Multiband emitter matched to multilayer photovoltaic collector

• US 4,776,895 A
• Filed: 06/02/1987
• Issued: 10/11/1988
• Est. Priority Date: 06/02/1987
• Status: Expired due to Term

• Current Assignee: Quantum Group Inc.
• Original Assignee: Quantum Group Inc.
• Inventors: Goldstein, Mark K.
• Primary Examiner(s): Weisstuch, Aaron
• Application Number:
  US07/057,902
• Time in Patent Office: 497 Days
• Field of Search: 136/253, 136/249 TJ
• US Class Current: 136/253
• CPC Class Codes: H01L 31/043 Mechanically stacked PV cells
• CPC Class Codes: H02S 10/30 Thermophotovoltaic systems photovoltaic cells specially adapted for conversion or sensing of infrared [IR] radiation H01L31/00; thermoelectric devices H10N10/00
• CPC Class Codes: H02S 99/00 Subject matter not provided for in other groups of this subclass
• CPC Class Codes: Y02E 10/50 Photovoltaic [PV] energy

Abstract

A thermophotovoltaic electric generating system provides high thermal to electric conversion efficiency by use of matched radiation emitter and radiation collector. The radiation emitter comprises ceramic materials which emit thermally stimulated quantum radiation in at least two characteristic wavelength bands when heated above a threshold temperature. By employing a low emissivity ceramic doped with rare earth metal oxide, more than 50% of the radiation emitted from the surface can be concentrated in two or more characteristic wavelength bands. A multilayer photovoltaic device selectively absorbs the radiation at the characteristic wavelength bands for high electric conversion efficiency. An overlying layer of the photovoltaic collector selectively absorbs at least one of such characteristic wavelength bands and is transparent to another wavelength band which is absorbed by an underlying photovoltaic layer. Preferably the emitter is a porous fiber matrix surface combustion burner comprising primarily aluminum oxide, from 8 to 20% yttrium oxide, and a minor amount of rare earth metal oxide. A ceramic tube burner may be used in an embodiment with preheated air, the outside of the tube having such a thermally stimulated quantum emitter.

Claims

1. A thermophotovoltaic electric power generating system comprising:

a ceramic emitter comprising a metal oxide having a low emissivity in about the same range as the emissivity of aluminum oxide, gallium oxide, thorium oxide, yttrium oxide, zirconium oxide, and at least one thermally stimulated quantum emitter material for emitting radiation in at least two wavelength bands when heated above a threshold temperature; and

a multilayer photovoltaic collector matched to the emitter for selectively absorbing radiation in the same wavelength bands emitted by the emitter.

2. A system as recited in claim 1, wherein the emitter comprises oxides of metals having unfilled inner electron shells.

3. A system as recited in claim 2, wherein the emitter comprises at least one rare earth metal oxide.

4. A system as recited in claim 3 wherein, the emitter comprises a minor amount of erbium oxide.

5. A system as recited in claim 1, wherein the emitter is primarily an oxide of at one metal selected from the group consisting of aluminum, gallium, yttrium, zirconium, and thorium.

6. A system as recited in claim 1, wherein the emitter comprises primarily aluminum oxide, from 8 to 20% yttrium oxide, and a minor amount of rare earth metal oxide.

7. A system as recited in claim 6, wherein the emitter further comprises a minor amount of an oxide of a metal selected from the group consisting of magnesium and tin.

8. A system as recited in claim 1, wherein each active layer of the photovoltaic collector selectively absorbs at least one characteristic wavelength band of radiation and is transparent to radiation in other wavelength bands.

9. A thermophotovoltaic electric power generating system comprising:

an emitting surface comprising a low emissivity ceramic and including at least one thermally stimulated quantum emitting material;

means for heating the surface to a sufficient temperature for stimulating such material to emit radiation in at least two characteristic wavelength bands; and

a photovoltaic device having band gaps for selectively absorbing and converting to electric current radiation in said characteristic wavelength bands.

10. A system as recited in claim 9, wherein the emitting surface comprises primarily an oxide of a metal selected from the group consisting of aluminum and yttrium.

11. A system as recited in claim 10, wherein the surface further comprises a minor amount of a rare earth metal oxide.

12. A system as recited in claim 11, wherein the surface further comprises an oxide of a metal selected from the group consisting of magnesium and tin.

13. A system as recited in claim 11, wherein the surface comprises from 8 to 20% yttrium.

14. A system as recited in claim 9, wherein the emitting surface comprises a porous surface combustion burner.

15. A system as recited in claim 14, wherein the porous surface combustion burner comprises ceramic fibers including at least one rare earth metal oxide adjacent to its outer surface.

16. A system as recited in claim 9, wherein the photovoltaic device comprises a plurality of layers of photovoltaic material wherein at least the upper layer selectively absorbs radiation of one characteristic wavelength band and is transparent to radiation of the other characteristic wavelength and the underlying layer absorbs the other characteristic wavelength band.

17. A system as recited in claim 9 wherein the emitting surface comprises a nonporous ceramic tube having a thermally stimulated quantum emitting material on at least its outer surface and means for supporting combustion inside the tube.

18. A system as recited in claim 17 wherein the ceramic tube comprises a layer of at least one rare earth metal oxide on the outer surface.

19. A method for generating electricity comprising:

heating a ceramic surface to a sufficient temperature to emit quantum radiation in at least two characteristic wavelength bands, the ceramic surface comprising primarily an oxide of at least one metal selected from the group consisting of aluminum, gallium, yttrium, zirconium and thorium, and a minor amount of an oxide of a metal with unfilled inner electron shells; and

selectively absorbing the characteristic wavelength bands in successive layers of a photovoltaic device for converting the radiation to electric current.

20. A method as recited in claim 19 comprising:

forming the ceramic surface to contain sufficient metal with unfilled inner electron shells to emit more than 50% of the radiation as thermally stimulated quantum radiation;

21. A method as recited in claim 19 comprising forming the ceramic surface to include a rare earth metal oxide.