Solid polymer electrolyte fuel cell stack water management system

• US 4,769,297 A
• Filed: 11/16/1987
• Issued: 09/06/1988
• Est. Priority Date: 11/16/1987
• Status: Expired due to Fees

• Current Assignee: International Fuel Cells Corporation South Windsor CT
• Original Assignee: International Fuel Cells Corporation (Doosan Corporation)
• Inventors: Sawyer, Richard D., Reiser, Carl A.
• Primary Examiner(s): Hearn, Brian E.
• Assistant Examiner(s): Kalafut, Stephen J.
• Application Number:
  US07/121,008
• Time in Patent Office: 295 Days
• Field of Search: 429/17, 429/30, 429/33, 429/34-39
• US Class Current: 429/413
• CPC Class Codes: H01M 2008/1095 Fuel cells with polymeric electrolytes
• CPC Class Codes: H01M 8/04007 related to heat exchange
• CPC Class Codes: H01M 8/04119 with simultaneous supply or evacuation of electrolyte; Humidifying or dehumidifying
• CPC Class Codes: H01M 8/2483 characterised by internal manifolds
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

Water is fed into the fuel cell stack in the hydrogen reactant stream. Some of the water is evaporated in the cells to cool the stack, and some of the water migrates through the stack from cell to cell. The water migration is the result of the water being dragged from the anode to the cathode through the electrolyte membrane and by the use of porous hydrophilic separator plates being interposed between adjacent cells in the stack. Water is forced through these porous separator plates by means of a reactant pressure differential maintained between the cathode and anode. The anode support plates provide a large surface area from which water is evaporated to perform the cooling function.

Claims

1. A solid polymer fuel cell stack power assembly comprising:

(a) a plurality of fuel cells stacked one atop another, each of said fuel cells comprising;

(i) a solid polymr electrolyte membrane;

(ii) means forming an anode on one face of said electrolyte membrane, and means forming a cathode of an opposite face of said electrolyte membrane;

(iii) a porous anode flow field plate disposed adjacent to said anode, said anode flow field plate having a contoured surface facing said anode with a plurality of grooves forming a hydrogen reactant flow field, and a plurality of intervening projections disposed in contact with said anode;

(iv) a porous cathode flow field plate disposed adjacent to said cathode, said cathode flow field plate having a contoured surface facing said cathode with a plurality of grooves forming an oxygen reactant flow field, and a plurality of intervening projections disposed in contact with said cathode;

(b) with the exception of an initial cell in the stack, each of said cells in the stack having its anode flow field plate disposed back-to-back with the cathode flow field plate of an adjacent cell;

(c) porous hydrophilic separator plates interposed between each of the back-to-back anode and cathode flow field plates;

(d) means for admitting hydrogen into said hydrogen reactant flow fields;

(e) means for entraining sufficient water in the hydrogen prior to entering the hydrogen reactant flow fields to sufficiently moisten said anode flow field plates to an extent that cooling of said fuel cells is accomplished by evaporation of water from said anode flow field plates, and sufficient unevaporated water will remain in said anode flow field plates to saturate the anode faces of the electrolyte membranes;

(f) means for admitting oxygen reactant into said oxygen reactant flow fields; and

(g) means for maintaining the oxygen reactant flow fields at an operating pressure which is sufficiently greater than the operating pressure of said hydrogen reactant flow fields to force water absorbed by said cathode flow field plates from said cathode faces of said electrolyte membranes to flow through said porous separator plates and into said anode flow field plates in adjacent cells.

2. The assembly of claim 1 further comprising condenser means for condensing evaporated water out of a hydrogen/water vapor mixture exhausted from said anode flow fields.

3. The assembly of claim 2 further comprising recirculating means for recirculating the condensed water from said condenser means back to hydrogen reactant admitted to said anode flow fields.

4. The assembly of claim 3 wherein said recirculating means includes a pair of water holding tanks, one of which receives and stores water from said condenser means and the other of which supplies water to a pressurized hydrogen reactant flow stream.

5. The assembly of claim 4 comprising pressurizing means for selectively pressurizing each of said water tanks, whereby said one of said tanks can be temporarily pressurized to a higher pressure than said other of said tanks to periodically transfer water from said one tank to said other tank.

6. A solid polymer fuel cell stack power assembly comprising:

(a) a first solid polymer electrolyte membrane in a first cell;

(b) means forming a cathode on one side of said first electrolyte membrane;

(c) a porous cathode flow field plate disposed adjacent to said cathode and in face-to-face contact with said cathode, said cathode flow field plate defining an oxygen reactant flow field plate defining an oxygen reactant flow field adjacent to said first electrolyte membrane, and said cathode flow field plate being operable to absorb water appearing on said cathode as a result of proton transfer through said first electrolyte membrane and as a result of the electrochemical reaction in said first electrolyte membrane and cathode;

(d) a hydrophilic porous separator plate adjacent to and in face-to-face contact with said cathode flow field, said separator plate being operable to absorb water from said cathode flow field plate;

(e) a second solid polymer electrolyte membrane having an anode thereon in a second cell adjacent to said first cell;

(f) a porous anode flow field plate in said second cell interposed between and in face-to-face contact with each of said separator plate and said second electrolyte membrane anode, said anode flow field plate defining a hydrogen reactant flow field adjacent to said second electrolyte membrane anode, and said anode flow field plate being operable to;

absorb water from said separator plate;

transfer water to said second electrolyte membrane; and

provide water for evaporation in said hydrogen reactant flow field to cool said second cell and

(g) means for providing a higher reactant pressure in said oxygen reactant flow field in said first cell than the reactant pressure in said hydrogen reactant flow field in said second cell whereby water is pumped through said flow field plates and said separator plate in the direction of said second cell by the pressure differential.

7. A method for operating a solid polymer fuel cell stack power plant, said method comprising the steps of:

(a) providing a series of adjacent solid polymer fuel cells to form said stack;

(b) supplying an anode side of each of said fuel cells with a stream of pressurized hydrogen reactant having water entrained therein;

(c) absorbing water from said hydrogen reactant stream into a porous anode flow field plate in each cell and transferring water from said anode flow field plate to the anode side of a solid polymer electrolyte membrane in each cell;

(d) absorbing product water and water dragged across said membrane by proton movement across the membrane, into a porous cathode flow field plate contacting the cathode side of said membrane in each cell;

(e) providing a hydrophilic porous separator plate between each pair of adjacent cells in the stack and absorbing water into each separator plate from each of the cathode flow field plates in the stack; and

transferring water from each of the separator plates to an adjacent node flow field plate in an adjacent cell, whereby water moves along an axial flow path through the stack through each of the components thereof from one cell to the next until reaching the last cell along the flow path whereupon the water is removed from the stack, said water flow occurring continuously during operation of the stack; and

(f) providing a pressurized stream of oxygen reactant to said cathode side of said membrane in each cell, said oxygen reactant stream being at a higher pressure than said hydrogen reactant stream to aid in transferring the water through said cathode flow field plates and separator plates, to the anode flow field plates in the adjacent cells.

8. The method of claim 7 wherein an excess amount of water is entrained in the hydrogen reactant stream sufficient to provide said anode flow field plates with water for evaporative cooling of each cell in the stack.