Herbicidal compositions comprising phenyl carbamates and other herbicides

• US 4,767,448 A
• Filed: 09/20/1984
• Issued: 08/30/1988
• Est. Priority Date: 02/29/1984
• Status: Expired due to Term

• Current Assignee: Schering Ag (Merck & Co., Inc.)
• Original Assignee: Kemisk Vaerk KOGE A/S
• Inventors: Nielsen, Erik
• Primary Examiner(s): Hollrah, Glennon H.
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US06/652,620
• Time in Patent Office: 1,440 Days
• Field of Search: 71/DIG. 1, 71/111
• US Class Current: 504/301
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 43/707 1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
• CPC Class Codes: A01N 47/22 O-Aryl or S-Aryl esters thereof

Abstract

Stabilized liquid herbicidal compositions containing at least one substituted phenyl carbamate of the general formula I ##STR1## in which R¹ represents a C₁ -C₆ alkyl group, a C₃ -C₆ cycloalkyl group or an aryl group, which aryl group may be substituted by a halogen atom and/or a C₁ -C₆ alkyl group and/or a trifluoromethyl group, and R² represents a C₁ -C₆ alkyl, C₂ -C₆ alkenyl or C₂ -C₆ alkynyl group that may be substituted by a terminal halogen atom, and optionally at least one herbicidally active compound selected from the group consisting of 5-amino-4-chloro-2-phenyl-3(2H)pyridazinone, 2-ethoxy-2,3-dihydro-3,3-dimethylbenzofuran-5-yl methanesulphonate, and 4-amino-4,5-dihydro-3-methyl-6-phenyl-1,2,4-triazin-5-one are prepared by dispersing the compound(s) in finely ground state in a liquid phase which comprises one or more oily components and one or more surfactants and which is able to form an oil-in-water emulsion or a microemulsion when mixed with water.

Claims

1. A stabilized liquid herbicidal composition comprising as an active ingredient a herbicidally effective amount of phenmedipham and/or desmedipham in which the active ingredient in a finely ground state is dispersed in an acidic liquid phase which comprises at least one oily component in an amount of 5-75% by weight, and at least one surfactant in an amount of 5-60% by weight, said oily component and surfactant may be able to form a stable solution which is capable of effectively suspending the active ingredient and said oily component being a mixture comprising a mineral oil, a chlorinated mineral oil or a vegetable oil in combination with at least one lower carboxylic acid ester of a monoalcohol or polyalcohol.

2. A composition according to claim 1 wherein the liquid phase comprises an oily component in an amount of 15-65% by weight.

3. A composition according to claim 1 comprising phenmedipham in an amount of 15-40% by weight formulated with an oily component in an amount of 10-75% by weight, and one or more surfactants in an amount of 5-25% by weight.

4. A composition according to claim 1 wherein a part of the surfactant is a phosphoric acid ester salt and/or an alkyl or aryl or alkaryl sulphonic acid salt, the total amount of surfactant mixture being 5-25% by weight.

5. A composition according to claim 1 in which the oily component and the surfactant and the relative amounts thereof are adapted such that the liquid phase forms a microemulsion or a translucent emulsion when mixed with water in the ratio 1:

1-1;

10 by weight.

6. The composition according to claim 1, wherein the pH of the composition is from 2 to 4.

7. The composition according to claim 1, wherein the surfactants are selected from the group consisting of polyethoxylated alkylphenols, polyethoxylated higher alkanols, alklarylsulphonic acids and phosphoric acid esters and salts thereof, and mixtures thereof.

8. A method for combating weeds comprising applying the composition according to claim 1 to an area where the weeds grow or will grow.

9. A method according to claim 8, wherein the composition is applied to beet fields.

10. The composition according to claim 1, wherein the surfactant comprises non-ionic, ampholytic, and/or cationic surfactants.

11. The composition according to claim 10, wherein the surfactant constitutes 10-40% by weight of the composition.

12. A method for combating weeds according to claim 8, wherein the composition further comprises water and surfactant to wet the sprayed surface.

13. A composition according to claim 1, wherein the active ingredient is 5-40% by weight of the composition.