Electrochromatic system with third electrode

• US 4,762,401 A
• Filed: 05/02/1986
• Issued: 08/09/1988
• Est. Priority Date: 05/04/1985
• Status: Expired due to Fees

• Current Assignee: Schott Glaswerke
• Original Assignee: Schott Glaswerke
• Inventors: Mucke, Klaus, Metz, Bernd, Baucke, Friedrich
• Primary Examiner(s): Wan, Gene
• Assistant Examiner(s): Lee, James C.
• Application Number:
  US06/858,959
• Time in Patent Office: 830 Days
• Field of Search: 350/357
• US Class Current: 359/266
• CPC Class Codes: G02F 1/1533 structural features not otherwise provided for
• CPC Class Codes: G02F 2001/1552 Inner electrode, e.g. the electrochromic layer being sandwiched between the inner electrode and the support substrate

Abstract

In an electrochromatic, transparent layer system comprising at least one electrochromatic layer (2), two electrodes (3, 5) separated by a hydrogen ion supplying layer which simultaneously is a hydrogen ion storing layer (4), there is located, seen in the direction of light incidence through the layer system, a further hydrogen ion conducting layer (6) (e.g. of SiO₂) behind the electrode (5), behind which a further electrode (7) is arranged. The electrode (7) is capable of oxidizing hydrogen diffusing from within the system into hydrogen ions. For this purpose, a protective voltage is applied between electrode (5) and electrode (7) such that the third electrode (7) forms the positive pole.

Claims

1. An electrochromatic transparent layer system hermetically sealed against an exchange of matter with the environment, comprising at least one electrochromatic layer, at least a front and a rear electrode separated by an hydrogen ion conductive layer, and at least one hydrogen ion supplying layer which simultaneously is a hydrogen ion storing layer, characterized by the fact that, seen in the direction of light incidence through the layer system, there is (a) an additional hydrogen ion-conducting layer behind the rear electrode and (b) an additional electrode behind the additional hydrogen-ion conducting layer which is capable of oxidizing diffused hydrogen gas into hydrogen ions.

2. An electrochromatic layer system as in claim 1, wherein the additional hydrogen ion conducting layer is a SiO₂ -layer which has been applied by metallizing.

3. An electrochromatic layer system as in claim 1, wherein the third electrode is a precious metal electrode.

4. An electrochromatic layer system as in claim 1, wherein a protective DC-voltage is applied between the rear electrode and the third electrode such that the third electrode forms the positive pole.

5. An electrochromatic layer system as in claim 4, wherein the protective voltage is at least 30 mV.

6. An electrochromatic layer system as in claim 4, wherein the protective voltage is at least 90 mV.