33/0031 comprising two or more sensors, e.g. a sensor array electrochemical electrode arrays G01N27/27

Abstract

The invention relates to method of monitoring a gas, which comprises simultaneously flowing said gas through a plurality of means for trapping gaseous species, each of said trapping means being adapted so that its selectivity in trapping of gaseous species differs from such selectivity of the other means in said plurality; subjecting each means of said plurality to conditions effecting release of any gaseous species trapped thereby while maintaining the other means of said plurality in a condition suitable for said selective trapping of gaseous species; contacting the gas issuing from each of said plurality of trapping means with each of a plurality of means for sensing said gaseous species, each said sensing means being adapted so that its selectivity to sensing said gaseous species differs from such selectivity of the other sensing means; and to apparatus for carrying out the method.

Claims

1. Apparatus for monitoring a gas, which comprises a plurality of means for trapping gaseous species, each of said trapping means being adapted so that its selectivity to trapping of gaseous species differs from such selectivity of the other means in said plurality, said plurality of trapping means being disposed for flow of said gas through each of said means simultaneously;

in operative association with each of the trapping means, means for selectively effecting the release of trapped gaseous species therefrom; and

a plurality of means for sensing any of said gaseous species released from said means for trapping, each of said sensing means being adapted so that its selectivity to sensing said gaseous species differs from such selectivity of the other sensing means, each of said sensing means in said plurality being disposed for contact with said gas issuing from each of the plurality of said means for trapping.

2. Apparatus as defined in claim 1, wherein said means for trapping gaseous species comprises a sorbent mass which selectively traps and concentrates said gaseous species under normal operating conditions and desorbs said gaseous species when heated.

3. Apparatus as defined in claim 2, wherein the sorbent mass is activated charcoal, alumina, a zeolite molecular sieve, a metal, a silica gel, or a polymeric sorbent.

4. Apparatus as defined in claim 3, wherein the polymeric sorbent is a derivative of 2,6-diphenyl-p-phenylene oxide, a styrene divinyl benzene polymer, an ethyl vinyl or divinyl benzene polymer, a vinyl pyrrolidone polymer, a vinyl pyridine polymer, cross-linked polystyrene, polyacrylonitrile or a cross-linked acrylic ester.

5. Apparatus as defined in claim 1, wherein the means for trapping gaseous species is a tube containing a sorbent material.

6. Apparatus as defined in claim 5, wherein said tube is formed of fused silica.

7. Apparatus as defined in claim 1, wherein said means for selectively effecting the release of trapped gaseous species is a heater disposed sufficiently proximately of said means for trapping gaseous species so that when said heater is operative it causes release of said gaseous species from said means for trapping same.

8. Apparatus as defined in claim 1, wherein the means for trapping gaseous species comprises a tube and the means for selectively effecting release of trapped gaseous species is a thin film resistance heater coverirg at least a portion of the outer wall of said tube.

9. Apparatus as defined in claim 8, wherein said resistance heater includes a resistive ink coated on at least a portion of the outer wall of said tube.

10. Apparatus as defined in claim 1, wherein said means for sensing said gaseous species is a piezoelectric sensor, an organic semiconductor chemiresistor, a chemically sensitive field effect transistor, a metal oxide semiconductor, or an electrochemical cell.

11. Apparatus as defined in claim 10, wherein said piezoelectric sensor is a bulk wave piezoelectric sensor or a surface acoustic wave sensor.

22. Apparatus as defined in claim 1, which further comprises means for measuring a signal emitted by each of the plurality of said sensing means.

23. Apparatus as defined in claim 1, which further comprises means for measuring a signal emitted by each of the plurality of said sensing means, and control means which causes said measuring means to measure said signal just prior to contacting the sensing means with gas containing the output of one of said trapping means which has been subjected to conditions effecting release of any gaseous species trapped therein, and again causing said measuring means to measure the corresponding signal when the sensing means is contacted with said gas containing said output.

12. A method of monitoring a gas, which comprises

simultaneously flowing said gas through a plurality of means for trapping gaseous species, each of said trapping means being adapted so that its selectivity in trapping of gaseous species differs from such selectivity of the other means in said plurality;

selectively subjecting each means of said plurality to conditions effecting release of any gaseous species trapped thereby while maintaining the other means of said plurality in a condition suitable for said selective trapping of gaseous species;

contacting the gas issuing from each of said plurality of trapping means with each of a plurality of means for sensing said gaseous species, said sensing means being adapted so that its selectivity of sensing said gaseous species differs from such selectivity of the other sensing means.

13. A method as defined in claim 12, which further comprises contacting said gas with a sorbent mass included in each said means for trapping gaseous species, thereby to sorb in each said mass any gaseous species as to which the sorbent mass is selective.

14. A method as defined in claim 13, wherein the sorbent mass is activated charcoal, alumina, a zeolite molecular sieve, a metal, a silica gel, or a polymeric sorbent.

15. A method as defined in claim 14, wherein the polymeric sorbent is a derivative of 2,6-diphenyl-p-phenylene oxide, a styrene divinyl benzene polymer, an ethyl vinyl or divinyl benzene polymer, a vinyl pyrrolidone polymer, a vinyl pyridine polymer, cross-linked polystyrene, polyacrylonitrile or a cross-linked acrylic ester.

16. A method as defined in claim 12, which further comprises passing said gas through a plurality of means for trapping a gaseous species wherein each such means comprises a tube having at least a part of its inner wall coated with a sorbent mass.

17. A method as defined in claim 16, wherein said tube is formed of fused silica.

18. A method as defined in claim 12, which comprises subjecting each means for trapping gaseous species to an amount of heating sufficient to release said trapped gaseous species, the heating of said means being effected with a thin-film resistance heater disposed sufficiently proximately of said means for trapping gaseous substances as to effect said release.

19. A method as defined in claim 12, wherein said plurality of means for sensing said gaseous species comprises an array of sensors the selectivity of each sensor to said gaseous species differing from such selectivity of the other sensors.

20. A method as defined in claim 19, wherein each said sensor comprises a piezoelectric sensor, an organic semiconductor chemirestor, a chemically sensitive field effect transistor, a metal oxide semiconductor, or an electrochemical cell.

21. A method as defined in claim 20, wherein said piezoelectric sensor is a bulk wave piezoelectric sensor or a surface acoustic wave sensor.

24. A method as defined in claim 12, which further comprises measuring a signal emitted by each of the plurality of said sensing means when the sensing means is contacted with the output of said trapping means which has been subjected to conditions effecting release of any gaseous species trapped therein.

25. A method as defined in claim 12, which further comprises, just prior to contacting said gas containing the output of one of said trapping means subjected to conditions effecting release of any trapped gaseous species, measuring a signal emitted by each of said sensing means, and then comparing the corresponding signal emitted by each of said sensing means when it is contacted with said gas containing said output.

26. Apparatus for monitoring a gas, which comprises an array of tubes containing a sorbent mass the selectivity of the sorbent mass in each said tube to trapping of gaseous species being different from such selectively of the sorbent mass in each of the other tubes in said array, said array of tubes being disposed in substantially parallel relationship such that there is flow of said gas through each of said tubes simultaneously;

a portion of the exterior of each of said tubes being coateed with a thin film resistance heater formed of a resistive ink; and

an array of piezoelectric sensors, each of said sensors being adapted so that its selectively to sensing said gaseous species differs from such selectivity of the other sensors, each of said sensors in said array being disposed for contact with said gas issuing from each of the array of said tubes.

27. A method of monitoring a gas, which comprises

simultaneously flowing said gas through an array of tubes containing sorbent mass, the selectivity of the sorbent mass in each said tube to trapping of gaseous species being different from such selectivity of the sorbent mass in each of the other of said tubes;

successively subjecting each of the tubes of said array to conditions effecting release of any gaseous species trapped thereby while maintaining the other tubes of said array in a condition suitable for said selective trapping of gaseous species;

contacting the gas issuing from each of said array of tubes with each of an array of piezoelectric sensors, the selectivity of each said sensor to sensing said gaseous species differing from such selectivity of each of the other sensors in said array.