Coated article and method of manufacturing the article

• US 4,777,090 A
• Filed: 11/03/1986
• Issued: 10/11/1988
• Est. Priority Date: 11/03/1986
• Status: Expired due to Term

• Current Assignee: Ovonic Synthetic Materials Company, Inc.
• Original Assignee: Ovonic Synthetic Materials Company, Inc.
• Inventors: Havener, Kenneth, Register, Arnold, Durisin, Daniel P., Ovshinsky, Stanford R., Flasck, James D., Custer, Russell C.
• Primary Examiner(s): Kittle, John E.
• Assistant Examiner(s): NOT, DEFINED
• Application Number:
  US06/926,271
• Time in Patent Office: 708 Days
• Field of Search: 427/45.1, 423/445, 423/446, 428/336, 428/408, 428/412, 428/423.1, 428/446, 428/688, 428/689, 428/702
• US Class Current: 428/408
• CPC Class Codes: C23C 16/029 Graded interfaces
• CPC Class Codes: C23C 16/26 Deposition of carbon only
• CPC Class Codes: C23C 16/511 using microwave discharges
• CPC Class Codes: C30B 25/02 Epitaxial-layer growth
• CPC Class Codes: C30B 29/04 Diamond
• CPC Class Codes: G02B 1/105 Protective coatings
• CPC Class Codes: G02B 1/111 using layers comprising organic materials
• CPC Class Codes: G02B 1/14 Protective coatings, e.g. hard coatings
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31678 Of metal
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers

Abstract

Disclosed is a coated article having a substrate with an adherent, abrasion resistant carbon coating. In a preferred examplification the coating is substantially transparent to visible light and partially absorbing to ultraviolet light. The coating has a relatively disordered portion at the substrate-coating interface and a relatively ordered portion remote from the substrate-coating interface. The coating is a microwave deposited coating with deposition initially at a low microwave energy, and thereafter at a high microwave energy.

Claims

1. A coated article comprising:

(a) a substrate chosen from the group consisting of soft metals, semiconductors and organic polymers; and

(b) an adherent, abrasion resistant coating thereon substantially amorphous and consisting essentially of carbon at the substrate-coating interface, graded in composition remote from the substrate-coating interface, and consisting essentially of one or more of C, or silicon dioxide, and mixtures thereof, where the compositionally graded material remote from the substrate-coating interface comprises SiOx where x is from 1.60 to 2.00.

2. The coated article of claim 1 wherein the coating has a a thickness of 2 to 5 microns and a transmissivity of 89 percent at wavelengths in the visible spectrum.

3. The coated article of claim 1 wherein the coated article has a polymeric substrate.

4. The coated article of claim 7 wherein the substrate is a polymer chosen from the group consisting of polyacrylates, polycarbonates, poly(allyl carbonates), and polyurethanes.

5. The coated article of claim 1 wherein the coated article has a metallic substrate or semiconductor substrate.

6. The coated article of claim 5 wherein the metallic substrate is a soft metallic substrate.

7. The coated article of claim 5 wherein the semiconductor substrate comprising amorphous silicon.

8. The coated article of claim 1 wherein the coating is prepared by the method comprising:

(a) providing a substrate to be coated in a vacuum chamber;

(b) providing a deposition gas comprising an inert gas and an active gas chosen from the group consisting of hydrocarbons and silanes;

(c) maintaining the deposition gas at a pressure of less than 10^-6 atmospheres;

(d) forming and maintaining a microwave plasma in contact with the substrate at an initial relatively high microwave power to decompose the gas and deposit a disordered coating a the substrate; and

(e) thereafter maintaining the microwave plasma in contact with the substrate at a relatively higher power and a graded gas pressure and increasing the silane content of the gas to build up the graded portion of the coating.

9. The coated article of claim 1 wherein

the coating thereon is matched in stress influencing parameters at an interface with the substrate, mix-matched in stress influencing parameters remote from the substrate, and graded in stress influencing parameters therebetween.

10. The coated article of claim 9 wherein the coating is matched to the substrate of the interface therewith in one or more stress influencing parameters chosen from the group consisting of modulus of elasticity, coefficient of thermal expansion, lattice parameters, extent of crystallinity, or degree of crystallinity.

11. The coated article of claim 9 wherein the coating is graded with respect to one or more stress influencing parameters chosen from the group consisting of composition, modulus of elasticity, coefficient of thermal expansion, lattice parameters, extent of crystallization, or degree of composition over a depth of several atomic diameters to 10 microns.

12. The coated article of claim 9 wherein the substrate is an amorphous silicon alloy semiconductor.

13. The coated article of claim 9 wherein the substrate is a transparent conductive oxide.