Alkali promoted manganese oxide compositions containing titanium

• US 4,769,508 A
• Filed: 05/15/1986
• Issued: 09/06/1988
• Est. Priority Date: 12/18/1984
• Status: Expired due to Fees

• Current Assignee: Atlantic Richfield Company (BP PLC)
• Original Assignee: Atlantic Richfield Company (BP PLC)
• Inventors: Gastinger, Robert G., Withers, Howard P. Jr., Sofranko, John A.
• Primary Examiner(s): Dixon, Jr., William R.
• Assistant Examiner(s): Hunter, Jr., James M.
• Application Number:
  US06/864,644
• Time in Patent Office: 845 Days
• Field of Search: 585/654, 585/656, 585/658, 585/661, 585/500, 585/700, 585/943
• US Class Current: 585/500
• CPC Class Codes: C07C 2/84 catalytic
• CPC Class Codes: C07C 2521/06 Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
• CPC Class Codes: C07C 2521/08 Silica
• CPC Class Codes: C07C 2523/04 Alkali metals
• CPC Class Codes: C07C 2523/34 Manganese
• CPC Class Codes: Y10S 585/943 Synthesis from methane or inorganic carbon source, e.g. coal

Abstract

A class of mixed oxide catalysts comprising Mn-containing oxides, alkali metals or compounds thereof, and at least one member of the group consisting of oxides of Ti, mixed oxides of Ti and Si, and mixed oxides of Ti and at least one alkaline earth metal. In the more preferred embodiments, the third component serves as a carrier for the Mn and alkali metal components. The composition preferably comprises a major amount of the carrier material and minor amounts of the other components. The compositions are useful for hydrocarbon conversion, methane conversion, and oxidative dehydrogenation processes characterized by formation of coproduct water.

Claims

1. A method for converting methane to higher hydrocarbon products which comprises contacting at a temperature within the range of about 500°

to 1000°

C. a gas comprising methane with a solid comprising;

(a) a reducible oxide of Mn,

(b) at least one alkali metal or compound thereof, and

(c) at least one member of the group consisting of oxides of Ti, mixed oxides of Ti and Si, mixed oxides of Ti and at least one alkaline earth metal.

2. The method of claim 1 wherein the amount of Mn present in said solid is about 1 to about 40 wt. %, based on the combined weight of Mn and component (c).

3. The method of claim 1 wherein the atomic ratio of alkali metal:

Mn in said solid is within the range of about 0.01 to 10;

1.