Clean up and passivation of mercury in gas liquefaction plants

• US 4,764,219 A
• Filed: 10/27/1986
• Issued: 08/16/1988
• Est. Priority Date: 10/27/1986
• Status: Expired due to Fees

• Current Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Original Assignee: Mobil Oil Corporation (Exxon Mobil Corporation)
• Inventors: Yan, Tsoung Y.
• Primary Examiner(s): Doll, John
• Assistant Examiner(s): RUSSEL, JEFFREY E
• Application Number:
  US06/923,245
• Time in Patent Office: 659 Days
• Field of Search: 423/210, 423/561 B, 55/72, 502/516, 422/7, 422/9, 148/DIG. 17, 106/14.45, 165/5, 252/8.3, 252/8.552, 252/8.555, 252/80, 252/87, 252/89.1, 134/2
• US Class Current: 134/2
• CPC Class Codes: A62D 2101/43 containing heavy metals, in the bonded or free state
• CPC Class Codes: A62D 3/33 by chemical fixing the harmful substance, e.g. by chelation or complexation
• CPC Class Codes: B01J 19/002 Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
• CPC Class Codes: C09K 3/32 for absorbing liquids to remove pollution, e.g. oil, gasoline, fat
• CPC Class Codes: Y10S 148/017 Clean surfaces

Abstract

Gas liquefaction apparatus contaminated with mercury is decontaminated by circulating through the apparatus a solvent containing sulfur or a gas containing a sulfur reactant such as sulfur, hydrogen sulfide or alkyl thiol.

Claims

1. A process for passivating mercury present as a contaminant on gas processing equipment comprising contacting said mercury with a liquid solvent containing at least in part sulfur or a sulfur-containing compound selected from the group consisting of free elemental sulfur, colloidal sulfur, hydrogen sulfide, monosulfides, polysulfides and alkyl thiols said liquid solvent being selected from the group consisting of benzene, toluene, methanol, butane, propane, gas condensate, ethane, ethanol, propanol, carbon disulfide and mixtures thereof.

2. The process of claim 1 wherein the sulfur or sulfur-containing compound is free elemental sulfur or colloidal sulfur.

3. The process of claim 1 wherein the sulfur-containing compound is hydrogen sulfide.

4. The process of claim 1 wherein the sulfur-containing compound is an alkyl thiol of the structure RSH where R is an alkyl group of 1 to 10 carbon atoms.

5. The process of claim 1 wherein the sulfur containing compound is selected from the group consisting of sodium polysulfide and ammonium sulfide and mixtures of the two.

6. The process of claim 1 wherein the process is conducted at a temperature between about -10°

C. and -70°

C.

7. A process for passivating mercury present as a contaminant on gas processing equipment comprising contacting said mercury with a liquid solution containing, at least in part, sulfur or a sulfur-containing compound selected from the group consisting of free elemental sulfur, colloidal sulfur, hydrogen sulfide, monosulfides, polysulfides and alkyl thiols and a liquid solvent selected from the group consisting of benzene, toluene, methanol, butane, propane, gas condensate, ethane, ethanol, propanol, carbon disulfide and mixtures thereof.

8. The process of claim 7 wherein the sulfur or sulfur-containg compound is free elemental sulfur or colloidal sulfur.

9. The process of claim 7 wherein the sulfur-containing compound is hydrogen sulfide.

10. The process of claim 7 wherein the sulfur-containing compound is an alkyl thiol of the structure RSH where R is an alkyl group of 1 to 10 carbon atoms.

11. The process of claim 7 wherein the sulfur-containing compound is selected from the group consisting of sodium polysulfide and ammonium sulfide and mixtures of the two.

12. The process of claim 7 wherein the temperature is between about -10°

C. and -70°

C.