Electrolytic method and cell for sterilizing water

• US 4,761,208 A
• Filed: 09/29/1986
• Issued: 08/02/1988
• Est. Priority Date: 09/29/1986
• Status: Expired due to Term

• Current Assignee: Miox Corporation (Industrie De Nora S.p.A)
• Original Assignee: Los Alamos Technical Associates, Inc.
• Inventors: Gram, Helen F., Pendergrass, Ann M., Muller, Martin E., Rink, Philip A.
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US06/913,844
• Time in Patent Office: 673 Days
• Field of Search: 204/257, 204/261, 204/263, 204/266, 204/94, 204/95, 204/242, 204/149, 204/293, 204/275, 204/151, 204/128-129
• US Class Current: 210/748.19
• CPC Class Codes: C02F 1/46104 Devices therefor; Their operating or servicing
• CPC Class Codes: C02F 1/4618 for producing "ionised" acidic or basic water
• CPC Class Codes: C02F 1/4674 with halogen or compound of halogens, e.g. chlorine, bromine
• CPC Class Codes: C02F 2001/46142 Catalytic coating
• CPC Class Codes: C02F 2201/4611 Fluid flow
• CPC Class Codes: C02F 2201/46115 Electrolytic cell with membranes or diaphragms
• CPC Class Codes: C02F 2201/4618 Supplying or removing reactants or electrolyte
• CPC Class Codes: C02F 2301/022 Laminar
• CPC Class Codes: C02F 2301/024 Turbulent
• CPC Class Codes: C02F 2301/043 Treatment of partial or bypass streams
• CPC Class Codes: C02F 2303/04 Disinfection
• CPC Class Codes: Y02W 10/37 using solar energy

Abstract

Electrolytic cell and low-voltage method for sterilizing water. The electrolytic cell of the invention contains a cathode and an anode which produce oxidants to effect sterilization of contaminated water. The anode is made of a Group VIII metal or compound thereof which acts as a catalyst to produce oxidants. In the method of the invention, a salt solution is introduced into the electrolytic cell, oxidants are produced in solution, and the anode effluent stream is introduced directly into the water to be treated.

Claims

1. A method for electrolytically sterilizing or disinfecting water comprising the following steps:

(a) obtain an aqueous electrolytic solution;

(b) introduce the electrolytic solution into an electrolytic cell, when provided, wherein said electrolytic cell comprises;

(i) an anode, wherein the electrolytic surface of said anode comprises a Group VIII metal or a compound thereof;

(ii) an anode area comprising a chamber at said anode;

(iii) a cathode, wherein the electrolytic surface of said cathode comprises a conducting meterial;

(iv) a cathode area comprising a chamber at said cathode;

(v) at least one inlet for introducing an electrolytic solution, when provided, into said cell;

(vi) an outlet for allowing aqueous effluent from said anode to exit said electrolytic cell;

(vii) an outlet for allowing aqueous effluent from said cathode to exit said electrolytic cell;

(viii) sealing means positioned between said anode and said cathode for sealing said cell; and

(ix) flow restricting means comprising a barrier positioned between said anode and said cathode, said barrier comprising aperture means, said aperture means being large but smaller in total cross-sectional area than either said anode or said cathode, said barrier thereby comprising at least one flow restricing body portion which extends into said cell for restrictively allowing the electrolytic solution to flow between said anode and said cathode through said aperture means;

(c) withdraw aqueous effluent from said anode area of said electrolytic cell; and

(d) introduce the aqueous anode effluent into the contaminated water to be treated.

2. A method in accordance with claim 1 wherein the aqueous anode effluent contains at least ozone, hypochlorite and chlorine.

3. A method in accordance with claim 1 wherein said flow restricting body portion of said barrier extends into said cell from one end of said cell and said aperture means is positioned on the other end of said cell.

4. A method in accordance with claim 1 wherein said barrier comprises two flow restricting body portions which extend into said cell from opposite ends of said cell and said aperture means is centrally located between said flow restricting body portions.

5. A method in accordance with claim 1 wherein voltage and current, when applied across said anode and cathode, do not exceed about 12 volts and about 20 amps, respectively.

6. A method for electrolytically sterilizing or disinfecting water in accordance with claim 1 wherein at least one of the following microorganisms selected from the group consisting of Legionella pneumophilia, Giardia muris cysts, Bacillus subtilis spores, and American Type Culture Collection Strain #15442 Pseudomonas aeruginosa is effectively sterilized.

7. A method for electrolytically sterilizing or disinfecting water in accordance with claim 3 wherein the electrolytic solution is introduced into said electrolytic cell by laminar flow.

8. A method for electrolytically sterilizing or disinfecting water in accordance with claim 4 wherein the electrolytic solution is introduced into said electrolytic cell by turbulent flow.

9. A method for electrolytically sterilizing or disinfecting water in accordance with claim 1 wherein a ratio of volume of anode effluent to volume of contaminated water to be treated ranges from 1:

1 to 1;

5000.

10. A method for electrolytically sterilizing or disinfecting water in accordance with claim 1 wherein the anode effluent is introduced into the contaminated water to be treated within five (5) minutes after the anode effluent is withdrawn from said electrolytic cell.

11. A method in accordance with claim 1 wherein the cathode effluent is discarded.

12. A method in accordance with claim 1 wherein the cathode effluent is recycled directly into said inlet of said electrolytic cell as a portion of the electrolytic solution.

13. A method for electrolytically sterilizing or disinfecting water in accordance with claim 1 wherein the chlorine residual of the treated water is at least 0.2 mg/l.

14. An electrolytic cell for sterilizing or disinfecting water comprising:

(a) an anode, wehrein the electrolytic surface of said anode comprises a Group VIII metal or a compound thereof;

(b) an anode area comprising a chamber at said anode;

(c) a cathode, wherein the electrolytic surface of said cathode comprises a conducting material;

(d) a cathode area comprising a chamber at said cathode;

(e) at least one inlet for introducing an electrolytic solution, when provided, into said cell;

(f) at least one outlet for allowing effluent to exit said cell;

(g) sealing means positioned between said anode and said cathode for sealing said cell; and

(h) flow restricting means comprising a barrier positioned between said anode and said cathode, said barrier comprising aperture means, said aperture means being large but smaller in total cross-sectional area than either said anode or said cathode, said barrier thereby comprising at least one flow restricting body portion which extends into said cell for restrictively allowing the electrolytic solution to flow between said anode and said cathode through said aperture means.

15. An electrolytic cell in accordance with claim 14 wherein said flow restricting body portion of said barrier extends into said cell from one end of said cell and said aperture means is positioned on the other end of said cell.

16. An electrolytic cell in accordance with claim 15 wherein said outlet for allowing effluent to exit said cell is positioned near the end of said cell from which said flow restricting body portion of said barrier extends.

17. An electrolytic cell in accordance with claim 14 wherein said barrier comprises two flow restricting body portions which extend into said cell from opposite ends of said cell, said aperture means being substantially centrally located between said flow restricting body portions.

18. An electrolytic cell in accordance with claim 14 wherein said flow restricting body portion of said barrier is nonpermeable.

19. An electrolytic cell in accordance with claim 18 wherein said flow restricting body portion of said barrier is integral with said sealing means.

20. An electrolytic cell in accordance with claim 14 wherein said cell comprises two outlets;

one outlet for withdrawing aqueous effluent from said anode area and a second outlet for withdrawing aqueous effluent from said cathode area.

21. An electrolytic cell in accordance with claim 14 wherein at least ozone, hypochlorite and chlorine are produced in an aqueous solution when said electrolytic cell is being operated.