Hydrometallurgical process for producing finely divided spherical maraging steel powders containing readily oxidizable alloying elements

• US 4,772,315 A
• Filed: 01/04/1988
• Issued: 09/20/1988
• Est. Priority Date: 01/04/1988
• Status: Expired due to Fees

• Current Assignee: GTE Products Corporation (Ams-Osram AG)
• Original Assignee: GTE Products Corporation (Ams-Osram AG)
• Inventors: Johnson, Walter A., Kopatz, Nelson E., Ritsko, Joseph E.
• Primary Examiner(s): NOT, DEFINED
• Application Number:
  US07/140,514
• Time in Patent Office: 260 Days
• Field of Search: 75/0.5 AA, 75/0.5 AC, 75/0.5 C, 75/251
• US Class Current: 420/96
• CPC Class Codes: B22F 1/065 Spherical particles
• CPC Class Codes: B22F 1/148 Agglomerating
• CPC Class Codes: B22F 2999/00 Aspects linked to processes or compositions used in powder metallurgy
• CPC Class Codes: B22F 9/08 by casting, e.g. through sieves or in water, by atomising or spraying using electric discharge B22F9/14
• CPC Class Codes: C22C 33/0207 Using a mixture of prealloyed powders or a master alloy mixtures of metal powder in general B22F1/09
• CPC Class Codes: C22C 33/0285 with Cr, Co, or Ni having a minimum content higher than 5%

Abstract

A process for producing spherically shaped maraging steel powder particles containing a readily oxidizable metal comprises forming an aqueous solution containing the metal values of iron, cobalt, nickel and molybdenum, in a predetermined ratio, forming a reducible solid material from the solution reducing the solid material to form metallic poweder particles. These particles are agglomerated with a predetermined amount of a second group consisting of at least one readily oxidizable metal selected from the group consisting of aluminum, titanium and vanadium. The agglomerates are entrained in a carrier gas and fed into a high temperature zone and droplets are formed. The droplets are cooled to form essentially spherical shaped particles of a maraging steel alloy containing at least one readily oxidizable metal.

Claims

1. A process comprising:

(a) forming an aqueous solution containing the metal values of iron, cobalt, nickel and molybdenum, said metals being present in a predetermined ratio,

(b) forming from said solution a reducible solid material selected from the group consisting of salts of said metals, oxides of said metals, hydroxides of said metals and mixtures thereof,

(c) reducing said material to form metallic powder particles,

(d) agglomerating said particles with a predetermined amount of a second group consisting of at least one readily oxidizable metal selected from the group consisting of aluminum, titanium and vanadium and,

(e) entraining at least a portion of said agglomerates in a carrier gas,

(f) feeding said entrained agglomerates and said carrier gas into a high temperature zone and maintaining said agglomerates within said zone for a sufficient time to melt at least about 50% by weight of said agglomerates and to form droplets therefrom, and

(g) cooling said droplets to form essentially spherical shaped particles of a maraging steel alloy containing at least one readily oxidizable metal.

2. A process according to claim 1 wherein said solution contains a mineral acid selected from the group consisting of hydrochloric, sulfuric and nitric acids.

3. A process according to claim 2 wherein said mineral acid is hydrochloric acid.

4. A process according to claim 1 wherein said aqueous solution contains a water soluble acid.

5. A process according to claim 2 wherein said reducible solid material is formed by evaporation of the water from the solution.

6. A process according to claim 2 wherein said reducible solid material is formed by adjusting the pH of the solution to form a solid which is separated from the resulting aqueous phase.

7. A process according to claim 1 whrein said carrier gas is an inert gas.

8. A process according to claim 1 wherein said high temperature zone is created by a plasma torch.

9. A process according to claim 1 wherein said agglomerating is achieved by spray drying.

10. A process according to claim 1 wherein said material produced by step (b) is subjected to a particle size reduction step prior to the reduction step (c).

11. A process according to claim 1 wherein the powder particles from step (c) are subjected to a particle size reduction step prior to the agglomerating step (d).

12. A process according to claim 1 wherein at least 50% of said metallic powder particles have a size less than about 20 micrometers.

13. A composition consisting essentially of maraging steel alloy powders containing at least one readily oxidizable metal wherein said powders consist essentially of spherical particles wherein at least 50% of said particles have a size less than about 50 micrometers and an average particle size of less than about 50 micrometers.

14. A composition according to claim 13 wherein at least 50% of said particles have a size less than about 20 micrometers and an average particle size of less than about 20 micrometers.

15. A composition according to claim 13 wherein said composition consists essentially of an alloy having the following elements in per cent by weight, from about 1 to 14% of molybdenum, from about 5% to about 20% of cobalt, from about 5% to about 20% of nickel, from about 0.05% to about 1% of at least one readily oxidizable metal selected from the group consisting of aluminum, titanium and vanadium.

16. A composition according to claim 15 wherein said composition contains both aluminum and titanium.