Olefin polymerization catalyst composition

• US 4,771,024 A
• Filed: 05/07/1987
• Issued: 09/13/1988
• Est. Priority Date: 02/28/1986
• Status: Expired due to Term

• Current Assignee: Union Carbide Chemicals & Plastics Technology Corporation (Dow, Inc.)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Job, Robert C., Burstain, Israel G., Nestlerode, Steven M.
• Primary Examiner(s): GARVIN, PATRICK
• Application Number:
  US07/053,491
• Time in Patent Office: 495 Days
• Field of Search: 502/120, 502/125, 502/127, 502/128, 502/133, 502/134, 502/121, 502/123, 502/124
• US Class Current: 502/127
• CPC Class Codes: C08F 10/00 Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
• CPC Class Codes: C08F 4/6465 containing silicium
• CPC Class Codes: C08F 4/6541 and metals of C08F4/64 or compounds thereof
• CPC Class Codes: C08F 4/6548 magnesium or compounds thereof, not provided for in C08F4/6543 or C08F4/6546

Abstract

Olefin polymerization catalyst components having improved activity and morphological properties are disclosed and claimed. In particular, the components are prepared by reacting a carbonized magnesium alkoxide or aryloxide component with a halogenated tetravalent titanium component, a halohydrocarbon component and an electron donor.

Claims

1. A solid magnesium halide/titanium halide catalyst component containing no carbonate magnesium compound useful for the polymerization of alphaolefins which has been obtained by

(a) heating a carbonated magnesium compound of the formula MgR'"'"'R"xCO₂ wherein R'"'"' is an alkoxide or aryloxide group, R" is an alkoxide group, aryloxide group or halogen, and x has a value between about 0.1 and 2.0 to a temperature above 100°

C. for a period of time sufficient to cause complete loss of CO₂ ;

(b) contacting the resulting product with a halide of tetravalent titantium in the presence of a halohydrocarbon and an electron donor;

(c) contacting the resulting halogenated product with a tetravalent titanium halide;

(d) washing the resulting product to remove unreacted titanium compounds; and

(e) recovering the solid product.

2. The solid component of claim 1 wherein said carbonated magnesium compound is prepared by bubbling essentially anhydrous CO₂ through a dispersion of MgR'"'"'R" in an alcohol.

3. The solid component of claim 1 wherein said carbonated magnesium compound is in the form of essentially spherical particles such that at least 90% by weight of the particles have diameters between about 10 and about 40 microns.

4. The solid component of claim 3 wherein said essentially spherical particles are obtained by spray drying a solution of said carbonated magnesium compound.

5. The solid component of claim 1 wherein said essentially spherical particles are obtained by impregnating an inert particulate support with a solution of said carbonated magnesium compound and removing the solvent.

6. The solid component of claim 1 wherein R'"'"' and R" are both ethoxide groups.

7. The solid component of claim 2 wherein R'"'"' and R" are both ethoxide groups and the alcohol is ethanol.

8. The solid component of claim 6 wherein said tetravalent titanium halide is TiCl₄ and said halohydrocarbon is a chlorohydrocarbon.

9. The solid component of claim 6 wherein said electron donor is an ester or diester of an aromatic carboxylic acid.

10. An olefinic polymerization catalyst composition comprising an organoaluminum compound, a selectivity control agent, and the solid catalyst component of claim 1 wherein the atomic ratio of aluminum to titanium is about 30:

1 to about 100;

1.

11. The composition of claim 10 wherein said organoaluminum compound is a trialkylaluminum and said selectivity control agent is selected from the group consisting of esters and diesters of aromatic carboxylic acids and silicon compounds of the general formula R_n¹ Si(OR²)_4-n, where n is between zero and three, R¹ is a hydrocarbon group or a halogen atom and R² is a hydrocarbon group.

12. The composition of claim 11 wherein said trialkylaluminum is triethyl aluminum.

13. The composition of claim 11 wherein said selectivity control agent is selected from ethyl benzoate and diisobutyl phthalate.

14. The composition of claim 11 wherein said selectivity control agent is selected from diphenyl dimethoxy silane and phenethyltrimethoxy silane.