Storage stable heat curable organosiloxane compositions containing microencapsulated platinum-containing catalysts

• US 4,766,176 A
• Filed: 07/20/1987
• Issued: 08/23/1988
• Est. Priority Date: 07/20/1987
• Status: Expired

• Current Assignee: Dow Corning Corporation (Dow, Inc.)
• Original Assignee: Dow Corning Corporation (Dow, Inc.)
• Inventors: Saam, John C., Lee, Chi-long, Juen, Donnie R., Willis, Robin L. Jr.
• Primary Examiner(s): Marquis, Melvyn I.
• Application Number:
  US07/075,177
• Time in Patent Office: 400 Days
• Field of Search: 528/15, 528/31, 528/32, 525/478, 525/100, 525/104, 525/105
• US Class Current: 525/100
• CPC Class Codes: C08F 30/08 containing silicon
• CPC Class Codes: C08F 8/42 Introducing metal atoms or metal-containing groups
• CPC Class Codes: C08G 77/12 containing silicon bound to hydrogen C08G77/045 takes precedence
• CPC Class Codes: C08G 77/20 containing silicon bound to unsaturated aliphatic groups C08G77/045 takes precedence
• CPC Class Codes: C08J 2383/04 Polysiloxanes
• CPC Class Codes: C08J 3/241 Preventing premature crosslinking by physical separation of components, e.g. encapsulation
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes

Abstract

Storage stable, one part organosiloxane compositions that cure upon heating by a platinum-catalyzed hydrosilation reaction comprise, in addition to the organosiloxane reactants, a platinum-containing hydrosilation catalyst that is microencapsulated within one or two layers of thermoplastic organic polymers. The microcapsules are formed using known techniques.

Claims

1. In an improved one-part, storage stable, heat curable organosiloxane composition comprising

(A) a curable polyorganosiloxane containing at least two ethylenically unsaturated hydrocarbon radicals per molecule;

(B) an organohydrogensiloxane containing at least two silicon bonded hydrogen atoms per molecule in an amount sufficient to achieve curing of said polyorganosiloxane (A), where the sum of the average number of ethylenically unsaturated hydrocarbon radicals per molecule of (A) and the average number of silicon bonded hydrogen atoms per molecule of said organohydrogensiloxane (B) is greater than 4, and

(C) an amount of a platinum-containing hydrosilation catalyst sufficient to promote curing of said composition at a temperature of at least 70°

C. and above,

the improvement comprising the presence of said platinum-containing catalyst in the form of microcapsules that in turn, comprise said catalyst as finely divided particles or droplets that are completely enveloped within a thermoplastic organic polymer where the average diameter of said microcapsules is less than 500 microns, and said thermoplastic organic polymer constitutes at least 50 percent of the weight of said microcapsules.

2. An composition according to claim 1 where said thermoplastic organic polymer constitutes at least 70 percent of the microcapsule weight, said polymer is derived from at least one ethylenically unsaturated organic compound or a condensation reaction between at least two organic compounds containing a plurality of condensable groups per molecule.

3. A composition according to claim 2 where said microcapsules are formed by precipitation of a preformed polymer in the presence of said catalyst where said catalyst is in the form of finely divided liquid droplets or finely divided solid particles.

4. A composition according to claim 2 where said polymer is formed in the presence of said catalyst in the form of a finely divided solid.

5. A composition according to claim 2 where said catalyst is the reaction product of a compound comprising a platinum atom and at least one halogen atom with an ethylenically unsaturated liquid organosilicon compound, and said ethylenically unsaturated organic compound is selected from the group consisting of ethylenically unsaturated hydrocarbons, acrylonitrile, esters of acrylic acid and esters methacrylic acid.

6. A composition according to claim 5 where said platinum compound is hexachloroplatinic acid.

7. A composition according to claim 6 where said organosilicon compound is a hexaorganodisiloxane.

8. A composition according to claim 1 where said catalyst is enveloped within an inner and an outer layer of thermoplastic organic polymers.

9. A composition according to claim 8 where said inner and outer layers are formed by precipitation of a preformed organic polymer in the presence of said catalyst in the form of finely divided liquid droplets or finely divided solid particles.

10. A composition according to claim 8 where the polymers constituting said inner and outer layer are different.

11. A composition according to claim 10 where said inner layer is formed from polystyrene and said outer layer is formed from cellulose acetate butyrate.

12. A composition according to claim 1 where said organosiloxane composition is in the form of a liquid.

13. A composition according to claim 1 where said organosiloxane composition is in the form of a high consistency gum.