Process for producing lubricant base oil

• US 4,770,763 A
• Filed: 06/23/1987
• Issued: 09/13/1988
• Est. Priority Date: 06/23/1986
• Status: Expired due to Fees

• Current Assignee: Japan Energy Corporation (ENEOS Holdings, Inc.)
• Original Assignee: Kyodo Oil Technical Research Center Co., Ltd. (ENEOS Holdings, Inc.), Nippon Mining Co Ltd (ENEOS Holdings, Inc.)
• Inventors: Kusayanagi, Sampo, Kaimai, Takashi
• Primary Examiner(s): Mc Farlane, Anthony
• Application Number:
  US07/065,459
• Time in Patent Office: 448 Days
• Field of Search: 208/14, 208/18, 208/19, 208/87, 208/86, 208/89, 208/98, 208/97, 208/96, 208/57, 208/33, 208/27, 208/99, 585/6.6
• US Class Current: 208/18
• CPC Class Codes: C10G 67/0418 The hydrotreatment being a hydrorefining
• CPC Class Codes: C10G 67/06 including a sorption process as the refining step in the absence of hydrogen
• CPC Class Codes: C10G 67/08 including acid treatment as the refining step in the absence of hydrogen
• CPC Class Codes: C10G 67/14 including at least two different refining steps in the absence of hydrogen

Abstract

A process for producing a lubricant base oil with low pour point and high aromaticity from a feedstock oil which is either a distillate fraction boiling at 250° C. or above that is obtained from a paraffin base or mixed base crude or a deasphalted oil obtained from a vacuum distillation residual oil of said crude, and process comprising:

(a) the step of bringing said feedstock oil into contact with a hydrofining catalyst in the presence of hydrogen and recovering a hydrofined oil;

(b) the step of dewaxing said hydrofined oil and recovering the dewaxed oil;

(c) the step of subjecting said dewaxed oil to extraction with a solvent having selective affinity for aromatic hydrocarbons so as to separate the feed into the raffinate portion and the extract portion, and removing the solvent from said extract portion to obtain an extract oil; and

(d) the step of treating said extract oil by means of contact with a solid adsorbent or sulfuric acid.

Claims

1. A process for producing a lubricant base oil having a pour point of 20°

C. or less and an n-d-M ring analysis value of at least 10% C_A from a feedstock oil which is selected from the qroup consisting of a distillate fraction boiling at 250°

C. or above obtained from a paraffin base or mixed base crude and a deasphalted oil obtained from a vacuum distillation residual oil of said crude, said process comprising;

(a) the step of bringing said feedstock oil into contact with a hydrofining catalyst in the presence of hydrogen under conditions to minimize hydrocracking and recovering a hydrofined oil;

(b) the step of dewaxing said hydrofined oil and recovering the dewaxed oil;

(c) the step of subjecting said dewaxed oil to extraction with a solvent having selective affinity for aromatic hydrocarbons so as to separate the feed into a raffinate portion and an extract portion, and removing the solvent from said extract portion to obtain an extract oil; and

(d) the step of treating said extract oil by means of contact with a solid adsorbent or sulfuric acid to stabilize said extract oil.

2. A process according to claim 1, wherein the base oil to be produced has a pour point in the range of from -30°

to -50°

C. and an n-d-M ring analysis value of at least 15% C_A.

3. A process according to claim 1, wherein the base oil produced has an n-d-M ring analysis value in the range of from 20 to 45% C_A.

4. A process according to claim 1, wherein the hydrofined oil has a sulfur content of no more than 1 wt % and a nitrogen content of no more than 300 ppm.

5. A process according to claim 1, wherein the dewaxed oil has a pour point of no higher than -10°

C.

6. A process according to claim 1, wherein the dewaxed oil is subjected to solvent extraction so as to attain the extract oil in a yield of from 5 to 40 vol %.

7. A rocess according to claim 1, wherein the dewaxed oil is subjected to solvent extraction so as to attain the extract oil in a yield of from 5 to 30 vol %.

8. A process according to claim 1, wherein the feedstock oil, prior to step (a), is subjected to extraction with a solvent having selective affinity for aromatic hydrocarbons and raffinate portion of 70 to 90% is obtained, and the raffinate portion, after removal of from 10 to 30% of the extraction portion, is subjected to treatments by steps (a), (b), (c) and (d).

9. A process according to claim 1, wherein said hydrotreating is conducted under a hydrogen pressure of from 30 to 80 kg/cm² G.

10. A process according to claim 1, wherein said hydrotreating is conducted under a hydrogen pressure of from 80 to 120 kg/cm² G.