Conductive polymer compositions

• US 4,774,024 A
• Filed: 03/14/1985
• Issued: 09/27/1988
• Est. Priority Date: 03/14/1985
• Status: Expired due to Term

• Current Assignee: Littelfuse Incorporated
• Original Assignee: Raychem Limited (TE Connectivity Limited)
• Inventors: Thein, Nelson H., Deep, Marguerite E.
• Primary Examiner(s): Barr, Josephine
• Application Number:
  US06/711,909
• Time in Patent Office: 1,293 Days
• Field of Search: 252/511, 252/510, 252/506, 252/507, 252/508, 524/495, 524/496, 524/437, 524/394, 524/434, 522/71
• US Class Current: 252/511
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08L 23/06 Polyethene
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon
• CPC Class Codes: H01C 7/027 consisting of conducting or semi-conducting material dispersed in a non-conductive organic material

Abstract

Conductive polymer compositions, particularly PTC compositions, which contain alumina trihydrate, or another arc-controlling agent, and a lubricant or coupling agent. Advantages which can result from use of the lubricant or coupling agent include improved PTC behavior and improved adhesion to metal conductors, in particular metal foils and solid metal wires.

Claims

1. A conductive polymer composition which comprises

(1) a polymeric component;

(2) a particulate conductive filler component comprising carbon black which is dispersed in the polymeric component;

(3) an arc-controlling agent which (i) comprises a particulate compound which, when heated in the absence of air, decomposes to give H₂ O, CO₂, or N₂, and (ii) is present at 7 to 25% by volume of the composition; and

(4) a lubricant or coupling agent for the arc-controlling agent, said lubricant or coupling agent comprising an organo-silicon compound, a stearate or a titanate which is (i) precoated onto the arc-controlling agent, and (ii) if the lubricant or coupling agent is not pre-coated onto the arc-controlling agent, the lubricant or coupling agent is present at at least 0.5% by volume of the composition.

2. A composition according to claim 1 wherein the arc-controlling agent is alumina trihydrate.

3. A composition according to claim 2 wherein the lubricant or coupling agent is coated onto the alumina trihydrate.

4. A composition according to claim 3 which comprises a silane-coated alumina trihydrate.

5. A composition according to claim 3 which comprises a stearate-coated alumina trihydrate.

6. A composition according to claim 3 which comprises a titanate-coated alumina trihydrate.

7. A composition according to claim 1 wherein the lubricant or coupling agent is pre-coated onto the arc-controlling agent.

8. A composition according to claim 1 which exhibits PTC behavior and which has been cross-linked by radiation.