Lubricant additive

• US 4,765,918 A
• Filed: 11/28/1986
• Issued: 08/23/1988
• Est. Priority Date: 11/28/1986
• Status: Expired due to Term

• Current Assignee: Ethyl Additives Corp. (Antwerp Distribution & Product Operations NV)
• Original Assignee: Texaco Incorporated (Chevron Corp.)
• Inventors: Biasotti, Joseph B., Love, Doris, Schlicht, Raymond C.
• Primary Examiner(s): Dixon, Jr., William R.
• Assistant Examiner(s): MCAVOY, ELLEN M
• Application Number:
  US06/935,861
• Time in Patent Office: 634 Days
• Field of Search: 252/46.4, 260/402.5
• US Class Current: 508/328
• CPC Class Codes: C10M 125/04 Metals; Alloys
• CPC Class Codes: C10M 125/06 Sulfur
• CPC Class Codes: C10M 125/10 Metal oxides, hydroxides, carbonates or bicarbonates
• CPC Class Codes: C10M 125/18 Compounds containing halogen
• CPC Class Codes: C10M 125/20 Compounds containing nitrogen
• CPC Class Codes: C10M 125/22 Compounds containing sulfur, selenium or tellurium
• CPC Class Codes: C10M 133/04 Amines, e.g. polyalkylene polyamines; Quaternary amines polyalkylene polyamines with eleven or more monomer units C10M149/22
• CPC Class Codes: C10M 133/16 Amides; Imides
• CPC Class Codes: C10M 135/04 Hydrocarbons
• CPC Class Codes: C10M 159/00 Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution carboxylic acids with less than 30 carbon atoms in the chain, of unknown or incompletely defined constitution C10M129/56
• CPC Class Codes: C10M 159/12 Reaction products
• CPC Class Codes: C10M 159/18 Complexes with metals
• CPC Class Codes: C10M 2201/043 Sulfur; Selenenium; Tellurium
• CPC Class Codes: C10M 2201/05 Metals; Alloys
• CPC Class Codes: C10M 2201/062 Oxides; Hydroxides; Carbonates or bicarbonates
• CPC Class Codes: C10M 2201/065 Sulfides; Selenides; Tellurides
• CPC Class Codes: C10M 2201/066 Molybdenum sulfide
• CPC Class Codes: C10M 2201/081 containing halogen
• CPC Class Codes: C10M 2201/082 containing nitrogen
• CPC Class Codes: C10M 2201/083 nitrites
• CPC Class Codes: C10M 2201/084 : containing sulfur, selenium or tellurium
• CPC Class Codes: C10M 2215/02 : Amines, e.g. polyalkylene polyamines; Quaternary amines
• CPC Class Codes: C10M 2215/08 : Amides
• CPC Class Codes: C10M 2215/082 : containing hydroxyl groups; Alkoxylated derivatives
• CPC Class Codes: C10M 2215/086 : Imides
• CPC Class Codes: C10M 2215/12 : Partial amides of polycarboxylic acids
• CPC Class Codes: C10M 2215/122 : Phtalamic acid
• CPC Class Codes: C10M 2219/022 : of hydrocarbons, e.g. olefines
• CPC Class Codes: C10M 2227/00 : Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
• CPC Class Codes: C10M 2227/09 : Complexes with metals
• CPC Class Codes: C10N 2010/12 : Groups 6 or 16

Abstract

A lubricating oil additive is prepared by reacting a triglyceride with a basic nitrogen compound to form a reaction product, reacting said reaction product with an acidic molybdenum compound to form an intermediate reaction product, and reacting said intermediate reaction product with a sulfur compound to produce a lubricating oil additive.

Claims

1. A lubricant additive prepared by reacting a triglyceride with a basic nitrogen compound employing a mole ratio of said triglyceride to said basic nitrogen compound in the range from about 2:

1 to 1;

3 respectively to produce a reaction product, reacting said reaction product with a acidic molybdenum compound employing a mole ratio of said reaction product to said molybdenum compound in the range from about 2;

1 to 1;

3 respectively to produce a second reaction product, and reacting said second reaction product with a sulfur compound employing a mole ratio of said second reaction product, based on molybdenum, to said sulfur in the range from about 1;

1 to 1;

4 respectively to produce said lubricant additive.

2. A lubricant additive according to claim 1 at which said triglyceride is represented by the formula:

##STR3## in which R, R'"'"' and R" represent aliphatic hydrocarbon radicals having from about 7 to 21 carbon atoms.

3. A lubricant additive according to claim 1 in which said reactions are conducted at a temperature above 100°

C. under an inert atmosphere.

4. A lubricant additive according to claim 1 in which said reaction steps are conducted at a temperature in the range from about 120°

to 200°

C.

5. A lubricant additive according to claim 1 in which said triglyceride is selected from the group consisting of coconut oil, safflower oil, sunflower oil, cottonseed oil, peanut oil, corn oil, castor oil, soybean oil, palm oil, sesame oil, animal oils and fats such as lard oil and tallow.

6. A lubricant additive according to claim 1 in which said acidic molybdenum compound is selected from the group consisting of molybdenum trioxide, molybdic acid and ammonium molybdate.

7. A lubricant additive according to claim 1 which said reaction steps are conducted under a nitrogen atmosphere while a stream of nitrogen is passed through the reaction mixtures at a rate ranging from about 25 to 200 milliliters per minute per liter of reaction mixture.

9. A lubricant additive according to claim 1 containing from about 1 to 4 weight percent nitrogen, from about 2 to 6 weight percent molybdenum and from about 1 to 4 weight percent sulfur.

10. A lubricant additive according to claim 1, in which the basic nitrogen compound is selected from the group consisting of polyalkylene polyamines, succinimides and carboxylic acid amides.

11. A lubricant additive according to claim 10 in which the polyalkylene polyamines are diethylenetriamine, triethylenetetramine, tetraethylenepentamine, and pentaethylenehexamine.

12. A lubricant additive according to claim 1 in which the sulfur compound is selected from elemental sulfur, sulfurized olefins, hydrogen sulfide and ammonium sulfides and polysulfides.

8. A lubricant composition prepared by reacting sunflower oil with diethylenetriamine at a temperature in the range of 125°

to 175°

C. under an inert atmosphere employing a mole ratio of said sunflower oil to said diethylenetriamine of about 1;

1 to produce a reaction product, reacting said reaction product with molybdenum trioxide at a temperature at a range of 125°

to 175°

C. under an inert atmosphere employing a mole ratio of said reaction product to said molybdenum trioxide of about 1;

1 to produce a second reaction product, and reacting said second reaction product with sulfur at a temperature at a range of 125°

to 175°

C. under an inert atmosphere employing a mole ratio of said second reaction product to said sulfur ranging from about 1 to 2 respectively to produce said lubricant additive.

13. A lubricant additive prepared by reacting a triglyceride with a polyalkyene polyamine compound employing a mole ratio of triglyceride to polyalkylene polyamine in the range from about 2:

1 to 1;

3 respectively to produce a first reaction product, reacting said first reaction product with an acidic molybdenum compound employing a mole ratio of said first reaction product to said molybdenum compound in the range from about 2;

1 to 1;

3 respectively to produce a second reaction product, and reacting said second reaction product with a sulfur compound employing a mole ratio of said second reaction product based on molybdenum to said sulfur in the range from about 1;

1 to 1;

4 respectively to produce said lubricant additive, said polyalkylene polyamine compound being represented by the formula;

##STR4## in which R is hydrogen or a methyl radical and x has a value from 1 to 10.