Compact electrochemical cell for gas detection

• US 4,769,122 A
• Filed: 07/10/1987
• Issued: 09/06/1988
• Est. Priority Date: 07/10/1987
• Status: Expired due to Fees

• Current Assignee: Bacharach Inc. (MSA Safety, Inc.)
• Original Assignee: Bacharach Inc. (MSA Safety, Inc.)
• Inventors: Marrese, Carl A., D'Amico, David J., Wolf, John H., Sicree, Andrew A., Noble, Peter M., Novack, Robert L.
• Primary Examiner(s): Kaplan, G. L.
• Application Number:
  US07/072,215
• Time in Patent Office: 424 Days
• Field of Search: 204/412, 204/431, 204/432, 204/408
• US Class Current: 204/408
• CPC Class Codes: G01N 27/4045 for gases other than oxygen

Abstract

An electrochemical cell for use in gas detection includes a cell body having an electrolyte cavity and a separate sensor cavity. The sensor cavity holds stacked sensor elements including a counter electrode, electrolyte mat, reference electrode and sensing electrode. A wick draws the electrolyte from the electrolyte cavity to the electrolyte mat. The sensing electrode closes off the sensor cavity and seals the counter and reference electrodes therein. The only gas which contacts the counter and reference electrodes is that which passes through the sensing electrode or is generated by the counter electrode and becomes dissolved in the electrolyte.

Claims

1. An electrochemical cell for gas detection comprising an impervious nonconductive cell body having an electrolyte cavity and a separate sensor cavity formed therein, said electrolyte cavity being at least partially filled with a liquid electrolyte, said sensor cavity having a plurality of sensor elements stacked therein including a counter electrode positioned at an inner end of said sensor cavity, a gas diffusion sensing electrode containing a catalytic material and positioned at an outer end of said sensor cavity and spaced from said counter electrode, an electrolyte mat positioned between and contacting said counter and sensing electrodes, and a reference electrode disposed within said electrolyte mat and spaced from said counter and sensing electrodes, said reference electrode formed of a non-porous, conductive material coated with a layer of a catalytic material, and with said counter electrode being a porous, hydrophilic, conductive structure containing a catalytic material, with said catalytic material of said sensing, counter and reference electrodes oxidizing or reducing a particular gas or particular gases coming in contact therewith, said sensing electrode closing off the outer end of said sensor cavity and sealing said counter electrode, reference electrode and electrolyte mat within said sensor cavity, said cell including wick means for wicking liquid electrolyte from said electrolyte cavity to said electrolyte mat, and including means for making electrical contact with said counter, reference and sensing electrodes, wherein said counter and reference electrodes are submerged within said sensor cavity by said sensing electrode and any gas contacting said counter and reference electrodes passes through said sensing electrode and is dissolved in said electrolyte.

2. The electrochemical cell of claim 1 wherein said sensing electrode includes a catalytic material which will reduce a particular gas in contact therewith.

3. The electrochemical cell of claim 1 wherein said sensing electrode includes a catalytic material which will oxidize a particular gas in contact therewith.

4. The electrochemical cell of claim 1 wherein said counter electrode is formed of an electrochemically non-reactive metal coated with a layer of a catalytic material.

5. The electrochemical cell of claim 1 wherein said electrolyte mat includes a top mat in contact with said sensing electrode and an adjacent bottom mat in contact with said counter electrode and with said top mat, with the reference electrode positioned between and in contact with said top mat and said bottom mat.

6. The electrochemical cell of claim 5 wherein said wick means is a stem extending through said counter electrode and between the electrolyte in said electrolyte cavity and said bottom mat.

7. The electrochemical cell of claim 6 wherein said electrolyte cavity is separated from said sensor cavity by a dividing wall and said stem extends through a slot in said dividing wall.

8. The electrochemical cell of claim 7 wherein said bottom mat is formed of a first bottom mat and an adjacent second bottom mat, and wherein said stem includes a first stem integral with said first bottom mat and a second stem integral with said second bottom mat.

9. The electrochemical cell of claim 6 wherein said top mat, bottom mat and stem are formed of a glass fiber material.

10. The electrochemical cell of claim 1 wherein said sensing electrode has a conductive outer surface and said cell further includes a conductive ring in contact with the outer surface of said sensing electrode and electrically connected to a sensing electrode terminal at an outer portion of said cell.

11. The electrochemical cell of claim 1 further including a diffusion barrier through which gas must flow to reach the sensing electrode.

12. The electrochemical cell of claim 11 wherein said diffusion barrier is a capillary tube.

13. The electrochemical cell of claim 1 wherein said cell body has one or more vents extending into said electrolyte cavity, with said vents covered by a gas permeable and liquid impermeable membrane.

14. The electrochemical cell of claim 1 wherein said cell body has a fill hole extending into said electrolyte cavity, with said fill hole closed by a removable plug.

15. An electrochemical cell for gas detection comprising an impervious, nonconductive cell body having an electrolyte cavity extending into said cell body from a rear surface thereof and a sensor cavity extending into said cell body from a front surface thereof, a dividing wall separating said sensor cavity and electrolyte cavity, means for closing off said electrolyte cavity at said rear surface, said electrolyte cavity being at least partially filled with a liquid electrolyte, said sensor cavity having a counter electrode at an inner end thereof and adjacent said dividing wall, an electrolyte mat adjacent said counter electrode, a gas diffusion sensing electrode containing a catalytic material and positioned adjacent said electrolyte mat and spaced from said counter electrode, a reference electrode disposed within said electrolyte mat and spaced from said counter and sensing electrodes, with said reference electrode formed of a non-porous, conductive material coated with a layer of a catalytic material, and with said counter electrode being a porous, hydrophilic, conductive structure containing a catalytic material, with said catalytic material of said sensing, counter and reference electrodes oxidizing or reducing a particular gas or particular gases coming in contact therewith, said sensing electrode closing off said sensor cavity at said front surface and sealing said counter electrode, reference electrode and electrolyte mat therein, said cell including a wick which extends between said electrolyte mat and the electrolyte in said electrolyte cavity and passes through said counter electrode and dividing wall, and including means for making electrical contact with said counter, reference and sensing electrodes, wherein said counter and reference electrodes are submerged within said sensor cavity by said sensing electrode and any gas contacting said counter and reference electrodes passes through said sensing electrode and is dissolved in said electrolyte.

16. The electrochemical cell of claim 15 wherein said sensing electrode includes a catalytic material which will reduce a particular gas in contact therewith.

17. The electrochemical cell of claim 15 wherein said sensing electrode includes a catalytic material which will oxidize a particular gas in contact therewith.

18. The electrochemical cell of claim 15 wherein said counter electrode is formed of an electrochemically non-reactive metal coated with a layer of a catalytic material.

19. The electrochemical cell of claim 15 wherein said sensing electrode has a conductive outer surface and said cell further includes a conductive ring in contact with the outer surface of said sensing electrode and electrically connected to a sensing electrode terminal at a front portion of said cell.

20. The electrochemical cell of claim 15 further including a diffusion barrier through which gas must flow to reach the sensing electrode.

21. An electrochemical cell for gas detection comprising an impervious nonconductive cell body having an electrolyte cavity and a separate sensor cavity formed therein, said electrolyte cavity being at least partially filled with a liquid electrolyte, said sensor cavity having a plurality of sensor elements stacked therein including a counter electrode positioned at an inner end of said sensor cavity, a gas diffusion sensing electrode containing a catalytic material and positioned at an outer end of said sensor cavity and spaced from said counter electrode, an electrolyte mat positioned between and contacting said counter and sensing electrodes, and a reference electrode disposed within said electrolyte mat and spaced from said counter and sensing electrodes, said reference electrode formed of a non-porous, conductive material coated with a layer of catalytic material, and with said counter electrode being a porous, hydrophilic, conductive structure containing a catalytic material, with said catalytic material of said sensing, counter and reference electrodes oxidizing or reducing a particular gas or particular gases coming in contact therewith, said sensing electrode closing off the outer end of said sensor cavity and sealing said counter electrode, reference electrode and electrolyte mat within said sensor cavity, said cell including wick means for wicking liquid electrolyte from said electrolyte cavity to said electrolyte mat, and including means for making electrical contact with said counter, reference and sensing electrodes, wherein said counter and reference electrodes are submerged within said sensor cavity by said sensing electrode and any gas contacting said counter and reference electrodes passes through said sensing electrode and is dissolved in said electrolyte, and further including a wire ring positioned behind and in contact with said counter electrode and terminating in a counter electrode lead wire which extends through said cell body and through said electrolyte cavity to a counter electrode connector at an outer portion of said cell and forms the means for making electrical contact with said counter electrode.

22. The electrochemical cell of claim 21 wherein said wire ring is formed of platinum.

23. The electrochemical cell of claim 21 further including a carbon cloth positioned behind and in contact with said counter electrode and said wire ring.

24. An electrochemical cell for gas detection comprising an impervious nonconductive cell body having an electrolyte cavity and a separate sensor cavity formed therein, said electrolyte cavity being at least partially filled with a liquid electrolyte, said sensor cavity having a plurality of sensor elements stacked therein including a counter electrode positioned at an inner end of said sensor cavity, a gas diffusion sensing electrode containing a catalytic material and positioned at an outer end of said sensor cavity and spaced from said counter electrode, an electrolyte mat positioned between and contacting said counter and sensing electrodes, and a reference electrode disposed within said electrolyte mat and spaced from said counter and sensing electrodes, with said reference electrode being a metal wire formed into one or more spaced loops and coated with a layer of a catalytic material, and with said counter electrode being a porous, hydrophilic, conductive structure containing a catalytic material, with said catalytic material of said sensing, counter and reference electrodes oxidizing or reducing a particular gas or particular gases coming in contact therewith, said sensing electrode closing off the outer end of said sensor cavity and sealing said counter electrode, reference electrode and electrolyte mat within said sensor cavity, said cell including wick means for wicking liquid electrolyte from said electrolyte cavity to said electrolyte mat, and including means for making electrical contact with said counter, reference and sensing electrodes, wherein said counter and reference electrodes are submerged within said sensor cavity by said sensing electrode and any gas contacting said counter and reference electrode passes through said sensing electrode and is dissolved in said electrolyte.

25. The electrochemical cell of claim 24 wherein said reference electrode is a platinum wire formed into a plurality of spaced loops and coated with a layer of platinum black.

26. An electrochemical cell for gas detection comprising an impervious nonconductive cell body having an electrolyte cavity and a separate sensor cavity formed therein, said electrolyte cavity being at least partially filled with a liquid electrolyte, said sensor cavity having a plurality of sensor elements stacked therein including a counter electrode positioned at an inner end of said sensor cavity, a gas diffusion sensing electrode containing a catalytic material and positioned at an outer end of said sensor cavity and spaced from said counter electrode, an electrolyte mat positioned between and contacting said counter and sensing electrodes, and a reference electrode disposed within said electrolyte mat and spaced from said counter and sensing electrodes, said reference electrode formed of a non-porous, conductive material coated with a layer of a catalytic material, and with said counter electrode being a porous, hydrophilic, conductive structure containing a catalytic material, with said catalytic material of said sensing, counter and reference electrodes oxidizing or reducing a particular gas or particular gases coming in contact therewith, said sensing electrode closing off the outer end of said sensor cavity and sealing said counter electrode, reference electrode and electrolyte mat within said sensor cavity, said cell including wick means for wicking liquid electrolyte from said electrolyte cavity to said electrolyte mat, and including means for making electrical contact with said counter, reference and sensing electrodes, wherein said counter and reference electrodes are submerged within said sensor cavity by said sensing electrode and any gas contacting said counter and reference electrodes passes through said sensing electrode and is dissolved in said electrolyte, and further including a reference electrode lead wire connected to said reference electrode and which extends through said electrolyte mat, counter electrode, cell body and electrolyte cavity to a reference electrode connector at an outer portion of said cell and forms the means for making electrical contact with said reference electrode.

27. An electrochemical cell for gas detection comprising an impervious nonconductive cell body having an electrolyte cavity and a separate sensor cavity formed therein, said electrolyte cavity being at least partially filled with a liquid electrolyte, said sensor cavity having a plurality of sensor elements stacked therein including a counter electrode positioned at an inner end of said sensor cavity, a gas diffusion sensing electrode containing a catalytic material and positioned at an outer end of said sensor cavity and spaced from said counter electrode, an electrolyte mat positioned between and contacting said counter and sensing electrodes, and a reference electrode disposed within said electrolyte mat and spaced from said counter and sensing electrodes, said reference electrode formed of a non-porous, conductive material coated with a layer of a catalytic material, and with said counter electrode being a porous, hydrophilic, conductive structure containing a catalytic material, with said catalytic material of said sensing, counter and reference electrodes oxidizing or reducing a particular gas or particular gases coming in contact therewith, said sensing electrode closing off the outer end of said sensor cavity and sealing said counter electrode, reference electrode and electrolyte mat within said sensor cavity, said cell including wick means for wicking liquid electrolyte from said electrolyte cavity to said electrolyte mat, and including means for making electrical contact with said counter, reference and sensing electrodes, wherein said counter and reference electrodes are submerged within said sensor cavity by said sensing electrode and any gas contacting said counter and reference electrodes passes through said sensing electrode and is dissolved in said electrolyte, with said sensing electrode having a conductive outer surface, said cell including a conductive ring in contact with the outer surface of said sensing electrode and electrically connected to a sensing electrode terminal at an outer portion of said cell, and including a planar sensor contact in contact with said conductive ring and extending to said sensing electrode terminal, said sensor contact having an enlarged portion spaced from and covering said sensing electrode, with said enlarged portion having a plurality of holes therethrough to permit gas flow to said sensing electrode.

28. An electrochemical cell for gas detection comprising an impervious, nonconductive cell body having an electrolyte cavity extending into said cell body from a rear surface thereof and a sensor cavity extending into said cell body from a front surface thereof, a dividing wall separating said sensor cavity and electrolyte cavity, means for closing off said electrolyte cavity at said rear surface, said electrolyte cavity being at least partially filled with a liquid electrolyte, said sensor cavity having a counter electrode at an inner end thereof and adjacent said dividing wall, an electrolyte mat adjacent said counter electrode, a gas diffusion sensing electrode containing a catalytic material and positioned adjacent said electrolyte mat and spaced from said counter electrode, a reference electrode disposed within said electrolyte mat and spaced from said counter and sensing electrodes, with said reference electrode formed of a non-porous, conductive material coated with a layer of a catalytic material, and with said counter electrode being a porous, hydrophilic, conductive structure containing a catalytic material, with said catalytic material of said sensing, counter and reference electrodes oxidizing or reducing a particular gas or particular gases coming in contact therewith, said sensing electrode closing off said sensor cavity at said front surface and sealing said counter electrode, reference electrode and electrolyte mat therein, said cell including a wick which extends between said electrolyte mat and the electrolyte in said electrolyte cavity and passes through said counter electrode and dividing wall, and including means for making electrical contact with said counter, reference and sensing electrodes, wherein said counter and reference electrodes are submerged within said sensor cavity by said sensing electrode and any gas contacting said counter and reference electrodes passes through said sensing electrode and is dissolved in said electrolyte, and further including a wire ring positioned behind and in contact with said counter electrode and terminating in a counter electrode lead wire which extends through said dividing wall and through said electrolyte cavity to a counter electrode connector at a rear portion of said cell and forms the means for making electrical contact with said counter electrode.

29. The electrochemical cell of claim 28 further including a reference electrode lead wire connected to said reference electrode and which extends through said electrolyte mat, counter electrode, dividing wall and electrolyte cavity to a reference electrode connector at a rear portion of said cell and forms the means for making electrical contact with said reference electrode.

30. The electrochemical cell of claim 29 wherein said counter electrode connector and said reference electrode connector are carried by a printed circuit board mounted to said cell body at the rear surface.

31. The electrochemical cell of claim 28 wherein said wire ring is formed of platinum.

32. The electrochemical cell of claim 28 further including a carbon cloth positioned behind and in contact with said counter electrode and said wire ring.

33. An electrochemical cell for gas detection comprising an impervious, nonconductive cell body having an electrolyte cavity extending into said cell body from a rear surface thereof and a sensor cavity extending into said cell body from a front surface thereof, a dividing wall separating said sensor cavity and electrolyte cavity, means for closing off said electrolyte cavity at said rear surface, said electrolyte cavity being at least partially filled with a liquid electrolyte, said sensor cavity having a counter electrode at an inner end thereof and adjacent said dividing wall, an electrolyte mat adjacent said counter electrode, a gas diffusion sensing electrode containing a catalytic material and positioned adjacent said electrolyte mat and spaced from said counter electrode, a reference electrode disposed within said electrolyte mat and spaced from said counter and sensing electrodes, with said reference electrode being a metal wire formed into one or more spaced loops coated with a layer of a catalytic material, and with said counter electrode being a porous, hydrophilic, conductive structure containing a catalytic material, with said catalytic material of said sensing, counter and reference electrodes oxidizing or reducing a particular gas or particular gases coming in contact therewith, said sensing electrode closing off said sensor cavity at said front surface and sealing said counter electrode, reference electrode and electrolyte mat therein, said cell including a wick which extends between said electrolyte mat and the electrolyte in said electrolyte cavity and passes through said counter electrode and dividing wall, and including means for making electrical contact with said counter, reference and sensing electrodes, wherein said counter and reference electrodes are submerged within said sensor cavity by said sensing electrode and any gas contacting said counter and reference electrodes passes through said sensing electrode and is dissolved in said electrolyte.

34. The electrochemical cell of claim 33 wherein said reference electrode is a platinum wire formed into a plurality of spaced loops and coated with a layer of platinum black.

35. An electrochemical cell for gas detection comprising an impervious, nonconductive cell body having an electrolyte cavity extending into said cell body from a rear surface thereof and a sensor cavity extending into said cell body from a front surface thereof, a dividing wall separating said sensor cavity and electrolyte cavity, means for closing off said electrolyte cavity at said rear surface, said electrolyte cavity being at least partially filled with a liquid electrolyte, said sensor cavity having a counter electrode at an inner end thereof and adjacent said dividing wall, an electrolyte mat adjacent said counter electrode, a gas diffusion sensing electrode containing a catalytic material and positioned adjacent said electrolyte mat and spaced from said counter electrode, a reference electrode disposed within said electrolyte mat and spaced from said counter and sensing electrodes, with said reference electrode formed of a non-porous, conductive material coated with a layer of a catalytic material, and with said counter electrode being a porous, hydrophilic, conductive structure containing a catalytic material, with said catalytic material of said sensing, counter and reference electrodes oxidizing or reducing a particular gas or particular gases coming in contact therewith, said sensing electrode closing off said sensor cavity at said front surface and sealing said counter electrode, reference electrode and electrolyte mat therein, said cell including a wick which extends between said electrolyte mat and the electrolyte in said electrolyte cavity and passes through said counter electrode and dividing wall, and including means for making electrical contact with said counter, reference and sensing electrodes, wherein said counter and reference electrodes are submerged within said sensor cavity by said sensing electrode and any gas contacting said counter and reference electrodes passes through said sensing electrode and is dissolved in said electrolyte, with said sensing electrode having a conductive outer surface, said cell including a conductive ring in contact with the outer surface of said sensing electrode and electrically connected to a sensing electrode terminal at a front portion of said cell, and including a planar sensor contact in contact with said conductive ring and extending to said sensing electrode terminal, said sensor contact having an enlarged portion spaced from and covering said sensing electrode, with said enlarged portion having a plurality of holes therethrough to permit gas flow to said sensing electrode.