Polyphenylene ether compositions and process

• US 4,760,114 A
• Filed: 08/06/1986
• Issued: 07/26/1988
• Est. Priority Date: 02/26/1981
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Katchmn, Arthur, Huebner, James A., Haaf, William R.
• Primary Examiner(s): Ziegler, Jacob
• Application Number:
  US06/894,309
• Time in Patent Office: 720 Days
• Field of Search: 525/68, 525/66, 525/132, 525/179, 525/905
• US Class Current: 525/66
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/22 Macromolecular compounds not provided for in C08L2666/16 - C08L2666/20
• CPC Class Codes: C08L 71/02 Polyalkylene oxides
• CPC Class Codes: C08L 71/123 not modified by chemical after-treatment
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: Y10S 525/905 Polyphenylene oxide

Abstract

Novel compositions are provided which comprise a polyphenylene ether, optionally a high impact polystyrene, optionally, an effective amount of an aromatic phosphate flame retardant, and a low molecular weight polymer selected from a polyolefin glycol or a polyamide, said comopsition being free from or excluding a substantial content of polyolefin, such as polyethylene. Such compositions when molded are readily paintable, and exhibit good adhesion between the paint and the molded compositions as distinguished from compositions containing polyolefins, such as polyethylene, which has been found to adversely affect paint adhesion. In addition, the novel compositions possess good or improved Izod and Gardner impact strengths, and in the case of polyolefin glycol, such as polyethylene glycol, the mutual solubility of all the components of the compositions is increased. Included within the disclosure of the invention are methods of preparing and molding such compositions and the molded products obtained therefrom.

Claims

1. A paintable composition comprising:

(a) a polyphenylene ether resin,

(b) a high impact polystyrene, and

(c) an effective paint adhesion promoting amount of a polymer consisting essentially of a polyamide having an average molecular weight from about 1,000 to about 10,000 and a melting point between 114°

C. and 124°

C., said composition being free from polyethylene.

2. The composition of claim 1, wherein the amount of (c) is from about 0.1 parts to about 5 parts, by weight.

3. The composition of claim 1 wherein the low molecular weight polyamide polymer is a resin composed of amides of dimerized tall-oil fatty acids, chiefly oleic and linoleic acids.

4. The composition of claim 1 wherein the polyphenylene ether resin is selected from compounds of the formula:

##STR3## wherein the oxygen ether atom of one unit is connected to the benzene nucleus of the next adjoining unit, n is a positive integer and is at least 50, and each Q is a monovalent substituent selected from the group consisting of hydrogen, halogen, hydrocarbon radicals free of a tertiary alpha-carbon atom, halohydrocarbon radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, hydrocarbonoxy radicals, and halohydrocarbonoxy radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus.

5. The composition of claim 1 wherein the high impact polystyrene is a rubber modified polystyrene.

6. The composition of claim 1 wherein the polyphenylene ether is poly(2,6-dimethyl-1,4-phenylene)ether.

7. The composition of claim 1, which comprises about 40 parts of poly(2,6-dimethylphenylene)ether, about 60 parts of high impact polystyrene, and about 1.5 parts of the low molecular weight polyamide, the parts being by weight.

8. A molded composition having a high level of paint adhesion obtained by molding the composition of claim 1.

9. A method for improving the paint adhesion after molding while retaining the mold releasability of a composition of (a) a polyphenylene ether resin, and (b) a high impact polystyrene, comprising including in the composition (c) an effective, paint adhesion promoting amount of a polyamide having an average molecular weight of from about 1,000 to about 10,000 and a melting point between 114°

C. and 124°

C., said composition being free from polyethylene.

10. A method according to claim 9 wherein the blended product is molded into a shaped article, the resulting molded article having a high level of paint adhesion.

11. A method according to claim 9, in which the amount of (c) is from about 0.1 to about 5 parts by weight per 100 parts by weight.

12. A method according to claim 9, in which the polyphenylene ether resin has the formula ##STR4## in which the oxygen ether atom of one unit is connected to the benzene nucleus of the next adjoining unit, n is a positive integer and is at least 50, and each Q is a monovalent substituent selected from the group consisting of hydrogen, halogen, hydrocarbon radicals free of a tertiary alpha-carbon atom, halohydrocarbon radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, hydrocarbonoxy radicals, and halohydrocarbonoxy radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus.

13. A method according to claim 12, in which the polyphenylene ether resin is poly(2,6-dimethyl-1,4-phenylene ether) resin.

14. A method according to claim 9, in which the polyamide contains recurring aromatic amide groups, recurring aliphatic amide groups or mixtures of the foregoing.

15. A method according to claim 9, in which the polystyrene is derived at least in part from a monomer of the formula ##STR5## wherein R¹ and R² are selected from the group consisting of hydrogen and lower alkyl of from 1 to 6 carbon atoms;

R³ and R⁴ are selected from the group consisting of chloro, bromo, hydrogen, and lower alkyl of from 1 to 6 carbon atoms; and

R⁵ and R⁶ selected from the group consisting of hydrogen and lower alkyl and alkenyl of from 1 to 6 carbon atoms, or R⁵ and R⁶ may be concatenated together with hydrocarbyl groups to form a naphthyl group.

16. A method according to claim 9, in which the polyamide is a resin composed of amides of dimerized tall-oil fatty acids, chiefly oleic and linoleic acids.