Oxazolidines containing silane groups
First Claim
1. A compound of the general formula I ##STR44## in which R1 is hydrogen, C1 -C12 -alkyl, C5 -C7 -cycloalkyl, phenyl or benzyl and R2 is hydrogen or C1 -C4 -alkyl, or R1 and R2, together with the C atom to which they are attached, form a 5-membered or 6-membered ring, and R3, R4, R5 and R6 are identical or different and are hydrogen, C1 -C12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C1 -C4 -alkyl, halogen or C1 -C4 -alkoxy, or is a group of the formula --CH2 OR7 (II) in which R7 is C1 -C12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C1 -C4 -alkyl, halogen or C1 -C4 -alkoxy, or is --C(O)--R8, and R8 is C1 -C12 -alkyl, and also not more than two of the radicals R3, R4, R5 and R6 are one or two groups of the formula --CH2 CH2 Si(OR9)3 (III), --CH2 OC(O)CH2 CH2 Si(OR9)3 (IV), --CH2 O(Cm H2m)Si(OR9)3 (V) or ##STR45## in which R9 is C1 -C4 -alkyl or phenyl and m is a number from 1 to 8 and r is a number 1 or 2 and t is 0, 1 or 2 and R1 is as defined above, and, in addition, compounds of the formula I in which R4 and R5 together form a group of the formula ##STR46## in which R9 is as defined above and R3 and R6 in this case are hydrogen and n is 1 or 2 and, if n is 1, Z is an organic radical which is derived from a primary amine ZNH2 and can contain one or two --Si(OR9)3 groups and, if n is 2, Z is a divalent organic radical derived from a diprimary diamine H2 NZNH2 ;
- subject to the proviso that the compounds of the formula I contain one to three --Si(OR9)3 groups.
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Accused Products
Abstract
Compounds of the general formula I ##STR1## in which R1 is hydrogen, C1 -C12 -alkyl, C5 -C7 -cycloalkyl, phenyl or benzyl and R2 is hydrogen or C1 -C4 -alkyl, or R1 and R2, together with the C atom to which they are attached, form a 5-membered or 6-membered ring, and R3, R4, R5 and R6 are identical or different and are hydrogen, C1 -C12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C1 -C4 -alkyl, halogen or C1 -C4 -alkoxy, or is a group of the formula --CH2 OR7 (II) in which R7 is C1 -C12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C1 -C4 -alkyl, halogen or C1 -C4 -alkoxy, or is --C(O)--R8, and R8 is C1 -C12 -alkyl, and also not more than two of the radicals R3, R4, R5 and R6 are one or two groups of the formula --CH2 CH2 Si(OR9)3 (III), --CH2 OC(O)CH2 CH2 Si(OR9)3 (IV), --CH2 O(Cm H2m)Si(OR9)3 (V) or ##STR2## in which R9 is C1 -C4 -alkyl or phenyl and m is a number from 1 to 8 and r is a number 1 or 2 and t is 0, 1 or 2 and R1 is as defined above, and, in addition, compounds of the formula I in which R4 and R5 together form a group of the formula ##STR3## in which R9 is as defined above and R3 and R6 in this case are hydrogen and n is 1 or 2 and, if n is 1, Z is an organic radical which is derived from a primary amine ZnH2 and can contain one or two --Si(OR9)3 groups and, if n is 2, Z is a divalent organic radical derived from a diprimary diamine H2 NZNH2 ; subject to the proviso that the compounds of the formula I contain one to three --Si(OR9)3 groups, are suitable for use as adhesion promoters, particularly for moisture-curing epoxide and polyurethane resins.
14 Citations
19 Claims
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1. A compound of the general formula I ##STR44## in which R1 is hydrogen, C1 -C12 -alkyl, C5 -C7 -cycloalkyl, phenyl or benzyl and R2 is hydrogen or C1 -C4 -alkyl, or R1 and R2, together with the C atom to which they are attached, form a 5-membered or 6-membered ring, and R3, R4, R5 and R6 are identical or different and are hydrogen, C1 -C12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C1 -C4 -alkyl, halogen or C1 -C4 -alkoxy, or is a group of the formula --CH2 OR7 (II) in which R7 is C1 -C12 -alkyl, phenyl which is unsubstituted or monosubstituted to trisubstituted by C1 -C4 -alkyl, halogen or C1 -C4 -alkoxy, or is --C(O)--R8, and R8 is C1 -C12 -alkyl, and also not more than two of the radicals R3, R4, R5 and R6 are one or two groups of the formula --CH2 CH2 Si(OR9)3 (III), --CH2 OC(O)CH2 CH2 Si(OR9)3 (IV), --CH2 O(Cm H2m)Si(OR9)3 (V) or ##STR45## in which R9 is C1 -C4 -alkyl or phenyl and m is a number from 1 to 8 and r is a number 1 or 2 and t is 0, 1 or 2 and R1 is as defined above, and, in addition, compounds of the formula I in which R4 and R5 together form a group of the formula ##STR46## in which R9 is as defined above and R3 and R6 in this case are hydrogen and n is 1 or 2 and, if n is 1, Z is an organic radical which is derived from a primary amine ZNH2 and can contain one or two --Si(OR9)3 groups and, if n is 2, Z is a divalent organic radical derived from a diprimary diamine H2 NZNH2 ;
- subject to the proviso that the compounds of the formula I contain one to three --Si(OR9)3 groups.
- View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19)
- 6. A compound according to claim 1 of the formula I in which n is 1 and Z is a group of the formula
- space="preserve" listing-type="equation">--[(R.sup.10)C(R.sup.11)].sub.u --O--R.sup.12 (IX), --(R.sup.10)C(R.sup.11)--C(O)O(CH.sub.2).sub.3 Si(OR.sup.9).sub.3 (X)
in which u is 2, 3 or 4 and R10 and R11 are hydrogen or methyl and R12 is a group of the formula ##STR47## in which the symbols m, t, R1 and R9 are as defined in claim 1.
- 7. A compound according to claim 1 of the formula I in which n is 1 and Z is a group of the formula
- space="preserve" listing-type="equation">--[(R.sup.10)C(R.sup.11)].sub.u --OR.sup.7 (XVII)
in which u is 2, 3 or 4 and R10 and R11 are hydrogen or methyl, and R7 is as defined in claim 1.
Specification
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- Resources
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Current AssigneeCiba-Geigy Corporation (Novartis Ag)
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Original AssigneeCiba-Geigy Corporation (Novartis Ag)
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InventorsMulhaupt, Rolf, Simon, Hubert
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Primary Examiner(s)Raymond, Richard L.
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Application NumberUS07/070,741Time in Patent Office442 DaysField of Search548/110US Class Current548/110CPC Class CodesC07F 7/1804 Compounds having Si-O-C lin...C08G 18/10 Prepolymer processes involv...C08G 18/3296 being in latent formC08G 18/3893 containing siliconC08K 5/54 Silicon-containing compound...C08L 63/00 Compositions of epoxy resin...C08L 75/04 Polyurethanes
